全文获取类型
收费全文 | 876篇 |
免费 | 83篇 |
国内免费 | 327篇 |
专业分类
安全科学 | 51篇 |
废物处理 | 102篇 |
环保管理 | 56篇 |
综合类 | 547篇 |
基础理论 | 258篇 |
污染及防治 | 193篇 |
评价与监测 | 72篇 |
社会与环境 | 7篇 |
出版年
2023年 | 13篇 |
2022年 | 23篇 |
2021年 | 20篇 |
2020年 | 18篇 |
2019年 | 23篇 |
2018年 | 32篇 |
2017年 | 38篇 |
2016年 | 49篇 |
2015年 | 64篇 |
2014年 | 56篇 |
2013年 | 134篇 |
2012年 | 87篇 |
2011年 | 69篇 |
2010年 | 60篇 |
2009年 | 59篇 |
2008年 | 41篇 |
2007年 | 55篇 |
2006年 | 70篇 |
2005年 | 64篇 |
2004年 | 34篇 |
2003年 | 39篇 |
2002年 | 34篇 |
2001年 | 44篇 |
2000年 | 19篇 |
1999年 | 18篇 |
1998年 | 20篇 |
1997年 | 17篇 |
1996年 | 23篇 |
1995年 | 22篇 |
1994年 | 5篇 |
1993年 | 11篇 |
1992年 | 4篇 |
1991年 | 9篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1286条查询结果,搜索用时 31 毫秒
101.
Cintya Aparecida Christofoletti Janaína Pedro Escher Jorge Evangelista Correia Julia Fernanda Urbano Marinho Carmem Silvia Fontanetti 《Waste management (New York, N.Y.)》2013,33(12):2752-2761
The inadequate and indiscriminate disposal of sugarcane vinasse in soils and water bodies has received much attention since decades ago, due to environmental problems associated to this practice. Vinasse is the final by-product of the biomass distillation, mainly for the production of ethanol, from sugar crops (beet and sugarcane), starch crops (corn, wheat, rice, and cassava), or cellulosic material (harvesting crop residues, sugarcane bagasse, and wood). Because of the large quantities of vinasse produced, alternative treatments and uses have been developed, such as recycling of vinasse in fermentation, fertirrigation, concentration by evaporation, and yeast and energy production. This review was aimed at examining the available data on the subject as a contribution to update the information on sugarcane vinasse, from its characteristics and chemical composition to alternatives uses in Brazil: fertirrigation, concentration by evaporation, energy production; the effects on soil physical, chemical and biological properties; its influence on seed germination, its use as biostimulant and environmental contaminant. The low pH, electric conductivity, and chemical elements present in sugarcane vinasse may cause changes in the chemical and physical–chemical properties of soils, rivers, and lakes with frequent discharges over a long period of time, and also have adverse effects on agricultural soils and biota in general. Thus, new studies and green methods need to be developed aiming at sugarcane vinasse recycling and disposal. 相似文献
102.
Zsuzsanna Horváth Judit Sali Andrea Zentai Enikő Dorogházi Zsuzsa Farkas Kata Kerekes 《Journal of environmental science and health. Part. B》2013,48(3):143-152
The pesticide usages are controlled by comparing residue concentrations in treated commodities to legally permitted maximum levels (MRLs) determined based on supervised trials designed to reflect likely maximum residues occurring in practice following authorised use. The number of trials available may significantly affect the accuracy of estimated maximum residues. We conducted a study with synthetic lognormal distributions with mean of 1 and standard deviations of 0.8 and 1.0, which reflect the residue distributions observed in practice. The likely residues in samples were modelled by drawing random samples of size 3, 5, 10 and 25 from the synthetic populations. The results indicate that the estimations of highest residues (HR), used for calculation of short-term intake, and the MRLs, serving as legal limits, are very uncertain based on 3–5 trials indicated by the calculated HR0.975/HR0.025 and MRL0.975/MRL0.025 ratios of 12 and 9, and 13 and 10, respectively, which question the suitability of such trials for the intended purpose. As the 95% range of HR and MRL rapidly decreases with number of trials, ideally ≥15 but minimum 6–8 trials should be used for estimation of HR and MRL according to the current typical practice of Codex Alimentarius. 相似文献
103.
