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371.
ABSTRACT. Water development planning has virtually since its beginnings over one hundred fifty years ago utilized a variety of devices for involving segments of the public. But a new insistence for increased public participation, particularly at the Federal level, has stimulated re-examination of objectives and methods for relating water planning to citizen interests and preferences. Involved is partly a recommitment to democratic symbols, partly a recognition that segments of society have been overlooked, and partly a reaction to the pressures of confrontation and demonstration. The rhetoric and polemics of participation have often implied a kind of “town-meeting” process of decision, difficult at best in a nation of 200 million. In water planning more emphasis has been placed on listening to citizens, which has meant providing opportunities for influentials to express their views and preferences. A more adequate approach would seem to require identification of all who are significantly affected by plans and proposals (even though they may not perceive then-interest). But gaining greater participation does not make the planning job easier. It may increase tension and conflict; it may require difficult choices; and it can alter existing power relationships and generate changes with considerable consequences for the agency and its programs.  相似文献   
372.
随着多环境介质问题研究的深入,重金属在跨介质迁移时产生的界面效应问题倍受人们关注。土-岩界面因其特有的微环境结构和特性,使重金属在该界面的行为过程既部分地表现出与在两侧的环境介质运移过程的动力学特征及机制,又有其独特的特性。有关研究表明自然因素及人为活动等引起的环境参数的变化对土-岩界面的重金属行为有显著影响。今后土-岩界面的重金属行为研究应在目前研究状况的基础上立足于为土壤污染的修复提供技术支撑。  相似文献   
373.
We present an overview of possible biotechnological applications for using carbon dioxide for the synthesis of chemicals. These approaches are very appealing as they contribute to the implementation of new synthetic methodologies that reduce waste and make a better use of carbon and energy. Several synthetic approaches will be considered including both the incorporation of the whole COO moiety or its reduction to other C1 molecules. Each option will be discussed making a comparison between the natural and artificial process in order to highlight the possibility to learn from Nature and develop useful mimetic or enzymatic systems.  相似文献   
374.
Chloroform in the environment: occurrence,sources, sinks and effects   总被引:4,自引:0,他引:4  
McCulloch A 《Chemosphere》2003,50(10):1291-1308
The chloroform flux through the environment is apparently constant at some 660±220 Gg yr−1 (±1σ) and about 90% of the emissions are natural in origin: the largest single source being in offshore sea water (contributing 360±90 Gg yr−1), with soil processes the next most important (220±100 Gg yr−1). Other natural sources, mainly volcanic and geological, account for less than 20 Gg yr−1. The non-natural sources total 66±23 Gg yr−1 and are much better characterised than the natural sources. They are predominantly the result of using strong oxidising agent on organic material in the presence of chloride ion, a direct parallel with the natural processes occurring in soils.

Chloroform partitions preferentially into the atmosphere; the equilibrium distribution is greater than 99% and the average global atmospheric concentration has been calculated to be 18.5 pmol mol−1. Atmospheric oxidation, the principal removal process, is approximately in balance with the identified source fluxes. Chloroform is widely dispersed in the aquatic environment (even naturally present in some mineral waters). Consequently, it is also widely dispersed in the tissue of living creatures and in foodstuffs but there is little evidence of bioaccumulation and the quantities in foodstuffs and drinking water are not problematical for human ingestion at the highest concentrations found. Definitive studies have shown that current environmental concentrations of chloroform do not present an ecotoxicological risk, even to fish at the embryonic and larval stages when they are most susceptible.

By virtue of the very small amounts that actually become transported to the stratosphere, chloroform does not deplete ozone materially, nor is it a photochemically active volatile organic compound (VOC). It has a global warming potential that is less than that of the photochemically active VOCs and is not classed as a greenhouse gas.  相似文献   

