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421.
中国降水酸沉降通量的空间特征 总被引:4,自引:0,他引:4
发展了降水酸沉降通量的概念,并在地理信息系统工具软件———ARC/INFO的支持下对中国降水酸沉降通量的分布进行了区域划分。结果表明,降水酸沉降通量的分布大致与降水酸度的分布一致,但有其自己的特点。华中和华南地区是降水酸沉降通量最大的地区。有机酸是降水中最重要的弱酸碱物质。在考虑它们的作用后,降水酸沉降通量增大。降水酸沉降通量的空间分布的估算是酸沉降引起的水体和土壤酸化研究的基础。 相似文献
422.
本文概述了联合国等国际组织以及发达国家官方文书中关于化学品健全管理的内涵、任务和指导原则的主要论述内容,以期加强我国危险化学品安全和环境管理。 相似文献
423.
A re-survey of acid-sensitive lakes in Ireland (initial survey 1997) was carried out during spring 2007 (n = 60). Since 1997, atmospheric emissions of sulfur dioxide and deposition of non-marine sulfate (SO4
2−) in Ireland have decreased by ~63 and 36%, respectively. Comparison of water chemistry between surveys showed significant
decreases in the concentration of SO4
2−, non-marine SO4
2−, and non-marine base cations. In concert, alkalinity increased significantly; however, no change was observed in surface
water pH and total aluminum. High inter-annual variability in sea salt inputs and increasing (albeit non-significant) dissolved
organic carbon may have influenced the response of pH and total aluminum (as ~70% is organic aluminum). Despite their location
on the western periphery of Europe, and dominant influence from Atlantic air masses, the repeat survey suggests that the chemistry
of small Irish lakes has shown a significant response to reductions in air pollution driven primarily by the implementation
of the Gothenburg Protocol under the UNECE Convention on Long-Range Transboundary Air Pollution. 相似文献
424.
北京市酸雨变化趋势及成因分析 总被引:2,自引:0,他引:2
1993-2002年中国气象局酸雨观测站网在北京地区有两个观测站,2003年增至3个。根据北京3个酸雨观测站的有关资料,研究了北京市酸雨变化的特征及成因。研究结果表明:第一,1993-2007年北京地区降水酸度呈现两个阶段,即1993-2002年降水酸度稳定在较弱水平,而2003-2008年呈逐年增强趋势。第二,与2003年以前相比,2003年以后硫酸根和硝酸根离子浓度均呈明显增加趋势,二者比值逐步下降并低于3,这表明北京乃至华北地区的酸雨已由硫酸型转为硫酸与硝酸并重型。第三,北京周边省、市二氧化硫年排放量的增加及钙离子和可吸入颗粒物浓度减少是近年来北京地区酸雨增强的人为原因。第四,气象条件是酸雨发生的主要动力因素。一般情况下,在地面风速较小的季节酸雨频率较高,850hPa高度为弱的偏南风或发生低层逆温时可促进酸雨的发生。此外降水量的大小也与酸雨有密切关系,24 h降水量达暴雨量级时酸雨频率最高。 相似文献
425.
Trace elements (n = 23) in Irish headwater lakes (n = 126) were investigated to determine their ambient concentrations, fractionation (total, dissolved, and non-labile), and geochemical controls. Lakes were generally located in remote upland, acid-sensitive regions along the coastal margins of the country. Total trace metal concentrations were low, within the range of natural pristine surface waters; however, some lakes (~20 %) had inorganic labile aluminum and manganese at levels potentially harmful to aquatic organisms. Redundancy analysis indicated that geochemical weathering was the dominant controlling factor for total metals, compared with acidity for dissolved metals. In addition, many metals were positively correlated with dissolved organic carbon indicating their affinity (or complexation) with humic substances (e.g., aluminum, iron, mercury, lead). However, a number of trace metals (e.g., aluminum, mercury, zinc) were correlated with anthropogenic acidic deposition (i.e., non-marine sulfate), suggesting atmospheric sources or elevated leaching owing to acidic deposition. As transboundary air pollution continues to decline, significant changes in the cycling of trace metals is anticipated. 相似文献
426.
