活性炭吸附与生物活性炭脱臭效果的比较研究

针对污水收集与处理系统中恶臭气体的组成与特性,比较分析不同情况下活性炭吸附与生物活性炭的脱臭效果。当干活性碳总处理气量达到1.3m~3/g时,出现穿透。将吸附饱和的活性炭填料塔转为生物滴滤反应器后,仍能较快的实现挂膜生长,达到满意的处理效果。直接运行的生物活性炭滴滤器对H_2S的处理效率在95％以上,并具有较强的恢复能力。H_2S平均出口浓度为0.052mg/m~3。循环液pH值与盐度在一定范围内对系统影响不大。     

Can Forest-protection carbon projects improve rural livelihoods? Analysis of the Noel Kempff Mercado climate action project,Bolivia

We studied the Noel KempffMercado Climate Action Project (NKMCAP),Bolivia, to assess whether forestprotection carbon (C) projects cansignificantly benefit local people. Wehypothesized that forest protection canonly securely deliver C if significantstakeholders are meaningfully andtransparently involved, traditional orcustomary rights are recognized and theirloss compensated for, and there are directlinkages between conservation anddevelopment objective. Our researchfocused on 53 members of the communities ofFlorida, Porvenir and Piso Firme and 36secondary stakeholders. In each of thevillages we held half-day meetings withcommunity leaders, complemented bysemi-structured one-hour interviews with 5,10, and 7 families, representing 20%, 10%and 8% of each community. The long-termimpact of the NKMCAP on the localcommunities may well be positive. However,in the short run, certain sections of thelocal communities are financially poorer. Forest protection projects clearly have thepotential to sequester C, protectbiodiversity and simultaneously contributeto sustainable rural development, but ifthey really are to improve rurallivelihoods, they must be designed andimplemented carefully and participatively.     

活性炭性质对其吸附水中硝基苯性能的影响

通过对活性炭进行HNO3氧化及热处理改性,研究了活性炭性质对其吸附硝基苯性能的影响.以低温液氮(N2/77 K)吸附测定活性炭的比表面积和孔容、孔径分布;以Boehm滴定、零电荷点pHPZC的测定及元素分析定量表征活性发表面含氧官能团变化.结果表明:经改性后,活性炭比表面积及总孔容略有减小,表面性质发生较大变化.改性活性炭对硝基苯的吸附容量明显改变,吸附容量大小依次为:AC1′＞AC0′＞AC0＞AC1.经硝酸氧化后,比表面积下降、存在过多表面含氧官能团是导致AC1吸附硝基苯能力降低的主要原因;而AC1'表面适量酚羟基所提供的氢键吸附是其对硝基苯吸附量增加的主要原因.     

Climate Change and Energy Technologies

The long time scale of the climate change problem and the inherent nature of the carbon cycle bring important implications for present technology development efforts. Even if major technology improvements are achieved for non-carbon-emitting technologies such as energy-intensity improvements, wind, solar, biomass, and nuclear over the course of the 21^st century, most examinations of potential future greenhouse emissions conclude that additional technology development will be required to stabilize greenhouse gas concentrations. The evelopment of an expanded suite of technologies including carbon capture and disposal, hydrogen systems and biotechnology hold the potential to dramatically reduce the cost of stabilizing greenhouse gas concentrations. This paper examines these technologies in the context of a global integrated assessment model of energy, agriculture, land-use, economics, and carbon cycle processes.     

腕足类生物壳体在沉积、成岩过程中同位素平衡问题研究

综合分析了现代腕足类生物壳体方解石中的C、O同位素特征，以及有关古生代腕足类生物壳体方解石构造和地球化学研究成果，分析结果证明：只有那些无发光性特点、无胶结和溶蚀构造特点、有较好纤维构造特点、含高Sr、Na和低Mn、Fe（Mg）的第二层腕足类生物壳体方解石的δ18O值不受成岩作用影响；而原始层和壳体中的特殊部位如铰合轴、腕骨、茎孔、交互面、肌痕等在沉积、成岩过程中与海水处于非同位素平衡状态。     

温泉宾馆室内PM_(10),PM_(2.5),CO_2和~(222)Rn的研究

对广东省 4座温泉宾馆室内外氡(222Rn)浓度和温泉水氡浓度进行研究,同时利用便携式探测器对室内外 PM10,PM2.5,CO2和CO 等污染物暴露水平进行直接测定.结果表明,温泉宾馆室内使用温泉水时氡浓度明显高于广东省室内平均氡浓度.除 CO 外,室内 PM10,PM2.5 和CO2 浓度都较高,其中 PM10 和 CO2 的超标率分别达到 67%和 89%.说明温泉宾馆室内不仅存在一般性污染物,而且存在高浓度的 Rn. 222     

活性炭厌氧流化床处理毒性有机废水存在的问题与对策

活性炭厌氧流不处理毒性有机废水存在问题，对含有活性炭能吸附而生物难降解成份的废水，通过定期替换少量活性炭、能维持工艺的稳定运行。     

生物活性炭处理废水中有机物的研究探讨

生物活性炭(BAC)是一种处理有机废水的有效方法。现以BAC处理废水中的酚和甲醇为例,综述BAC处理废水中有机物的机理和影响因素。并通过生物活性炭吸附降解四氯乙烯(PCE)的综合模型得到BAC作用与吸附和生物降解的关系。最后简单介绍了BAC中活性炭与微生物的选择。     

In-situ-reduced synthesis of cyano group modified g-C3N4/CaCO3 composite with highly enhanced photocatalytic activity for nicotine elimination

Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C₃N₄ to solve this problem a simple and safe in-situ reduction method. g-C₃N₄/CaCO₃ was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO₃. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C₃N₄. The successful combination of g-C₃N₄ and CaCO₃ and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O₂⁻ and ¹O₂ in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air.     

超临界二氧化碳流体萃取土壤中有机污染物的研究进展

就近年来人们利用超临界二氧化碳流体对有机污染物污染的土壤所做的研究工作以及所取得的成果进行了总结。