375.
为了研究高级氧化法脱除聚乙烯醇(PVA)浆料清洁生产新工艺的可行性,研究了3种高级氧化法UV/H2O2、UV/TiO2、Nafion-Fe2 /H2O2对含PVA溶液的氧化降解,其降解效果依次为:UV/H2O2>Nafion-Fe2 /H2O2>UV/TiO2.对于UV/H2O2法,PVA降解速率与H2O2的初始浓度成正相关,且H2O2浓度为2.95 mmol/L时14 min内就能使PVA的去除率达到98%;pH和温度对PVA的氧化降解效果影响不明显.在此基础上,对建立在高级氧化法基础上的退浆新工艺进行了探讨,结果表明,在65℃和75℃下,高级氧化法条件下的纯棉织物PVA退浆率分别达到70.16%和95.65%;该法不仅可以促进PVA从纯棉织物上的脱附,而且可以达到对PVA的较高降解效果,使得所排退浆废水的生化处理难度明显降低.  相似文献   
376.
377.
Microbial oxidation and reduction of iron and sulfur are important parts of biogeochemical cycles in acidic environments such as geothermal solfataric regions. Species of Acidithiobacillus and Leptospirillum are the common ferrous-iron and sulfur oxidizers from such environments. This study focused on the Tengchong sofataric region, located in Yunnan Province, Southwest China. Based on cultivation, 9 strains that grow on ferrous-iron and sulfuric compounds were obtained. Analysis of 16S rRNA genes of the 9 strains indicated that they were a liated to Acidithiobacillus, Alicyclobacillus, Sulfobacillus, Leptospirillum and Acidiphilium. Physiological and phylogenetic studies indicated that two strains (TC-34 and TC-71) might represent two novel members of Alicyclobacillus. Strain TC-34 and TC-71 showed 94.8%–97.1% 16S rRNA gene identities to other species of Alicyclobacillus. Di erent from the previously described Alicyclobacillus species, strains TC-34 and TC-71 were mesophilic and their cellular fatty acids do not contain !-cyclic fatty acids. Strain TC-71 was obligately dependent on ferrous-iron for growth. It was concluded that the ferrous-iron oxidizers were diversified and Alicyclobacillus species were proposed to take part in biochemical geocycling of iron in the Tengchong solfataric region.  相似文献   
378.
Life cycle assessment is emerging as a powerful tool in the evaluation of the environmental impact of manufacturing processes. This paper describes a general methodology for the life cycle analysis of manufacturing processes taking into account the flexibility and decision-making potential of knowledge base systems. Emphasis is placed on on-site waste minimisation and associated sustainability characteristics in relation to environmental impact assessment and process improvement. The ensuing software model is applied with some success to an initial study of pulp and paper manufacture.  相似文献   
379.
水稻土中铁-氮循环耦合体系影响镉活性机理研究   总被引:4,自引:1,他引:4  
关于铁-氮循环耦合体系对镉(Cd)活性影响的研究目前尚鲜见报道.本文采用淹水培养试验,研究不同硝酸根(NO_3~-)、铵根(NH_4~+)处理条件下,南方典型Cd污染水稻土中铁氧化还原与氮形态转化耦合关系及其对Cd活性影响的机理.结果表明:随着培养时间延长,不同处理的pH值逐渐向7.0靠拢,Eh值由273~321 mV持续下降至118~132 mV,pe+pH值(e-活度的负对数值与H+活度的负对数值之和)从10.62~11.19持续下降至8.55~8.83,土-水体系处于中度还原条件;化学反硝化(Chemodenitrification)和NO_3~-依赖的厌氧铁氧化过程(Microbial NO_3~--dependent FeIIoxidation,NDFO)生成无定形氢氧化铁(Fe(OH)_3(amorp)),其对Cd~(2+)专性吸附及与Cd~(2+)共沉淀降低了有效态Cd浓度,加之pH值上升增大Cd~(2+)在土壤固相表面的吸附量,导致水稻土中Cd活性下降;NH_4~+被Fe(OH)_3(amorp)厌氧氧化(Anaerobic NH_4~+oxidation coupled to FeIII reduction,Feammox)会消耗H+而提高体系的pH值,在一定程度上会降低Cd活性,但其自身与Cd~(2+)对土壤固相表面吸附位点的竞争,可能会更大程度地减少Cd~(2+)在土壤固相表面的吸附量,而导致Cd活性提高.本研究成果可为丰富和拓展水稻土中Cd的生物地球化学理论,并为南方Cd污染农田修复及治理提供科学依据.  相似文献   
380.
文章进行了UV/H2O2/GAC和GAC系统用于微污染水深度处理的试验研究,结果表明:UV/H2O2/GAC对uV篮;和TOC均有良好的去除效果,当H2O2投量3.0mg/L,UV/H2O2反应器停留时间20min时,系统的COD和UV254去除率为44.6%和72.8%。UV/H2O2主要作用在于改善了GAC对有机物的吸附,产生了羟基自由基,从而提高了去除效果。  相似文献   
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