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91.
制备了一种聚(丙烯酸-co-丙烯酰胺)/膨润土/腐植酸钠三维网络凝胶吸附剂,重点考察了吸附剂对Cd2+吸附的pH依赖性、吸附动力学和吸附等温线.结果表明,Cd2+溶液pH值对吸附容量有较大影响.在pH=8、吸附时间30 min、Cd2+溶液初始浓度0.02 mol/L和吸附剂用量0.10 g的条件下,吸附剂对Cd2+的饱和吸附量可达294.7 mg/g.与膨润土相比,三维网络凝胶吸附剂具有更高的吸附容量和更快的吸附速率. 相似文献
92.
Reclamation and revegetation of fly ash disposal sites - Challenges and research needs 总被引:1,自引:1,他引:0
Haynes RJ 《Journal of environmental management》2009,90(1):43-53
Coal-fired power generation is a principal energy source throughout the world. Approximately, 70-75% of coal combustion residues are fly ash and its utilization worldwide is only slightly above 30%. The remainder is disposed of in landfills and fly ash basins. It is desirable to revegetate these sites for aesthetic purposes, to stabilize the surface ash against wind and water erosion and to reduce the quantity of water leaching through the deposit. Limitations to plant establishment and growth in fly ash can include a high pH (and consequent deficiencies of Fe, Mn, Cu, Zn and P), high soluble salts, toxic levels of elements such as B, pozzalanic properties of ash resulting in cemented/compacted layers and lack of microbial activity. An integrated organic/biotechnological approach to revegetation seems appropriate and should be investigated further. This would include incorporation of organic matter into the surface layer of ash, mycorrhizal inoculation of establishing vegetation and use of inoculated legumes to add N. Leaching losses from ash disposal sites are likely to be site-specific but a sparse number of studies have revealed enriched concentrations of elements such as Ca, Fe, Cd, Pb, and Sb in surrounding groundwater. This aspect deserves further study particularly in the longer-term. In addition, during weathering of the ash and deposition of organic matter during plant growth, a soil will form with properties vastly different to that of the parent ash. In turn, this will influence the effect that the disposal site has on the surrounding environment. Nevertheless, the effects of ash weathering and organic matter accumulation over time on the chemical, physical and biological properties of the developing ash-derived soil are not well understood and require further study. 相似文献
93.
Govil PK Sorlie JE Murthy NN Sujatha D Reddy GL Rudolph-Lund K Krishna AK Rama Mohan K 《Environmental monitoring and assessment》2008,140(1-3):313-323
Studies on quantitative soil contamination due to heavy metals were carried out in Katedan Industrial Development Area (KIDA),
south of Hyderabad, Andhra Pradesh, India under the Indo-Norwegian Institutional Cooperation Programme. The study area falls
under a semi-arid type of climate and consists of granites and pegmatite of igneous origin belonging to the Archaean age.
There are about 300 industries dealing with dyeing, edible oil production, battery manufacturing, metal plating, chemicals,
etc. Most of the industries discharge their untreated effluents either on open land or into ditches. Solid waste from industries
is randomly dumped along roads and open grounds. Soil samples were collected throughout the industrial area and from downstream
residential areas and were analysed by X-ray Fluorescence Spectrometer for fourteen trace metals and ten major oxides. The
analytical data shows very high concentrations of lead, chromium, nickel, zinc, arsenic and cadmium through out the industrial
area. The random dumping of hazardous waste in the industrial area could be the main cause of the soil contamination spreading
by rainwater and wind. In the residential areas the local dumping is expected to be the main source as it is difficult to
foresee that rain and wind can transport the contaminants from the industrial area. If emission to air by the smokestacks
is significant, this may contribute to considerable spreading of contaminants like As, Cd and Pb throughout the area. A comparison
of the results with the Canadian Soil Quality Guidelines (SQGL) show that most of the industrial area is heavily contaminated
by As, Pb and Zn and local areas by Cr, Cu and Ni. The residential area is also contaminated by As and some small areas by
Cr, Cu, Pb and Zn. The Cd contamination is detected over large area but it is not exceeding the SQGL value. Natural background
values of As and Cr exceed the SQGL values and contribute significantly to the contamination in the residential area. However,
the availability is considerably less than anthropogenic contaminants and must therefore be assessed differently. The pre-
and post-monsoon sampling over two hydrological cycles in 2002 and 2003 indicate that the As, Cd and Pb contaminants are more
mobile and may expect to reach the groundwater. The other contaminants seem to be much more stable. The contamination is especially
serious in the industrial area as it is housing a large permanent residing population. The study not only aims at determining
the natural background levels of trace elements as a guide for future pollution monitoring but also focuses on the pollution
vulnerability of the watershed. A plan of action for remediation is recommended. 相似文献
94.
