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101.
采用自制的负载型CuO-ZnO-CeO2/γ-Al2O3催化剂,常温常压下通过紫外辐照-催化湿式氧化技术处理酸性大红GR模拟染料废水。考察了催化剂加入量、H2O2加入量、废水pH、反应时间、初始酸性大红GR质量浓度等对废水脱色率的影响。实验得到最佳工艺条件为初始酸性大红GR质量浓度200mg/L,催化剂加入量10.0g/L,H2O2加入量2.0mL/L,废水pH4,反应时间2h。最佳工艺条件下废水脱色率达99.33%。 相似文献
102.
Spent hydroprocessing catalysts from refineries have been classified as hazardous solid waste by the United States Environmental Protection Agency (USEPA), refiners must find a viable but economical solution to solve this serious environmental issue. Catalyst rejuvenation is an attractive option for minimizing the environmental problems associated with spent catalysts. In this study, a preliminary design for such a process and the corresponding economic analysis are performed to assess the proposed catalyst rejuvenation process for metal-fouled spent catalysts generated in residue hydroprocessing units. The scenarios used in the economic assessment are based on three options of process synthesis and two operator modes. It is found that the option of rejuvenating medium and lightly fouled spent catalyst produced by the refinery will be the best solution for refiners, both environmentally and economically. 相似文献
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本文介绍了炭催化剂吸附剂标准物质的研制过程。对标准物质的制备技术、均匀性检验、稳定性考察及定值和不确定度进行了逐项分析。采用活性炭浸渍、煅烧技术制得炭催化剂吸附剂标准物质。试验结果表明,该标准物质定值结果准确,均匀性、稳定性良好。铜含量的标准值为11.06%,扩展不确定度为0.13%。 相似文献
105.
通过把起相转移作用的聚乙二醇链固载在硅胶上(SiO2-PEG600),再将聚乙稀吡咯烷酮(PVP)络合双金属Pd-Cu(PVP-PdCl2-CuCl2)后负载其中,制成一种新型双负载双金属水相脱卤催化剂PVP-PdCl2-CuCl2/SiO2-PEG600。以甲酸钠为氢转移试制,在水相中催化有机卤化物脱卤,研究结果表明:反应温度为800℃,Pd∶Cu=2∶1(摩尔比),反应介质pH≈11.7左右时,该催化剂对芳香氯化物及α-氯代酮、酯具有良好的催化脱氯和重复使用性能。 相似文献
106.
杀虫单降解菌的筛选分离与降解特性研究 总被引:8,自引:0,他引:8
从农药厂废水排放沟污泥中分离到一株对杀虫单有较强降解能力的菌株LY-4,经鉴定为巨大芽孢杆菌(Bacillus megaterium)。其生长的最适pH为7,最适温度为30℃。该菌对杀虫单有很强的耐受性,在杀虫单浓度ρ=5000mg/L时,仍能较好地生长并发挥降解作用。当杀虫单初始浓度高于一定值时,一定量的菌剂对杀虫单的降解率随底物浓度的提高而降低,而绝对去除量则随底物浓度的提高而提高。与不加菌的对照相比,加入LY-4后,可使杀虫单浓度在很短的时间内降到很低的水平。图5表1参6 相似文献
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Jurgen Garbrecht Lawrence W. Martz 《Journal of the American Water Resources Association》1993,29(6):909-916
ABSTRACT: An automated extraction of channel network and sub-watershed characteristics from digital elevation models (DEM) is performed by model DEDNM. This model can process DEM data of limited vertical resolution representing low relief terrain. Such representations often include ill-defined drainage boundaries and indeterminate flow paths. The application watershed is an 84 km2 low relief watershed in southwestern Oklahoma. The standard for validation is the network and subwatershed parameters defined by the blue line method on USGS 7.5–minute topographic maps. Evaluation of the generated and validation networks by visual comparisons shows a high degree of correlation. Comparison of selected network parameters (channel length, slope, drainage density, etc.) and of drainage network composition (bifurcation, length, slope, and area ratios) shows that, on the average, the generated parameters are within 5 percent of those derived from the validation network. The largest discrepancies were found for the channel slope values. The results of this application demonstrate that DEDNM effectively addresses network definition problems often encountered in low relief terrain and that it can generate accurate network and subwatershed parameters under those conditions. 相似文献
110.
Travis C Obenshain KR Gunter JT Regens JL Whipple C 《Environmental science and pollution research international》2004,11(5):302-306
GOAL, SCOPE AND BACKGROUND: This paper uses two case studies of U.S. Department of Energy nuclear weapons complex installations to illustrate the integration of expedited site characterization (ESC) and multimedia modeling in the remedial action decision making process. CONCEPTUAL SITE MODELS, MULTIMEDIA MODELS, AND EXPEDITED SITE CHARACTERIZATION: Conceptual site models outline assumptions about contaminates and the spatial/temporal distribution of potential receptors. Multimedia models simulate contaminant transport and fate through multiple environmental media, estimate potential human exposure via specific exposure pathways, and estimate the risk of cancer and non-cancer health outcomes. ESC relies on using monitoring data to quantify the key components of an initial conceptual site model that is modified iteratively using the multimedia model. CASE STUDIES: Two case studies are presented that used the ESC approach: Los Alamos National Laboratory (LANL) and Pantex. LANL released radionuclides, metals, and organic compounds, into canyons surrounding the facility. The Pantex Plant has past waste management operations which included burning chemical wastes in unlined pits, burying wastes in unlined landfills, and discharging plant wastewaters into on-site surface waters. CONCLUSIONS: The case studies indicate that using multimedia models with the ESC approach can inform assessors about what, where, and how much site characterization data needs to be collected to reduce the uncertainty associated with risk assessment. Lowering the degree of uncertainty reduces the time and cost associated with assessing potential risk and increases the confidence that decision makers have in the assessments performed. 相似文献