4种食用菌对蔗渣利用状况的灰色关联法分析

本文将再生资源循环利用优化方案的系统分析作为一个灰色系统的决策分析过程,把灰色系统理论的关联方法应用到蔗渣再利用的优化决策分析之中,取得了满意效果。通过对4种食用菌利用蔗渣营养成份的分析,得出了用3号培养基接种培养佛罗里达侧耳,既能最大限度地利用蔗渣中的营养,又能培养出精制的菌丝体饲料,为资源的再利用提供了一个优化决策的实例。     

Processing of Straw/Corn Stover: Comparison of Life Cycle Emissions

The LCA emissions from four renewable energy routes that convert straw/corn stover into usable energy are examined. The conversion options studied are ethanol by fermentation, syndiesel by oxygen gasification followed by Fischer Tropsch synthesis, and electricity by either direct combustion or biomass integrated gasification and combined cycle (BIGCC). The greenhouse gas (GHG) emissions of these four options are evaluated, drawing on a range of studies, and compared to the conventional technology they would replace in a western North American setting. The net avoided GHG emissions for the four energy conversion processes calculated relative to a “business as usual” case are 830 g CO₂e/kWh for direct combustion, 839 g CO₂e/kWh for BIGCC, 2,060 g CO₂e/L for ethanol production, and 2,440 g CO₂e/L for FT synthesis of syndiesel. The largest impact on avoided emissions arises from substitution of biomass for fossil fuel. Relative to this, the impact of emissions from processing of fossil fuel, e.g., refining of oil to produce gasoline or diesel, and processing of biomass to produce electricity or transportation fuels, is minor.     

四川省农业生产环境压力分析

研究主要采用产排污系数法,分析了2012年四川省农业投入品使用量及残留量,以及主要农业残留物产量,以咨环境管理参考。结果发现,四川全省化肥施用强度、农药使用强度和农用塑料薄膜残留量较大,化肥施用强度超标;年末作物秸秆产量3504.2万吨,焚烧(焚烧比20%)排放的细颗粒物质和总悬浮颗粒物超过4.0万吨;主要粪便污染物是COD与总氮,粪肥年施氮量及总磷均超过还田限值。农业稳定增产条件下,农业环境压力将持续增加。     

火场残留助燃剂的提取分离及气相色谱/质谱分析

本文总结了从火灾现场提取样品中分离残留助燃剂的常用方法,比较了各种不同分离方法的优缺点及主要适用对象,并介绍了常见助燃剂的典型气相色谱/质谱图特性,为火灾调查识别的研究提供理论指导。     

Characterization of Shredder Residues generated and deposited in Denmark

This study presents a detailed characterization of Shredder residues (SR) generated and deposited in Denmark from 1990 to 2010. It represents approximately 85% of total Danish SR. A comprehensive sampling, size fractionation and chemical analysis was carried out on entire samples as well as on each individual size fraction. All significant elemental contents except oxygen were analyzed. The unexplained “balance” was subsequently explained by oxygen content in metal oxides, carbonates, sulphates and in organics, mainly cellulose. Using mass and calorific balance approaches, it was possible to balance the composition and, thereby, estimate the degree of oxidation of elements including metals. This revealed that larger fractions (>10 mm, 10–4 mm, 4–1 mm) contain significant amount of valuable free metals for recovery. The fractionation revealed that the >10 mm coarse fraction was the largest amount of SR being 35–40% (w/w) with a metal content constituting about 4–9% of the total SR by weight and the <1 mm fine fraction constituted 27–37% (w/w) of the total weight. The lower heat value (LHV) of SR samples over different time periods (1990–2010) was between 7 and 17 MJ/kg, declining with decreasing particle size. The SR composition is greatly dependent on the applied shredding and post shredding processes at the shredding plants causing some variations. There are uncertainties related to sampling and preparation of samples for analyses due to its heterogeneous nature and uncertainties in the chemical analyses results (≈15–25%). This exhaustive characterization is believed to constitute hitherto the best data platform for assessing potential value and feasibility of further resource recovery from SR.     

Recycling of air pollution control residues from municipal solid waste incineration into lightweight aggregates

This work focuses on the assessment of technological properties and on the leaching behavior of lightweight aggregates (LWA) produced by incorporating different quantities of air pollution control (APC) residues from municipal solid waste (MSW) incineration. Currently this hazardous waste has been mostly landfilled after stabilization/solidification. The LWA were produced by pelletizing natural clay, APC residues as-received from incineration plant, or after a washing treatment, a small amount of oil and water. The pellets were fired in a laboratory chamber furnace over calcium carbonate. The main technological properties of the LWA were evaluated, mainly concerning morphology, bulk and particle densities, compressive strength, bloating index, water adsorption and porosity. Given that APC residues do not own expansive (bloating) properties, the incorporation into LWA is only possible in moderate quantities, such as 3% as received or 5% after pre-washing treatment.The leaching behavior of heavy metals from sintered LWA using water or acid solutions was investigated, and despite the low acid neutralization capacity of the synthetic aggregates, the released quantities were low over a wide pH range.In conclusion, after a washing pre-treatment and if the percentage of incorporation is low, these residues may be incorporated into LWA. However, the recycling of APC residues from MSW incineration into LWA does not revealed any technical advantage.     