Fecal source tracking by antibiotic resistance analysis on a watershed exhibiting low resistance 总被引:2,自引:0,他引:2
The ongoing development of microbial source tracking has made it possible to identify contamination sources with varying accuracy,
depending on the method used. The purpose of this study was to test the efficiency of the antibiotic resistance analysis (ARA)
method under low resistance by tracking the fecal sources at Turkey Creek, Oklahoma exhibiting this condition. The resistance
patterns of 772 water-isolates, tested with nine antibiotics, were analyzed by discriminant analysis (DA) utilizing a five-source
library containing 2250 isolates. The library passed various representativeness tests; however, two of the pulled-sample tests
suggested insufficient sampling. The resubstitution test of the library individual sources showed significant isolate misclassification
with an average rate of correct classification (ARCC) of 58%. These misclassifications were explained by low antibiotic resistance
(Wilcoxon test P < 0.0001). Seasonal DA of stream E. coli isolates for the pooled sources human/livestock/deer indicated that in fall, the human source dominated (P < 0.0001) at a rate of 56%, and that human and livestock respective contributions in winter (35 and 39%), spring (43 and
40%), and summer (37 and 35%) were similar. Deer scored lower (17–28%) than human and livestock at every season. The DA was
revised using results from a misclassification analysis to provide a perspective of the effect caused by low antibiotic resistance
and a more realistic determination of the fecal source rates at Turkey Creek. The revision increased livestock rates by 13–14%
(0.04 ≤ P ≤ 0.06), and decreased human and deer by 6–7%. Negative misclassification into livestock was significant (0.04 ≤ P ≤ 0.06). Low antibiotic resistance showed the greatest effect in this category. 相似文献
95.
Modelling vegetation greenness responses to climate variability in a Mediterranean terrestrial ecosystem 总被引:2,自引:0,他引:2
Accurate knowledge of the quality and environmental impact of the highway runoff in Pear River Delta, South China is required
to assess this important non-point pollution source. This paper presents the quality characterization and environmental impact
assessment of rainfall runoff from highways in urban and rural area of Guangzhou, the largest city of Pear River Delta over
1 year’s investigation. Multiple regression and Pearson correlation analysis were used to determine influence of the rainfall
characteristics on water quality and correlations among the constituents in highway runoff. The results and analysis indicates
that the runoff water is nearly neutral with low biodegradability. Oil and grease (O&G), suspended solids (SS) and heavy metals
are the dominant pollutants in contrast to the low level of nutrient constituents in runoff. Quality of highway runoff at
rural site is better than that of at urban site for most constituents. Depth and antecedent dry period are the main rainfall
factors influencing quality of highway runoff. The correlation patterns among constituents in highway runoff at urban site
are consistent with their dominant phases in water. Strong correlations (r ≥ 0.80) are found among chemical oxygen demand (COD), total phosphorus, Cu and Zn as well as conductivity, nitrate nitrogen
and total nitrogen. O&G, COD, SS and Pb in highway runoff at urban site substantially exceed their concentrations in receiving
water of Pear River. The soil directly discharged by highway runoff at rural site has contaminated seriously by heavy metals
in surface layer accompanying with pH conversion from original acidic to alkaline at present. 相似文献
96.
