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901.
902.
Athiyanam Venkatesan Ramya Manoj Balachandran 《Frontiers of Environmental Science & Engineering》2022,16(3):27
903.
Chen Xing Daihui Yang Yan Zhang Tian Sun Junfei Duan Hussein A.Younus Shiguo Zhang 《绿色能源与环境(英文)》2022,7(1):43-52
Heteroatom-doped meso/micro-porous carbon materials are conventionally produced by harsh carbonization under an inert atmosphere involving specific precursors, hard/soft templates, and heteroatom-containing agents. Herein, we report a facile synthesis of N and O co-doped meso/micro-porous carbon (NOMC) by template-free carbonization of a small-molecule precursor in a semi-closed system. The semi-closed carbonizaiton process yields hydrophilic NOMCs with large surface area in a high yield. The porous structure as well as the elemental composition of NOMCs can be modulated by changing the holding time at a particular temperature. NOMCs as metal-free heterogeneous catalysts can selectively oxidize benzyl alcohol and its derivatives into aldehydes/ketones with>85%conversion in aqueous solution, which is much higher than that of the control sample obtained in tube furnace (21%conversion), mainly due to their high N content, high percentage of pyridinic N, and large surface area. The presence of O-containing moieties also helps to improve the hydrophilicity and dispersion ability of catalysts and thus facilitates the mass transfer process during aqueous oxidation. The NOMC catalysts also dispayed excellent activity for a wide range of substrates with a selectivity of>99%. 相似文献
904.
为进一步提高活性炭对VOCs的吸附性能和热安全性,采用铵盐类离子液体改性原始活性炭,优化其理化性质。结果表明:改性活性炭表面生成新的无机盐化合物,C=O、-OH、C-O、-COOH和C-S基团增加;孔隙结构增多且分布均匀,比表面积及微孔体积增大;改性后活性炭对甲苯的吸附量提高3.14倍,吸附效率明显提升;在固定碳的燃烧阶段,改性活性炭活化能为54.44 kJ·mol-1,是改性前活性炭的1.38倍,活化能增大,物质稳定性增强;当粒径为120~150目及200目以上时,改性前后活性炭的自燃温度分别从328.4 ℃、319.3 ℃增长至355.1 ℃、345.7 ℃。因此,负载季铵盐离子液体可有效提高活性炭吸附性能和热安全性,研究结果可为优化VOCs处理工艺提供参考。 相似文献
905.
崇明东滩大型底栖动物食源的稳定同位素示踪 总被引:1,自引:0,他引:1
利用稳定同位素示踪技术,对崇明东滩盐沼湿地夏季不同生境大型底栖动物的食物来源和营养结构进行了初步研究。结果显示,表层沉积有机质稳定碳、氮同位素组成分别在-21.3‰~-24.2‰、4.6‰~5.6‰,不同生境下存在一定差异。植物体各组织的同位素值存在差异,在判别食物来源时需要注意,不能简单地以植物叶片值来代替整个植株。大型底栖动物的δ13C值为-14.7‰~-23.6‰,表现出食物来源的差异。总体上说,湿地优势植物的活植物体不是大型底栖动物的主要食物来源,沉积有机质是大部分底栖消费者的食物基础。底栖动物的氮同位素能较好地反映其食性和营养级,计算出崇明东滩大型底栖动物营养级在2.0~3.7,为一级消费者和二级消费者。 相似文献
906.
907.