本文对用硫法锂渣制取白炭黑的基本原理及工艺流程作了较为详细的阐述,对该工艺的各种影响因素进行了探讨,并制得了合格的白炭黑,为锂渣的综合利用开辟了新的途径。 相似文献
104.
W. L. Nutter T. Tkacs P. B. Bush D. G. Neary 《Journal of the American Water Resources Association》1984,20(6):851-858
The breakpoint rainfall hydrology and pesticide options of the field scale model CREAMS (Chemicals, Runoff, and Erosion from Agricultural Management Systems) were used to predict average concentrations of hexazinone [3 cyclohexyl-6-(dimethyl-amino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione] in stormflow from four forested watersheds in the upper Piedmont region of Georgia. Predicted concentrations were compared with measured concentrations recorded over a 13-month period. CREAMS accurately predicted hexazinone concetrations in the initial stormflow events which also contained the highest concentrations. The model underestimated the hexazinone concentrations in stormflow two months and greater following pesticide application. In a companion study, the daily rainfall option of the CREAMS model was used to evaluate the reltive risk associated with the maximum expected concentration of hexazinone, bromacil (5-bromo-3 sec-butyl-6 methyuracil), picloram (4-amino-3,5,6 trichloropicolinic acid), dicamba (3,6-dichloro-0-anisic acid), and triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid} in stormflow from small forested watersheds. The model predicted the following order of potential residue appearance in stormflow: bromacil>triclopyr>hexazinone>picloram>dicamba. Subsurface movement of residues via interflow and deep leaching losses are not simulated by the version of CREAMS used in these studies. 相似文献
105.
Holger Ecke Nourreddine Menad Anders Lagerkvist 《Journal of Material Cycles and Waste Management》2002,4(2):117-126
Dry scrubber residue from municipal solid waste incineration (MSWI) was characterized to identify critical inorganic pollutants
and to suggest a conceptual treatment method. The key methods used were thermal analysis, including thermogravimetry (TG)
and differential thermal analysis (DTA), pHstat titration, qualitative X-ray diffraction (XRD), scanning electron microscopy (SEM), chemical equilibrium calculations, and
statistics such as error propagation, principal component analysis (PCA), and empirical modeling based on factorial designs.
Based on EU directives, the major inorganic pollutants Cd, Cr, Pb, and Zn were found. In addition, the pH was too high. With
dry scrubber residue stabilization in mind, the impact of carbonation and hydration was assessed and judged to be encouraging.
In particular, chemical equilibrium calculations showed that carbonation has considerable potential to lower the pH and the
availability of Pb, Zn, and Cr. The impact of carbonation on the mobility of Cd was found to be small. During carbonation,
a metal-trapping calcium aluminosilicate hydrate (C–A–S–H) phase is also formed. Both processes together have the potential
to lead to a robust, reliable, and reasonable stabilization method for dry scrubber residue. However, to control these processes,
the decisive factors need to be identified and their effects need to be quantified. Ca, Cl, Na, and K might be abundant components
which would be mobile even after stabilization.
Received: September 11, 2001 / Accepted: December 6, 2001 相似文献
106.
Caroline Michel Marie-Thérèse Giudici-Orticoni Frauke Baymann Mireille Bruschi 《Water, Air, & Soil Pollution: Focus》2003,3(3):161-169
The treatment of soils and ground waters polluted by heavy metals is of economical and environmental interest. Reduction of Cr(VI) to the less toxic Cr(III) associated to its precipitation is a potentially useful process for bioremediation. In order to develop ecological processes using micro-organisms, we have compared various sulfate-reducing bacteria for enzymatic reduction of chromate. The best Cr(VI) reductase activity was obtained with Desulfomicrobium norvegicum. Despite morphological changes induced by the presence of chromate, this strain can grow in the presence of up to 500 M Cr(VI) and can decontaminate waters polluted by Cr(VI) when seeded in bioreactors. We have demonstrated the ability of several metalloenzymes (cytochromes c
3 and hydrogenases) to reduce chromate. Biophysical investigations of the chromate/protein interaction in order to get further informations on the mechanism of metal reduction by cytochromes c
3 are under the way. 相似文献
107.
