高温干发酵对互花米草产气和结构的影响

互花米草的疯长已带来严重的环境问题,厌氧发酵提供了一种资源化的解决途径.通过渗滤床高温、干式发酵互花米草,考察其产气特性;并通过元素分析、X-ray和FT-IR分析,考察干发酵及预处理对互花米草物化性质的影响.结果表明:60 d高温干发酵互花米草,累计产气量为280.9 mL/g VS(0℃);总TS与VS去除率分别为...     

Chemical and microbiological hazards associated with recycling of anaerobic digested residue intended for agricultural use

In the present study, three full-scale biogas plants (BGP) were investigated for the concentration of heavy metals, organic pollutants, pesticides and the pathogenic bacteria Bacillus cereus and Escherichia coli in the anaerobically digested residues (ADR). The BGPs mainly utilize source-separated organic wastes and industrial food waste as energy sources and separate the ADR into an ADR-liquid and an ADR-solid fraction by centrifugation at the BGP. According to the Norwegian standard for organic fertilizers, the ADR were classified as quality 1 mainly because of high zinc (132-422 mg kg(-1) DM) and copper (23-93 mg kg(-1) DM) concentrations, but also because of high cadmium (0.21-0.60 mg kg(-1) DM) concentrations in the liquid-ADR. In the screening of organic pollutants, only DEHP (9.7-62.1 mg kg(-1)) and ∑ PAH 16 (0.2-1.98 mg kg(-1) DM) were detected in high concentrations according to international regulations. Of the 250 pesticides analyzed, 11 were detected, but only imazalil (<0.30-5.77 mg kg(-1) DM) and thiabendazol (<0.14-0.73 mg kg(-1) DM) were frequently detected in the ADR-fiber. Concentrations of imazalil and thiabendazol were highest during the winter months, due to a high consumption of citrus fruits in Norway in this period. Ten percent of the ADR-liquid samples contained cereulide-producing B. cereus, whereas no verotoxigenic E. coli was detected. The authors conclude that the risk of chemical and bacterial contamination of the food chain or the environment from agricultural use of ADR seems low.     

农村沼气建设对四川省节能减排的贡献——以西昌市的典型调查为例

以西昌市农村能源利用结构为例,分析发展农村户用沼气后,在能源的需求量减少的情况下,可以获得更多的热能,并达到减排的目的。     

球形氧化铝负载Ni-Co双金属催化剂上沼气重整制氢——操作条件的影响

前期研究开发出了活性、稳定性和抗积碳性能都较好的沼气重整制氢Ni-Co/La2O3-Al2O3催化剂。在此基础上选用商业球形氧化铝作为载体(4~5 mm)并掺杂La2O3,用浸渍法制备了Ni-Co/La2O3-Al2O3球形催化剂,以CH4/CO2体积比为1的混合气模拟沼气,考察了操作条件对工业尺度催化剂沼气重整反应性能的影响。结果表明:负载活性组分的γ-Al2O3球形催化剂的沼气重整活性基本达到小试的水平。反应温度升高有利于提高催化剂的重整活性,850℃以上催化剂的活性趋于稳定。反应温度升高有利于减少催化剂的表面积碳,却加速了金属颗粒的团聚。随着空速的增加,催化剂的活性显著降低。较好的催化剂还原方式为用纯H2在700℃下还原2 h,用该方式还原的催化剂反应后金属粒径较小,平均积碳速率较低。     

An overview on biogas generation from anaerobic digestion of food waste

Food waste is an inevitable type of waste in every city, and its treatment technology evolves with time. Due to the high organic content and high biodegradability of food waste, anaerobic digestion becomes a commonly accepted treatment method to deal with it. This review article summarizes key factors for anaerobic digestion and provides useful information for successful anaerobic digestions. Reasonable temperature and pH are essential for a successful and productive anaerobic digestion process. A good inoculum to substrate ratio triggers a profitable food waste digestion. Good mixing and small particle sizes are important factors too. In addition, the pros and cons of different reactors to food waste digestion are highlighted. Moreover, co-digestion of food waste with animal manures, sewage sludge, and green waste were introduced.     

