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171.
为了认识岩溶区石灰土含水介质中化学氧化联合生物降解去除燃油苯系物的效果,以汽油中的苯、甲苯、乙苯和二甲苯(BTEX)作为污染物,通过批实验研究过硫酸盐(PS)联合硝酸盐去除汽油BTEX的效果,并认识不同浓度乙醇(EtOH)存在时带来的影响及化学氧化与反硝化联合修复的可能性.结果表明,在35 d内各组的BTEX去除率均达到91.00%以上,PS化学氧化能有效地去除BTEX.在不含EtOH及含EtOH初始浓度为500和5000 mg·L-1的情况下,BTEX浓度在第65 d时分别为未检出、0.226 mg·L-1、0.243 mg·L-1,去除率分别为99.98%、99.00%、98.70%,其中,苯的去除率分别为99.98%、97.01%、93.32%.随着EtOH浓度的增加,苯的去除受到抑制,EtOH对BTEX的化学氧化具有阻碍作用.石灰土介质中高铁含量对PS具有活化能力,高含量有机质能促进PS分解,并导致pH值回升,出现反硝化作用和硫酸盐还原作用,有利于生物降解作用的恢复. 相似文献
172.
为探究大气污染的特征,于2020年5月—2021年4月在中国西北部的兰州市区采集了总悬浮颗粒物样品227个,利用离子色谱仪、热/光碳分析仪对主要水溶性离子、元素碳(EC)和有机碳(OC)的质量浓度进行了测定.结果显示,兰州地区大气总悬浮颗粒物质量浓度均值为(376.7±974.8)μg·m-3,高于国家环境空气质量二级标准(NAAQS),呈昼低夜高的变化特征主要是由于兰州地区夜间大气多处于静稳状态导致的污染物累积效应.水溶性阴、阳离子按质量浓度排序为NO3->SO42->Cl-、Ca2+>NH4+>Na+>K+>Mg2+,其中二次离子(NO3-、SO42-、NH4+ 相似文献
173.
化工事故应急救援仿真演练系统的实施探讨 总被引:4,自引:1,他引:3
阐述了化工事故应急救援仿真的必要性及其国内外研究进展;提出整个系统的框架并设计系统开发过程的模型;分析了基于高层体系结构(HIA)的仿真系统的开发要点,给出参考开发工具,从而为整个系统开发提供思路. 相似文献
174.
ABSTRACT: Selected studies from the literature were reviewed to determine the extent of knowledge about the relationship between hydrology and wetland ecosystem studies. Wetland studies of chemical input-output relationships have been the most dependent on hydrologic data of all wetland investigations; yet, very few of these studies have attempted to measure all components of a wetland's water balance. Usually, unmeasured components were calculated as the difference between measured inputs and outputs. Ground water frequently was overlooked. Chemical input-output investigations primarily were concerned with determining the amount of input retained in the wetlands. Few studies also included direct measurement of biogeochemical processes within wetlands of elements that were part of simultaneous input-output investigations. The importance of uncertainties in chemical budgets that are due to uncertainties in hydrologic budgets has been addressed in very few wetland investigations. Although many studies have emphasized the importance of hydrology to wetland ecosystem research, few studies have documented this, so that hydrology remains one of the least understood components of wetland ecosystems. 相似文献
175.
Enrique J. La Motta 《Journal of the American Water Resources Association》1995,31(2):207-216
ABSTRACT: This paper presents a discussion of the chemistry of CO2 removal in tray aerators, and different sets of equations that are applicable to several initial water chemical conditions are proposed. These chemical equations and a statistical model to predict the kinetic constant were tested with field data observed by other researchers in pilot units and in a full scale plant. The water temperature in their experiments was around 15°C. 相似文献
176.
用固体力学化学理论研究岩土的力学化学行为——以成都龙泉紫色土为例 总被引:1,自引:0,他引:1
根据固体力学化学理论 ,提出用化学动力学方法研究岩土破坏及滑坡形成的机理 ,并以成都龙泉紫色土为例研究了在力与水协同作用下易滑土层的力学化学行为。实验表明 ,土长期抗剪强度降低的幅度与溶液的pH值有关 ,土的溶解速度与易溶盐含量有关 ,且溶解曲线略呈“S”型。这初步证明了龙泉紫色土破坏的力学 化学效应及其可能存在的自催化趋势。通过实验了解了力与水协同作用导致土破坏的力学化学规律 ,并将定量求解滑面长期抗剪强度与反应机理研究结合起来 ,为定量评价地下水和应力对岩土破坏机理这一滑坡学关键问题打下基础。 相似文献
177.
178.
文章在介绍我国化学工业排放三废的严峻现状后,阐述了通过工艺改造和综合回收途径来推进三废资源化的技术对策,以及从宏观和微观上看深化三废资源化的意义和光明前景。 相似文献
179.
Clifford W. Randall Bruce S. Huloher Paul H. King 《Journal of the American Water Resources Association》1970,6(4):648-660
The activated sludge process can remove significant amounts of phosphorus from sewage, but the removal efficiency is usually significantly reduced by the release of phosphate back to solution during subsequent treatment steps. This research presents a study of soluble phosphate release from activated sludge with emphasis on defining the factors that affect such release and the actual release mechanisms. Laboratory units were used for experimental purposes. The experiments were designed to study the relationship between soluble phosphate release and various environmental factors such as redox potential (ORP), dissolved oxygen (DO), pH, solids concentration, solids destruction, and sulfate salt addition. The effect of substrate utilization on phosphate uptake and the relationship between uptake characteristics and subsequent phosphate release were also studied. The results show that some phosphate storage occurs during aerobic substrate utilization. Following substrate utilization, activated sludge phosphate release is directly related to the amount of biological stress the organisms are subjected to, and the mechanism of release is primarily cell lysis. The phosphate released per unit sludge under anoxic conditions is relatively constant. Under normal environmental conditions, neither ORP or pH change have a significant affect on phosphate release. 相似文献
180.