108.
Status of recycling end-of-life vehicles and efforts to reduce automobile shredder residues in Korea
Hyun-Tae Joung Sung-Jin Cho Yong-Chil Seo Woo-Hyun Kim 《Journal of Material Cycles and Waste Management》2007,9(2):159-166
The present end-of-life vehicle (ELV) recycle rate and management status during the dismantling stage were investigated to
aid the establishment of policies for the management of ELVs by surveying information and using the results gained from questionnaires
given to dismantlers. The average recycle rate at the dismantling stage was 44% of the mass of a new vehicle and the rest
of the ELV was then compressed and transported to shredding companies to recover mainly the iron content, which averaged 38.7%
of the mass of a new vehicle. Nonferrous metals such as copper, antimony, zinc, and aluminum accounted for only 1.5%. The
automobile shredder residues (ASRs) were composed of light and heavy fluffs and soil/dust and amounted to 15.8% based on the
mass of a new vehicle. The dumping of fluff and inorganic residues in landfill sites, however, will be restricted when new
regulations are implemented to reduce the disposal amount to less than 5% of a new car, as has been done in European countries
and in Japan. The detailed characteristics of ASR were investigated to suggest appropriate means of treatment such as volume
reduction or the utilization of thermal technologies to meet future expected enforcement. Also, some concerns on hazardous
pollutant release such as that of dioxins while utilizing such thermal treatment methods were considered. The present on-going
research and development projects to meet such future management targets are also introduced. 相似文献
109.
William G. Wilber Joseph V. Hunter 《Journal of the American Water Resources Association》1979,15(3):790-800
ABSTRACT: A three-year study has been conducted on a 4.6 mile stretch of the Saddle River near Lodi, New Jersey. The primary objectives of this investigation were (1) to provide baseline information on the concentration and distribution of heavy metals in bottom sediments of the Saddle River; (2) to qualitatively evaluate which parameters affect this distribution; and (3) to determine the effect of urbanization on the concentration and distribution of these materials. Significant enrichments of several heavy metals were observed in bottom sediments of the lower Saddle River near Lodi, New Jersey, as compared to the upper Saddle River. Attempts to correlate metal concentrations in bottom sediments with chemical-oxygen demand were not successful in demonstrating a relationship between these two factors. Metal concentrations were found to be strongly dependent upon particle size. In general, metal concentrations in bottom sediments increased with decreasing partical diameter. However, metals enrichment was observed to be considerably greater in the larger sediment fractions studied (>420μ) than the smaller sediment fractions as one proceeded downstream through the urban area. Since the larger sediment fractions are least effected by scour and transport they may best reflect the effect of urbanization on the distribution of heavy metals over an extended period of time at a given location. 相似文献
110.
《Chemistry and Ecology》2007,23(5):409-425
The use of a new sorbent developed from the husk of pomegranate, a famous fruit in Egypt, for the removal of toxic chromium from aqueous solution has been investigated. The batch experiment was conducted to determine the adsorption capacity of the pomegranate husk. The effects of initial metal concentration (25 and 50 mg l-1), pH, contact time, and sorbent concentration (2-6 g l-1) have been studied at room temperature. A strong dependence of the adsorption capacity on pH was observed, the capacity increased as the pH decreased, and the optimum pH value was pH 1.0. Adsorption equilibrium and kinetics were studied with different sorbent and metal concentrations. The adsorption process was fast, and equilibrium was reached within 3 h. The maximum removal was 100% for 25 mg l-1 of Cr6+ concentration on 5 g l-1 pomegranate husk concentration, and the maximum adsorption capacity was 10.59 mg g-1. The kinetic data were analysed using various kinetic models—pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion equations—and the equilibrium data were tested using several isotherm models, Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich, and Generalized isotherm equations. The Elovich and pseudo-second-order equations provided the greatest accuracy for the kinetic data, while Langmuir and Generalized isotherm models were the closest fit for the equilibrium data. The activation energy of sorption has also been evaluated as 0.236 and 0.707 kJ mol-1 for 25 and 50 mg l-1 chromium concentration, respectively. 相似文献