全文获取类型
收费全文 | 255篇 |
免费 | 28篇 |
国内免费 | 151篇 |
专业分类
安全科学 | 19篇 |
废物处理 | 48篇 |
环保管理 | 18篇 |
综合类 | 222篇 |
基础理论 | 59篇 |
污染及防治 | 63篇 |
评价与监测 | 4篇 |
社会与环境 | 1篇 |
出版年
2024年 | 1篇 |
2022年 | 8篇 |
2021年 | 11篇 |
2020年 | 14篇 |
2019年 | 13篇 |
2018年 | 8篇 |
2017年 | 11篇 |
2016年 | 11篇 |
2015年 | 22篇 |
2014年 | 22篇 |
2013年 | 46篇 |
2012年 | 35篇 |
2011年 | 21篇 |
2010年 | 24篇 |
2009年 | 22篇 |
2008年 | 22篇 |
2007年 | 24篇 |
2006年 | 21篇 |
2005年 | 15篇 |
2004年 | 11篇 |
2003年 | 8篇 |
2002年 | 10篇 |
2001年 | 11篇 |
2000年 | 5篇 |
1999年 | 11篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1995年 | 5篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有434条查询结果,搜索用时 15 毫秒
141.
水体中Ca2+湖泊沉积物磷吸附特征的影响 总被引:4,自引:1,他引:3
对于高钙质湖泊来说,水体中钙离子对沉积物磷吸附特征影响非常重要.文章选取北方典型湖泊沉积物进行了吸附实验并通过Langmuir等温吸附模型线性拟合,研究了沉积物的等温吸附特性及水溶液中钙离子浓度对沉积物吸附的影响.沉积物最大吸附量(Qmax)在208.77~450.45 g/kg之间.Qmax与沉积物中Fe和Al的含量... 相似文献
142.
143.
144.
烟气脱硫脱硝一体化技术已成为当前大气污染防治领域的研究热点,其中氧化剂液相吸收法极有可能率先实现产业化。文章理论上首次提出了次氯酸钙溶液脱硫脱硝一体化技术,利用热力学函数计算分析了脱硫脱硝反应的方向和限度,通过SO2和NO平衡分压计算推导了污染物的脱除效率,考察标准吉布斯函数变分析了该技术的优势。结果表明:脱硫脱硝反应的标准吉布斯函数变分别为-614.55和-888.21 kJ/mol,热力学角度上完全可行,反应限度极深,优于文献中介绍的尿素、NaClO2、KMnO4/NaOH溶液吸收法和臭氧结合氨水吸收法。同时,SO2和NO平衡分压很小,说明次氯酸钙溶液几乎可以完全脱除烟气中的SO2和NOX。 相似文献
145.
Xiang ZHANG Xiaogang GU Shuguang LU Zhouwei MIAO Minhui XU Xiaori FU Muhammad DANISH Mark L. BRUSSEAU Zhaofu QIU Qian SUI 《Frontiers of Environmental Science & Engineering》2016,10(3):502-512
Trichloroethene (TCE) degradation by Fe(III)-activated calcium peroxide (CP) in the presence of citric acid (CA) in aqueous solution was investigated. The results demonstrated that the presence of CA enhanced TCE degradation significantly by increasing the concentration of soluble Fe(III) and promoting H2O2 generation. The generation of HO? and O2-? in both the CP/Fe(III) and CP/Fe(III)/CA systems was confirmed with chemical probes. The results of radical scavenging tests showed that TCE degradation was due predominantly to direct oxidation by HO?, while O2-? strengthened the generation of HO? by promoting Fe(III) transformation in the CP/Fe(III)/CA system. Acidic pH conditions were favorable for TCE degradation, and the TCE degradation rate decreased with increasing pH. The presence of Cl-, HCO3-, and humic acid (HA) inhibited TCE degradation to different extents for the CP/Fe(III)/CA system. Analysis of Cl- production suggested that TCE degradation in the CP/Fe(III)/CA system occurred through a dechlorination process. In summary, this study provided detailed information for the application of CA-enhanced Fe(III)-activated calcium peroxide for treating TCE contaminated groundwater. 相似文献
146.
Diuron samples at 40mg/L concentration were photolyzed with ultraviolet lamps and with natural sunlight to determine if data from ultraviolet lamp photolysis could be used to predict results from sunlight photolysis. Seven photoproducts were identified from the photolysis experiments. The identified photoproducts and the photoproduct yields were essentially the same for the two light sources. 相似文献
147.
