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301.
化学混凝-催化氧化法处理钻井污水 总被引:22,自引:3,他引:19
由于钻井污水经混凝处理后仍存在COD、色度超标问题,因此需采用其他方法深度处理污水。故采用混凝-催化氧化法工艺处理钻井污水,混凝剂为硫酸铁或聚合硫酸铁,混凝剂加量一般为2000mg/L,初始pH值为3.0~5.0,氧化时间为3h等。通过实验结果可知:该方法完全能满足钻井污水处理的要求,处理后出水可达标外排。化学混凝-催化氧化处理工艺是解决高浓度钻井污水处理COD、色度超标的重要途径,在技术经济上是可行的,具有广阔的应用前景 相似文献
302.
催化剂生产废水铵离子选择交换处理工艺 总被引:2,自引:0,他引:2
用铵离子选择交换工艺对催化剂生产过程排出的含氨氮废水进行处理。考察了再生液中NH3-N浓度、进水NH3-N浓度、进水悬浮物浓度、进水pH、再生液用量等因素对处理效果的影响;探讨了铵离子选择交换床液体空速与出水NH3-N浓度的关系、铵离子交换床总交换容量与进水NH3-N负荷之比与出水NH3-N浓度的关系。 相似文献
303.
Scott N. Miller William G. Kepner Megan H. Mehaffey Mariano Hernandez Ryan C. Miller David C. Goodrich K. Kim Devonald Daniel T. Heggem W. Paul Miller 《Journal of the American Water Resources Association》2002,38(4):915-929
ABSTRACT: Significant land cover changes have occurred in the watersheds that contribute runoff to the upper San Pedro River in Sonora, Mexico, and southeast Arizona. These changes, observed using a series of remotely sensed images taken in the 1970s, 1980s, and 1990s, have been implicated in the alteration of the basin hydrologic response. The Cannonsville subwatershed, located in the Catskill/Delaware watershed complex that delivers water to New York City, provides a contrast in land cover change. In this region, the Cannonsville watershed condition has improved over a comparable time period. A landscape assessment tool using a geographic information system (GIS) has been developed that automates the parameterization of the Soil and Water Assessment Tool (SWAT) and KINEmatic Runoff and EROSion (KINEROS) hydrologic models. The Automated Geospatial Watershed Assessment (AGWA) tool was used to prepare parameter input files for the Upper San Pedro Basin, a subwatershed within the San Pedro undergoing significant changes, and the Cannonsville watershed using historical land cover data. Runoff and sediment yield were simulated using these models. In the Cannonsville watershed, land cover change had a beneficial impact on modeled watershed response due to the transition from agriculture to forest land cover. Simulation results for the San Pedro indicate that increasing urban and agricultural areas and the simultaneous invasion of woody plants and decline of grasslands resulted in increased annual and event runoff volumes, flashier flood response, and decreased water quality due to sediment loading. These results demonstrate the usefulness of integrating remote sensing and distributed hydrologic models through the use of GIS for assessing watershed condition and the relative impacts of land cover transitions on hydrologic response. 相似文献
304.
IntroductionMontmorilloniteisaclaymineralwithsubstantialisomorphicsubstitution .Mesoporouspillaredmontmorillonitecanbepreparedbyintroducinggallerytemplates ,suchasquaternaryammoniumcationandlongchainamine .Thusformedorgano montmorilloniteshaveimprovedcapa… 相似文献
305.
Four metal oxide catalysts composed of copper (Cu), stannum (Sn), copper-stannum (Cu-Sn) and copper-cerium(Cu-Ce) respectively were prepared by the co-impregnation method, and γ-alumina(γ-Al2O3 ) is selected as support. A first-order kinetics model was established to study the catalytic wet air oxidation of phenol at different temperature when these catalysts were used. The model simulations are good agreement with present experimental data. Results showed that the reaction rate constants can be significantly increased when catalysts were used, and the catalyst of 6% Cu-10% Ce/γ-Al2 O3 showed the best catalytic activity. This is consistent witht he result of catalytic wet air oxidation of phenol and the COD removal can be arrived at 98.2% at temperature 210℃, oxygen partial pressure 3 MPa and reaction time 30 rain. The activation energies of each reaction with different catalysts are nearly equal, which is found to be about 42 kJ/mol and the reaction in this study is proved to be kinetics control. 相似文献
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研究了以废镍铝合金粉(废镍渣)为原料、H2SO4为浸出剂、尿素为沉淀剂制备镍催化剂的方法;考察了Ni浸出条件对其浸出率的影响,并通过催化加氢实验对镍催化剂的活性进行了评价。Ni的浸出条件:w(H2SO4)25%、酸浸时间3h、n(废镍渣):n(H2SO4)=1.0:1.4。在该条件下,Ni的浸出率为92.85%。Ni的回收率在90%以上。催化加氢实验结果表明,在温度120~125℃、压力大于或等于1.2MPa、催化剂用量1%(质量分数)的条件下,可将异丙叉丙酮经一步液相催化加氢反应制备成甲基异丁基甲醇(MBC),异丙叉丙酮转化率为100%,MIBC的收率达99.3%。 相似文献
310.