利用水葫芦治理水体富营养化与生产沼气的环境经济学分析

资源化、无害化利用水葫芦是治理其泛滥的有效途径。利用水葫芦去除水体中的营养物并利用其生物质生产沼气在技术上具有可行性,但是其环境经济效益尚不明确。以滇池为例,针对富营养化水体的水葫芦控制进行了成本收益分析。与将水葫芦打捞后填埋处理相比,将所打捞的水葫芦用于生产沼气具有经济可行性和能量效率。与现行的填埋处理法相比,实施沼气项目不但同样能控制水葫芦泛滥,而且能生产能源。此外,填埋水葫芦会释放甲烷这一环境问题值得重视,利用水葫芦生产沼气可以减少温室气体的排放,但减排的价值取决于沼气厂的生产规模。由于将水葫芦填埋和用于生产沼气都能去除水体中的营养物,只有当沼气厂的水葫芦处理量大于当前的填埋量时,沼气项目才具有额外的水质改良价值。在中国关于水污染控制、可再生能源发展和节能减排等政策的背景下,利用水葫芦生产沼气是一种潜在的政策响应     

机械淋滤-厌氧生物组合工艺处理有机生活垃圾中试研究

采用机械淋滤/厌氧生物组合工艺,充分发挥机械淋滤反应器的水解酸化功能和厌氧生物反应器的产甲烷功能,对有机生活垃圾进行了中试规模处理。厌氧生物反应器经过接种,15 d驯化完成。厌氧反应器出水回流淋洗水量对机械淋滤反应器运行特征有较大影响,当回流淋洗水量为3.0 m3/d时,淋滤液COD、VFA第8天时浓度分别为41 000 kg/L和2 000 kg/L。对机械淋滤反应器/厌氧反应器组合工艺进行了多批次实验,每吨有机生活垃圾平均产生沼气87.2 m3,甲烷含量稳定在75%,平均产沼系数为0.46 m3/kg COD,厌氧生物反应器出水COD平均值为560 mg/L,在对有机生活垃圾处理的同时实现有机生活垃圾资源化利用。     

农村联户沼气工程可行性研究及经验——以浙江省江山市淤头镇为例

以浙江省江山市淤头镇联户沼气工程为例,从经济、技术及社会可行性三方面进行具体分析,指出联户沼气相比户用沼气具有规模经济效益显著、资金支持渠道多、管理便利、农户满意度高、技术和市场创新空间大等突出优势,可为联户沼气工程推广提供经验借鉴。     

Acquisition feasibility and methane fermentation effectiveness of biomass of microalgae occurring in eutrophicated aquifers on the example of the Vistula Lagoon

This study was aimed at establishing the feasibility of microalgae biomass acquisition from waters of the Vistula Lagoon with the use of an installation operating in the fractional–technical scale, and at determining the effectiveness of biogas production from the acquired substrate. Depending on the technological solution of the concentration process, the degree of aquatic biomass hydration ranged from 99.6 to 97.90%. The quantity of biogas produced during methane fermentation fitted within the range of 243.9 to 395.2 dm³/kg d.m.. The values achieved were found to depend directly on the concentration of organic matter in the acquired water biomass and on system’s loading with a feedstock of organic compounds. The content of methane in a gaseous mixture ranged from 41.4 to 61.9%. The biomass produced was predominated by taxa belonging to Cyanoprokaryota, Bacillarophyceae, and Chlorophyta.     

Exergy and economic analysis of organic Rankine cycle hybrid system utilizing biogas and solar energy in rural area of China

Due to the existing huge biogas resource in the rural area of China, biogas is widely used for production and living. Cogeneration system provides an opportunity to realize the balanced utilization of the renewable energy such as biogas and solar energy. This article presented a numerical investigation of a hybrid energy-driven organic Rankine cycle (ORC) cogeneration system, involving a solar ORC and a biogas boiler. The biogas boiler with a module of solar parabolic trough collectors (PTCs) is employed to provide heat source to the ORC via two distinct intermediate pressurized circuits. The cogeneration supplied the power to the air-condition in summer condition and hot water, which is heated in the condenser, in winter condition. The system performance under the subcritical pressures has been assessed according to the energy–exergy and economic analysis with the organic working fluid R123. The effects of various parameters such as the evaporation and condensation temperatures on system performance were investigated. The net power generation efficiency of the cogeneration system is 11.17%, which is 25.8% higher than that of the base system at an evaporation temperature 110°C. The exergy efficiency of ORC system increases from 35.2% to 38.2%. Moreover, an economic analysis of the system is carried out. The results demonstrate that the profits generated from the reduction of biogas fuel and electricity consumption can lead to a significant saving, resulting in an approximate annual saving from $1,700 to $3,000. Finally, a case study based on the consideration of typical rural residence was performed, which needs a payback period of 7.8 years under the best case.