作为高能耗和高排放产业之一的盐化产业,探索低碳发展之路具有重要意义.在对自贡市盐化产业发展现状分析的基础上,从节能、减排、引导的角度论述了盐化产业低碳发展的基本路径,并围绕低碳发展路径,从机制、政策、制度等方面提出盐化产业低碳发展的主要对策. 相似文献
427.
428.
Sangiorgi G Ferrero L Perrone MG Bolzacchini E Duane M Larsen BR 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3545-3552
A novel approach for measuring vertical profiles of HCs and particle number concentrations was described and applied in the low troposphere over Milan (Italy) during typical spring and summer days. Particle profiles yielded nearly homogeneous concentrations below the mixing height, with level-to-ground concentration ratios of 92-97%, while HCs showed a more pronounced decrease (74-95%). Vertical mixing and photochemical loss of HCs were demonstrated to cause these gradients. Much lower concentrations were observed for the profiles above the mixing height, where the HC mixtures showed also a different composition, which was partially explained by the horizontal advection of air with HC sources different to those prevailing at the site. The application of pseudo-first order kinetics for reactions between HCs and the hydroxyl radical allowed for the estimation of the vertical mixing time scale in the order of 100 ± 20 min. 相似文献
429.
Vânia Martins Carolina Correi Inês Cunha-Lopes Tiago Fari Evangelia Diapouli Manousos Ioannis Manousakas Konstantinos Eleftheriadis Susana Marta Almeida 《环境科学学报(英文版)》2021,33(2):51-61
Traffic is a main source of air pollutants in urban areas and consequently daily peak exposures tend to occur during commuting. Personal exposure to particulate matter (PM) was monitored while cycling and travelling by bus, car and metro along an assigned route in Lisbon (Portugal), focusing on PM2.5 and PM10 (PM with aerodynamic diameter <2.5 and 10 µm, respectively) mass concentrations and their chemical composition. In vehicles, the indoor-outdoor interplay was also evaluated. The PM2.5 mean concentrations were 28?±?5, 31?±?9, 34?±?9 and 38?±?21?µg/m3 for bus, bicycle, car and metro modes, respectively. Black carbon concentrations when travelling by car were 1.4 to 2.0 times higher than in the other transport modes due to the closer proximity to exhaust emissions. There are marked differences in PM chemical composition depending on transport mode. In particular, Fe was the most abundant component of metro PM, derived from abrasion of rail-wheel-brake interfaces. Enhanced concentrations of Zn and Cu in cars and buses were related with brake and tyre wear particles, which can penetrate into the vehicles. In the motorised transport modes, Fe, Zn, Cu, Ni and K were correlated, evidencing their common traffic-related source. On average, the highest inhaled dose of PM2.5 was observed while cycling (55 µg), and the lowest in car travels (17 µg). Cyclists inhaled higher doses of PM2.5 due to both higher inhalation rates and longer journey times, with a clear enrichment in mineral elements. The presented results evidence the importance of considering the transport mode in exposure assessment studies. 相似文献
430.
A. M. O. Abdul Raheem F. A. Adekola I. O. Obioh 《Environmental Modeling and Assessment》2009,14(4):497-509
A combination of multivariate statistical methods including factor analysis, principal component analysis, principal component
regression, and multiple linear regression (MLR) were employed to evaluate the influence of seasons on the concentrations
of ozone, sulfur (IV) oxide, and oxides of nitrogen in ambient air of Nigerian cities of Lagos and Ilorin. The former city
is located in the coastal area, and it is highly congested with a high intensity of marine, vehicular, and industrial activities,
and the latter city is a medium size town, located in the central guinea savannah zone of Nigeria. Samples were collected
using a high-volume sampler from near the ground at various sites of diverse human and industrial activities, during wet and
dry seasons from 2003 to 2006. The PCA reveals three distinct groupings during the day for all data, which is a reflection
of different factors contributing to the atmospheric chemistry of these cities. The predicted ozone concentration values by
MLR agree fairly well with the measured data. The dependence of ozone on meteorological parameters including relative humidity,
air temperature, and sun exposure and the precursor pollutants depends on weather and the anthropogenic activities. The results
for the two cities indicate that reduction in the level of NO2 is accompanied by an increase in the level of ozone, suggesting the interconversion between the two via photochemical activity. 相似文献