Performance of a biogas upgrading process based on alkali absorption with regeneration using air pollution control residues

This work analyzes the performance of an innovative biogas upgrading method, Alkali absorption with Regeneration (AwR) that employs industrial residues and allows to permanently store the separated CO₂. This process consists in a first stage in which CO₂ is removed from the biogas by means of chemical absorption with KOH or NaOH solutions followed by a second stage in which the spent absorption solution is contacted with waste incineration Air Pollution Control (APC) residues. The latter reaction leads to the regeneration of the alkali reagent in the solution and to the precipitation of calcium carbonate and hence allows to reuse the regenerated solution in the absorption process and to permanently store the separated CO₂ in solid form. In addition, the final solid product is characterized by an improved environmental behavior compared to the untreated residues. In this paper the results obtained by AwR tests carried out in purposely designed demonstrative units installed in a landfill site are presented and discussed with the aim of verifying the feasibility of this process at pilot-scale and of identifying the conditions that allow to achieve all of the goals targeted by the proposed treatment. Specifically, the CO₂ removal efficiency achieved in the absorption stage, the yield of alkali regeneration and CO₂ uptake resulting for the regeneration stage, as well as the leaching behavior of the solid product are analyzed as a function of the type and concentration of the alkali reagent employed for the absorption reaction.     

Potential Remobilization of Toxic Anions during Reduction of Arsenated and Chromated Schwertmannite by the Dissimilatory Fe(III)-Reducing Bacterium Acidiphilium cryptum JF-5

Schwertmannite, an iron(III)-oxyhydroxysulfate formed in acidic mining-impacted stream or lake waters often contaminated with toxic elements like arsenate or chromate, is able to incorporate high amounts of these oxyanions. Detoxification of the water might be achieved if precipitated arsenated or chromated schwertmannite is fixed in the sediment. However, under reduced conditions, reductive dissolution of iron oxides mediated by the activity of Fe(III)-reducing bacteria might mobilize arsenate and chromate again. In this study, the reduction of synthesized arsenated or chromated schwertmannite by the acidophilic Fe(III)-reducer Acidiphilium cryptum JF-5, isolated from an acidic mining-impacted sediment, was investigated. In TSB medium at pH 2.7 with glucose as electron donor, A. cryptum JF-5 reduced about 10% of the total Fe(III) present in pure synthetic schwertmannite but only 5% of Fe(III) present in arsenated schwertmannite. In contrast to sulfate that was released during the reductive dissolution of pure schwertmannite, arsenate was not released during the reduction of arsenated schwertmannite probably due to the high surface complexation constant of arsenate and Fe(III). In medium containing chromated schwertmannite, no Fe(II) was formed, and no glucose was consumed indicating that chromate might have been toxic to cells of A. cryptum JF-5. Both As(V) or Cr(VI) could not be utilized as electron acceptor by A. cryptum JF-5. A comparison between autoclaved (121 °C for 20 min) and non-autoclaved schwertmannite samples demonstrated that nearly 100%of the bound sulfate was released during heating, and FTIR spectra indicated a transformation of schwertmannite to goethite. This structural change was not observed with autoclaved arsenated or chromated schwertmannite. These results suggest that the mobility of arsenate and chromate is not enhanced by the activity of acidophilic Fe(III)-reducing bacteria in mining-impacted sediments. In contrast, the presence of bound arsenate and chromate seemed to stabilize schwertmannite against reductive dissolution and its further transformation to goethite that is an ongoing process in those sediments.     

碱锰型电解二氧化锰生产环境影响与环保措施

主要以某公司9000t/a碱锰型电解二氧化锰技改项目环境影响评价为例,结合验收监测数据,简要介绍碱锰型电解二氧化锰生产的环境影响与环保措施.该公司采用氧化锰矿和硫铁矿混合硫酸溶液浸出--电解的生产工艺生产碱锰型电解二氧化锰,生产过程中大气污染源主要有锅炉排放的烟气,化合、电解工序产生的硫酸雾;生产废水主要有锅炉除尘废水、漂洗水及炭黑生产废水;废渣主要是压滤锰渣.     

兰炭生产过程中固体废物的产生与利用现状分析

在对国内兰炭生产工艺流程应用及现状介绍的基础上,概括总结了旧式低温干馏阶段和现阶段兰炭生产过程中固体废物的产生节点、种类、性质和主要处置方式。结果表明,旧式低温干馏阶段,兰炭生产过程中产生的固体废物主要包括煤筛分破碎工序产生的末煤和煤矸石、筛焦工序产生的焦粉、焦油冷却收集系统产生的焦油渣等;现阶段,兰炭生产过程中产生的固体废物主要包括煤筛分破碎工序产生的末煤和煤矸石以及破碎过程中经除尘器收集的煤尘、筛焦工序产生的焦粉、废水处理污泥、焦油冷却收集系统产生的焦油渣、脱硫工序产生的脱硫残液等。其中末煤、煤矸石、煤尘、焦粉作为一般工业固废全部综合利用,废水污泥、焦油渣、脱硫残液主要掺入原料煤中自行消化处置。