Blood level of calcium fractions (ionized and bound), phosphates, magnesium and albumin were measured in non‐insulin dependent diabetic patients (NIDD). Results were compared with healthy controls to elucidate the pathogenesis of probable changes of these elements. Total ionized calcium and magnesium showed significant decrease (p<0.001, p<0.05 and p<0.05) respectively. Phosphates showed non‐significant decrease while albumin reported nearly similar results. Positive correlation between inorganic phosphates and ionized calcium (r = 0.48, p<0.05) was observed only in healthy control group, not in diabetics. This may be attributed to alteration of ions excretions under diabetic condition through unknown mechanism. Additive increase of heparin sodium units in vitro to normal blood resulted in progressive fall in ionized calcium. Significant decrease was only observed upon addition of higher unit (5IU/ml). This must be taken into consideration biochemically for plasma determination of ionized calcium. 相似文献
148.
Hacer Dogan 《毒物与环境化学》2013,95(3):482-499
Composite adsorbent materials containing calcium alginate, clinoptilolite, and coal-derived humic acid were prepared. Humic acid (HA), clinoptilolite (CL), alginate (AL), alginate-entrapped humic acid (AL/HA), clinoptilolite (AL/CL), and humic acid/clinoptilolite (AL/HA/CL) samples were characterized. The effectiveness of the samples as adsorbents for the removal of cadmium (Cd), mercury (Hg), and lead (Pb) were studied in a series of batch-adsorption experiments. For the AL, AL/HA, AL/CL, and AL/HA/CL adsorbents, uptake versus time data were evaluated using two kinetic models, a linear and a non-linear pseudo-first-order and a pseudo-second-order model. The data for each metal ion on all adsorbents showed good correspondence with the pseudo-second-order kinetic model. The equilibrium data were fitted to Langmuir, Freundlich, Dubinin–Radushkevich, and Temkin isotherm models. The results show that a non-linear method seems more appropriate for obtaining isotherm parameters. The non-linear Freundlich and Langmuir models for Pb and Hg produced a best fit with high R 2 value (0.99). For HA adsorbent, the equilibrium data for Cd removal better fit to the non-linear Dubinin–Radushkevich isotherm. 相似文献
149.
Abstract Reef blocks made from stabilized oil ash were taken from the sea after five years in the ocean to examine the chemical behaviour of calcium. Experiments included (1) determination of the calcium leaching rate and a comparison with the rate for unexposed blocks to test the validity of a diffusion model for predicting long term (5 years) leaching rates, (2) determination of the effect of biological cover (shell) on the leaching rate, (3) determination of the leaching rate of the core of exposed reef blocks, (4) determination of the calcium content in ‘ring areas’ - regions of discoloration observed in sectioned exposed reef blocks, and (5) determination of the leachable fraction of the total calcium in exposed reef blocks. Results showed the presence of a pronounced calcium discontinuity zone located 3–7 cm from the outside surface of the reef blocks. Cumulated calcium release rates ranged from 2.81–3.14 μmol cm?2 day?1 for original unexposed reef blocks and the core of exposed (in the ocean for five years) blocks, respectively, to 0.47–0.50 μmol cm?2 day?1 for outside (facing sea water) surfaces of exposed reef blocks. Tank leaching studies also showed that the presence or absence of hard biological cover (shells) had little or no effect on the calcium release rate. the diffusion model normally used in modelling the chemical behaviour of calcium cannot be used to predict the long term (five years) leaching of calcium. the core of the exposed blocks released calcium at a rate similar to new, unexposed reef block material. Overall, it appears that the calcium discontinuity zone is probably responsible for restricting the release of calcium and hence the failure of the diffusion model. 相似文献
150.
Normal female rats of Wistar strain (Rattus norvegicus) weighing between 150–200 g were treated with fluoride (Fl) contaminated drinking water (FW, 5.8 ppm), vitamin C (6 mg) and vitamin C (6 mg) + D (6 mg once a week) + calcium (6 mg) for 30 days. Fl water treatment to rats produced reduction in weights of ovaries, uterus, vagina, kidneys, and adrenal glands, circulating levels of estrogen, number of litters, fertility rate, and altered tissue and serum biochemistry compared to control rats. However, cholesterol concentrations of ovaries and adrenals increased significantly. The above altered parameters were restored partially/completely after exogenous feeding with vitamin C and vitamins (C + D) and calcium. The data suggest that Fl-induced adverse effects on reproductive and other organs in female rats, whereas vitamin C, vitamin D and calcium treatment ameliorated Fl toxicity. Therefore, vitamins (C and D) and calcium play an important role in prophylactic treatment of fluorosis. 相似文献