广西一个典型矿业镇环境中重金属污染分析 总被引:2,自引:0,他引:2
广西河池市是我国重要的有色金属基地.以该市一个典型的矿业镇作为研究对象,采集了该镇周围23个旱地土壤样品,并在镇里布设两个大气采样点采集了可吸入颗粒物(PM10)样品,运用ICP-MS分析了样品中20种金属元素的含量,采用地积指数法判定旱地土壤和可吸入颗粒物中污染元素及来源.结果表明,这些与人们生活密切的环境介质(旱地土,可吸入颗粒物)均受到了多种重金属元素的复合污染,其共同的污染元素有Cd、As、Sb、Pb、Xn、Cu,而其中致癌元素Cd和As污染最为突出.大气可吸入颗粒物与旱地土壤中各污染元素的污染强度排序相同,均为Cd>As>Sb>Pb>Zn>Cu.经过现场调查和识别,污染源主要来自当地开放性运矿产生的扬尘所致.因此加强该地区矿石运输管理是保护该地区耕地和人群健康的需要. 相似文献
97.
Paz-Alberto AM Sigua GC Baui BG Prudente JA 《Environmental science and pollution research international》2007,14(7):498-504
Background, Aims and Scope The global problem concerning contamination of the environment as a consequence of human activities is increasing. Most of
the environmental contaminants are chemical by-products and heavy metals such as lead (Pb). Lead released into the environment
makes its way into the air, soil and water. Lead contributes to a variety of health effects such as decline in mental, cognitive
and physical health of the individual. An alternative way of reducing Pb concentration from the soil is through phytoremediation.
Phytoremediation is an alternative method that uses plants to clean up a contaminated area. The objectives of this study were:
(1) to determine the survival rate and vegetative characteristics of three grass species such as vetivergrass, cogongrass
and carabaograss grown in soils with different Pb levels; and (2) to determine and compare the ability of the three grass
species as potential phytoremediators in terms of Pb accumulation by plants.
Methods The three test plants: vetivergrass (Vetiveria zizanioides L.); cogongrass (Imperata cylindrica L.); and carabaograss (Paspalum conjugatum L.) were grown in individual plastic bags containing soils with 75 mg kg−1 (37.5 kg ha−1) and 150 mg kg−1 (75 kg ha−1) of Pb, respectively. The Pb contents of the test plants and the soil were analyzed before and after experimental treatments
using an atomic absorption spectrophotometer. This study was laid out following a 3 × 2 factorial experiment in a completely
randomized design.
Results On the vegetative characteristics of the test plants, vetivergrass registered the highest whole plant dry matter weight (33.85–39.39
Mg ha−1). Carabaograss had the lowest herbage mass production of 4.12 Mg ha−1 and 5.72 Mg ha−1 from soils added with 75 and 150 mg Pb kg−1, respectively. Vetivergrass also had the highest percent plant survival which meant it best tolerated the Pb contamination
in soils. Vetivergrass registered the highest rate of Pb absorption (10.16 ± 2.81 mg kg−1). This was followed by cogongrass (2.34 ± 0.52 mg kg−1) and carabaograss with a mean Pb level of 0.49 ± 0.56 mg kg−1. Levels of Pb among the three grasses (shoots + roots) did not vary significantly with the amount of Pb added (75 and 150
mg kg−1) to the soil.
Discussion Vetivergrass yielded the highest biomass; it also has the greatest amount of Pb absorbed (roots + shoots). This can be attributed
to the highly extensive root system of vetivergrass with the presence of an enormous amount of root hairs. Extensive root
system denotes more contact to nutrients in soils, therefore more likelihood of nutrient absorption and Pb uptake. The efficiency
of plants as phytoremediators could be correlated with the plants’ total biomass. This implies that the higher the biomass,
the greater the Pb uptake. Plants characteristically exhibit remarkable capacity to absorb what they need and exclude what
they do not need. Some plants utilize exclusion mechanisms, where there is a reduced uptake by the roots or a restricted transport
of the metals from root to shoots. Combination of high metal accumulation and high biomass production results in the most
metal removal from the soil.