Cho ST Tsai SH Ravindran A Selvam A Yang SS 《Environmental geochemistry and health》2008,30(3):255-272
To investigate the seasonal variations of microbial ecology in grassland of Tatachia forest, soil properties, microbial populations,
microbial biomass, and 16S rDNA clone library analysis were determined. The soil had temperatures 6.6–18.4°C, pH 3.6–5.1,
total organic carbon 1.11–10.68%, total nitrogen 0.18–0.78%, and C/N ratios 3.46–20.55. Each gram of dry soil contained bacteria,
actinomycetes, fungi, cellulolytic, phosphate-solubilizing microbes, and nitrogen-fixing microbes 4.54 × 104 to 3.79 × 107, 3.43 × 102 to 2.17 × 105, 5.74 × 103 to 3.76 × 106, 1.97 × 103 to 1.34 × 106, 8.49 × 102 to 5.59 × 105, and 3.86 × 102 to 3.75 × 105 CFU, respectively. Each gram of soil contained 117–2,482 μg of microbial biomass carbon, 23–216 μg of microbial biomass nitrogen
and 9–29 μg of DNA. The microbial populations, microbial biomass, and DNA decreased stepwise with the depth of soil, and they
had low values in winter seasons. The microbial populations, microbial biomass carbon, microbial biomass nitrogen, and DNA
at the BW2 horizon were 8.42–17.84, 19.26–64.40, 16.84–61.11, and 31.03–46.26% of those at the O horizon, respectively. When
analyzing 16S rDNA library, members of Proteobacteria, Acidobacteria, Actinobacteria, Bacteroidetes, Chloroflexi, Firmicutes,
candidate division TM1, candidate division TM7, Gammatimonadetes, and Verrucomicrobia were identified. Members of Proteobacteria
(44.4%) and Acidobacteria (33.3%) dominated the clone libraries. Within the phylum Proteobacteria, α-, β-, and γ-Proteobacteria
were most numerous, followed by δ-Proteobacteria. 相似文献
908.
909.
Global emissions trading allows for agricultural measures to be accounted for the carbon sequestration in soils. The Environmental Policy Integrated Climate (EPIC) model was tested for central European site conditions by means of agricultural extensification scenarios. Results of soil and management analyses of different management systems (cultivation with mouldboard plough, reduced tillage, and grassland/fallow establishment) on 13 representative sites in the German State Baden-Württemberg were used to calibrate the EPIC model. Calibration results were compared to those of the Intergovernmental Panel on Climate Change (IPCC) prognosis tool. The first calibration step included adjustments in (a) N depositions, (b) N2-fixation by bacteria during fallow, and (c) nutrient content of organic fertilisers according to regional values. The mixing efficiency of implements used for reduced tillage and four crop parameters were adapted to site conditions as a second step of the iterative calibration process, which should optimise the agreement between measured and simulated humus changes. Thus, general rules were obtained for the calibration of EPIC for different criteria and regions. EPIC simulated an average increase of +0.341 Mg humus-C ha−1 a−1 for on average 11.3 years of reduced tillage compared to land cultivated with mouldboard plough during the same time scale. Field measurements revealed an average increase of +0.343 Mg C ha−1 a−1 and the IPCC prognosis tool +0.345 Mg C ha−1 a−1. EPIC simulated an average increase of +1.253 Mg C ha−1 a−1 for on average 10.6 years of grassland/fallow establishment compared to an average increase of +1.342 Mg humus-C ha−1 a−1 measured by field measurements and +1.254 Mg C ha−1 a−1 according to the IPCC prognosis tool. The comparison of simulated and measured humus C stocks was r2 ≥ 0.825 for all treatments. However, on some sites deviations between simulated and measured results were considerable. The result for the simulation of yields was similar. In 49% of the cases the simulated yields differed from the surveyed ones by more than 20%. Some explanations could be found by qualitative cause analyses. Yet, for quantitative analyses the available information from farmers was not sufficient. Altogether EPIC is able to represent the expected changes by reduced tillage or grassland/fallow establishment acceptably under central European site conditions of south-western Germany. 相似文献
910.
This paper introduces an innovative modelling strategy aimed at simulating the main terms of net forest carbon budget (net primary production, NPP and net ecosystem exchange, NEE) in Tuscany (Central Italy). The strategy is based on the preliminary calibration and application of parametric and bio-geochemical models (C-Fix and BIOME-BGC, respectively), which simulate the behaviour of forest ecosystems close to equilibrium condition (climax). Next, the ratio of actual over-potential tree volume is computed as an indicator of ecosystem distance from climax and is combined with the model outputs to estimate the NPP and NEE of real forests. The per-pixel application of the new modelling strategy was made possible by the collection of several data layers (maps of forest type and volume, daily meteorological data and monthly normalized difference vegetation index (NDVI) images for the years 1999–2003) which served to characterize the eco-climatic and forest features of the region. The obtained estimates of forest NPP and NEE were evaluated against ground measurements of accumulated woody biomass and net carbon exchange. The results of these experiments testify the good potential of the proposed strategy and indicate some problem areas which should be the subject of future research. 相似文献