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Chemical defense and evolutionary trends in biosynthetic capacity among dorid nudibranchs (Mollusca: Gastropoda: Opisthobranchia) 总被引:5,自引:0,他引:5
Summary. An evolutionary scenario incorporating recent advances in phylogenetic research begins with an opisthobranch-pulmonate common
ancestor that was herbivorous and had some diet-derived chemical defense. The Nudibranchia and their closest relatives, the
Notaspidea, form a lineage the ancestors of which had switched to feeding upon sponges and deriving protection from metabolites
contained in them. Subsequently there have been repeated shifts in food and defensive metabolites, and trends are evident
in the ability to detoxify, sequester and utilize metabolites from food, as well as to synthesize defensive compounds de novo. The Notaspidea display a minor adaptive radiation that foreshadows a more extensive one in the various lineages of nudibranchs.
This review emphasizes changes that have occurred within the Holohepatica, or dorid nudibranchs (order Doridacea). Their sister-group,
the Cladohepatica, consists of three other orders, Dendronotacea, Arminacea, and Aeolidiacea, in which there has been a shift
from sponges to Cnidaria as food. The Dendronotacea often feed upon Octocorallia, which combine spicules, chemical defense,
and stinging capsules and thereby suggest a transition from feeding on sponges. A previous diet of Octocorallia is suggested
by the defensive use of prostaglandins in the dendronotacean Tethys fimbria, which eats crustaceans. A shift to bryozoans in some Arminacea is accompanied by use of different metabolites. Dorid nudibranchs
evidently began as sponge-feeders, but some lineages have shifted to a variety of other food organisms, and others have specialized
in the kind of sponges they feed on and how they do it. There have been shifts to bryozoans (Ectoprocta) and ascidians (Chordata:
Urochordata) that track metabolites rather than the taxonomy of the food. There is a crude correlation between the genealogy
and the defensive metabolites of the sponge-feeding dorids. De novo synthesis is well documented in this order and the metabolites are appropriately positioned so as to have an adaptive effect.
The hypothesis that the capacity for de novo synthesis was acquired by gene transfer across lineages is rejected, partly on the basis of different chirality of metabolites
in the nudibranchs and their food organisms. Instead it is proposed that there has been a preadaptive phase followed by evolution
in a retrosynthetic mode, with selection favoring enzymes that enhance the yield of end products that are already present
in the food.
Received 5 February 1999; accepted 26 July 1999 相似文献
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Andrés González Frank C. Schroeder Athula B. Attygalle Aleš Svatoš Jerrold Meinwald Thomas Eisner 《Chemoecology》1999,9(3):105-112
Summary. Female Photuris fireflies sequester defensive steroidal pyrones (lucibufagins) from male fireflies of the genus Photinus. Lucibufagin analyses of Photuris females and Photinus ignitus males show that the lucibufagin mixtures of predator and prey differ in their composition. Analyses of whole body extracts
showed that P. ignitus males contain a mixture of eight non-glycosylated lucibufagins, composed mostly of compounds with two oxygenated positions
in the steroidal A-ring (C-3, C-5). After feeding on P. ignitus males, Photuris females contain six major lucibufagins. Three of these compounds are not present in the prey, including the novel lucibufagin
glycoside 5β,11α-dihydroxy-12-oxo-3β-O-β-D-xylopyranosylbufalin, and two other lucibufagins with a trioxygenated A-ring (C-2,
C-3, C-5). These results indicate that Photuris females transform the sequestered lucibufagins both by glycosylation and oxidation, which could affect the systemic transportability
of these compounds due to an increase in their polarity.
Received 18 February 1999; accepted 19 April 1999. 相似文献
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以WO3粉体作为催化剂对化纤厂废水采用光催化氧化法进行脱色处理,讨论了光催化氧化法的反应机理,以及化纤厂废水的pH值、光催化剂的投入量、光照时间各因素对废水色度去除率的影响。实验结果表明:WO3粉体的投入量为1.000g/L,pH值为3.00时,利用300W高压汞灯光照7h后,废水试样的吸光度由0.596降低至0.020,色度去除率达到96.6%。 相似文献