Conclusions The present study indicated that vetivergrass possessed many beneficial characteristics to uptake Pb from contaminated soil.
It was the most tolerant and could grow in soil contaminated with high Pb concentration. Cogongrass and carabaograss are also
potential phytoremediators since they can absorb small amount of Pb in soils, although cogongrass is more tolerant to Pb-contaminated
soil compared with carabaograss. The important implication of our findings is that vetivergrass can be used for phytoextraction
on sites contaminated with high levels of heavy metals; particularly Pb.
Recommendations and Perspectives High levels of Pb in localized areas are still a concern especially in urban areas with high levels of traffic, near Pb smelters,
battery plants, or industrial facilities that burn fuel ending up in water and soils. The grasses used in the study, and particularly
vetivergrass, can be used to phytoremediate urban soil with various contaminations by planting these grasses in lawns and
public parks.
ESS-Submission Editor: Dr. Willie Peijnenburg (wjgm.peijnenburg@rivm.nl) 相似文献
98.
俚岛湾海域砷的分布特征及污染评价 总被引:1,自引:1,他引:0
以威海俚岛湾养殖区为研究对象,调查研究了俚岛湾海域表层海水和沉积物中总砷的分布特征,并综合评价了砷的污染状况及潜在生态风险。俚岛湾海域表层海水总砷浓度为1.78~2.78μg/L,平均浓度为2.20μg/L,比大洋水略高,俚岛湾海域海水水质较好,未受到砷污染;海水中砷的季节变化为夏季较高、秋冬季基本稳定、春季最低。俚岛湾海域表层沉积物中砷的平面分布呈现出由近岸向远岸降低的趋势,砷含量的年际变化甚微,基本保持稳定的水平;采用潜在生态风险指数法和重金属质量基准法对沉积物进行评价。评价结果表明,该海域表层沉积物中砷污染水平较低,属于低潜在生态风险。 相似文献
99.
以碳酸镁为吸附剂,在镉离子初始浓度为0~6 mmol/L,初始pH值为4和7的条件下,研究了碳酸镁与镉离子的吸附与沉淀作用。结果表明,由于碳酸镁的溶解及与体系中氢离子的中和,碳酸镁—镉体系的最终pH值为10.4左右;体系的平衡pH值随着镉离子初始浓度的增加而减小;体系中镉的平衡浓度随着初始镉离子浓度的增加缓慢上升;碳酸镁对镉的吸附等温线为折线型,不符合Freundlich和Langmuir模型,符合伪二阶吸附动力学模型。结合碳酸镁吸附镉前后固相表征的结果,说明碳酸镁与镉离子的作用机制随着镉离子浓度的增加,从离子交换发展为离子交换和表面配位反应并存,最后表现为表面沉淀。 相似文献
100.
为查明华东某铀矿区稻米中放射性核素铀污染现状及健康风险问题,测定铀矿区和对照区共136件稻米样品中放射性核素U含量,采用单因子污染指数法评价放射性铀污染,并开展U元素健康风险评价。结果表明:(1)研究区稻米中U含量平均值为1.46 ng·g~(–1),各亚区稻米中U含量平均值从大到小顺序为:开采矿井区水冶场区含矿未采区废弃矿井区江西省背景值对照区;(2)稻米单因子污染指数为1.25,属于轻度污染。其中,开采矿井区和水冶厂区为轻度污染,废弃矿井区和对照区未受污染;(3)首次计算提出江西省大米U元素致癌风险最大斜率系数为1.04×10~3(d·kg)·mg~(–1)。各亚区稻米中成人和儿童致癌风险指数高低顺序均为:开采矿井区水冶厂区含矿未采区废弃矿井区对照区。儿童直接饮食稻米具有一定的致癌风险;开采矿井区和水冶厂区的成人存在一定致癌风险,含矿未采区和废弃矿井区以及对照区均无致癌风险。 相似文献