Electron paramagnetic resonance spectrometry of diesel particulate matter

Electron paramagnetic resonance (EPR) spectrometry has been used to study diesel particulate matter. The EPR signals for a graphitized carbon black and particles collected from two different diesel engines have been compared. Variations in the line widths and signal intensities due to various chemical and physical pretreatments of the particles were observed. The EPR signals for the diesel particulates were shown to be sensitive to oxygen, nitric oxide, nitrogen dioxide, and ultraviolet and visible radiation. These results suggest that EPR may be a convenient means for characterizing particles from different sources or for demonstrating particle reactivities. The demonstrated photochemical reactivities of the airborne particles have significant environmental health implications.     

Pollution studies on Nigerian rivers: The onset of lead pollution of surface waters in Ibadan

Lead levels in the waters and sediments of the lake of the International Institute of Tropical Agriculture, Agodi Lake, Oba Lake, at three stations on Ogunpa stream, and at three stations on Ona River were measured from October 1977 to June 1978, using the combined APDC-MIBK-flame atomic absorption spectrophotometry technique. The lead levels recorded ranged from 0.2 to 46 μg/L for the aqueous phases; however, the levels in the sediments were much higher, ranging from about 18 to 85 mg/kg (dry weight). Although there is nothing alarming about these levels, the levels of lead in water bodies located in areas with high traffic density were consistently higher than levels for comparable waters in low traffic density areas. Similarly, lead levels were significantly higher in the fresh sediments of water bodies in areas with high traffic density, clearly indicating the onset of lead pollution for those high traffic density areas.     

Concentration of some elements in the hair of cattle as an indicator of contamination by air pollutant deposition on grass

Some 20 elements were determined in cow hair sampled in farms located in various industrial and rural zones of Belgium. Apart from the well-documented dependence of hair contamination as a function of age, the most characteristic feature observed in this study is that the high correlations existing between concentrations of some elements in cow hair provide inter-element ratios which significantly vary from one farm to another. These variations parallel the variations observed in the air pollutants deposited on grass while the inter-element ratios remain almost constant in the soils of all the sampling sites. As a consequence, it is proposed that elemental deposition on pastures is the main source of contamination of cattle by these elements, at least in the rural sites of industrialized countries such as Belgium.     

PCBQ: Computerized quantification of total PCB and congeners in environmental samples

Computerized methodologies for the quantification of total PCBs, PCB in Aroclor mixtures and individual PCB congeners in environmental samples are presented. The method for total PCBs is based on a multiple-linear regression analysis using data from capillary gas chromatography of Arocolor standards. PCB congeners were identified and their weight percentages determined in Aroclor mixtures by GC/MS. PCB congeners and total PCBs were accurately quantified in predetermined test data and environmental samples.     

Trace element and radionuclide mass balances at a coal-fired electric generating station

Coal, bottom ash, and fly ash from Milliken Station, a coal-fired 270 MW power plant, were analyzed for 20 elements (Ag, Al, As, Be, Cd, Co, Cr, Cu, Ga, Hg, Mn, Ni, Pb, Sb, Se, Sn, Te, Tl, V, and Zn) and the major natural radionuclides (²³⁸U series, ²³²Th series, and ⁴⁰K). Mass balance calculations showed that most of the Hg, and some of the Sb and Se, were unaccounted for by ash collection, suggesting their possible discharge into the atmosphere. Silver, As, Hg, Pb, Cd, and Zn were more concentrated in the fly ash than in the bottom ash while all of the other elements were equally distributed, by concentration, between the ash fractions. The radionuclides showed a 46% higher concentration in fly ash than in bottom ash, and ²¹⁰Pb was enriched in the fly ash relative to the other radionuclides by a factor of 2.4. Mass balance calculations indicated a balance within statistical error for the radionuclides, except for ²¹⁰Pb.     

Degradation of volatile chlorinated aliphatic priority pollutants in groundwater

The known degradation products and degradative pathways involving selected volatile aliphatic chlorinated hydrocarbons in soil-groundwater systems are summarized. Current data indicate that the most commonly found products of microbial degradation of these compounds come from reductive dehalogenation, while nonmicrobial degradations tend to involve hydrolysis and/or oxidation. However, conclusions must be regarded as tentative, since most of the available studies have involved model systems and extrapolations, rather than direct studies of compounds in groundwater systems. Other potentially complicating factors, such as mobility and volatilization, are mentioned. Current knowledge is discussed in the context of data that would be desirable to obtain in future studies.     

Study of total organic halogen as a means to detect groundwater contamination

Total organic halogen (TOX) was evaluated as a means to detect contamination of groundwater by halogenated organics. Groundwater samples from monitoring wells at 10 Canadian landfill sites were analyzed for carbon adsorbable TOX, total organic carbon and volatile organics. Low concentrations of TOX (range, ND-44; median 8 μg Cl L^?1) were found at nine sites, and elevated TOX levels (?2072 μg Cl L^?1) at the tenth site. This latter site was studied in greater detail, and TOX and GC-MS analyses were carried out for volatile, base neutral, and acid extractable fractions of the water in six monitoring wells at this site. The TOX and GC-MS techniques were found to provide complementary information. GC-MS analysis detected high concentrations of 1,2-dichloroethylene, trichloroethylene, toluene, and ethylbenzene in some of the wells. TOX measurements, however, indicated the presence of halogenated contaminants in the base-neutral and acid extractable fractions, which had not been detected by GC-MS.     

咸宁市房地产业发展取向

近10年来，咸宁市房地产业的发展以个人开发为主，城镇规模的增长明显滞后于人口的增长，出现了一系列影响房地产经济持续发展的问题。在统计分析的基础上，用线性预测法计算了本市在未来10年内房地产发展的合理速度与规模。研究结果表明：在GDP保持9％增长率的情况下，2001-2010年咸宁市每年需净增居住用房地产300万m^2，房地产业的合理增长率为12．9％。稳定和规范住宅业的发展，加强城市基础设施和社会公共服务设施建设是今后本市房地产业发展的主要取向。     

灵活就业人员参加失业保险问题的探讨

随着灵活就业人员的大量出现，他们的社会保障问题已经成为一个新的社会问题。而现行失业保险政策并不适应灵活就业多样化的特点和多层次的需要，灵活就业人员没有被纳入失业保险覆盖范围，因此设计一套更能适应当前形势的合理的、高效的社会保障措施已经迫在眉睫。