装置级突发事故应急预案编制的思考与对策

结合石化企业装置生产特点,分析装置级突发事故应急预案编制中存在的不足和问题,并对应急预案编制的思路和处置对策进行了深入地探讨.     

Impact analysis of drought, water excess and salinity on grass production in The Netherlands using historical and future climate data

The coupled SWAP-WOFOST model was used to study the effects of increasing salinity of groundwater, drought and water excess on grass production in The Netherlands. WOFOST simulates crop growth and SWAP simulates transport of water, solutes and heat in the vadose zone. The model was tested using several datasets from field experiments. We applied the models at regional scale where we quantified the impact of various groundwater salinity levels on grass growth and production using historical weather data (1971-2000). The salt concentrations in the subsoil were derived from the National Hydrological Instrument. The results show that salinity effects on grass production are limited. In wet years the excess rainfall will infiltrate the soil and reduce salt water seepage. In a next step we used future weather data for the year 2050, derived from 3 Global Circulation Models. From each model we used data from two CO₂ emission scenarios. As expected higher temperatures increased drought stress, however, the production reduction as a result of salt water in the root zone is limited. Salt stress mainly occurred when irrigation was applied with saline water. The increased CO₂ concentration in combination with the limited drought stress resulted in increasing simulated actual and potential yields. Overall conclusion for grassland in The Netherlands: drought stress is stronger than stress caused by water excess which on its turn is stronger than salinity stress. Future water demand for irrigation may increase by 11-19% and result in water scarcity if water supply is insufficient.     

The evolution of climate policies - the role of learning and evaluations

All member states of the EU have had to develop climate strategies following the commitment to the UN Framework Convention on Climate Change and the Kyoto Protocol. The evolution of the strategies provides insights into the learning that takes place at the level of policy development and offers material for analysing how ex ante and ex post evaluations have contributed to this learning. In the analysis, Finland is used as a case demonstrating different levels and types of learning, from deeper reframing to political learning. The results show that the full potential of the evaluations has not been utilised, partly because they have been constrained by their mandate. Greater openness and transparency in the policy processes would create favourable conditions for independent evaluations that could provide additional input to the policy processes. This would support social and reflexive learning and allow for greater adaptability.     

1957-2007年新疆天山山区气候变化对径流的影响

利用天山山区1957-2007年的气温、降水量及径流数据,借助非参数检验、小波变换等方法分析了天山山区气温、降水量及年径流量的变化趋势及多时间尺度相关。结果表明:玛纳斯河与塔里木河源流区年径流量、气温与降水量均呈显著增加趋势;在年代际上,塔里木河源流区气温存在11、18和22 a的主周期,降水量存在10、20与22 a的主周期;玛纳斯河气温在10与22 a处存在明显周期,降水量在20与22 a处周期性明显;同时,两源流区气温和降水量皆存在3~6 a的年际周期变化;塔里木河年径流量、气温和降水量的突变点分别发生在1993、1993和1992年,而玛纳斯河分别在1995、1988与1996年发生显著性突变;两流域源流区年径流量与气候因子存在显著的多时间尺度相关关系。     

后寨河流域岩溶含水层脆弱性及其对土地利用方式的响应

由于强烈的溶蚀作用,岩溶地区溶蚀裂隙、管道等高度发育,并相互贯通,形成岩溶区特有的地下、地表“双层空间”结构体系,地下空间成为地下水存储和运移的重要场所。岩溶地区由于土层浅薄或缺失,并且溶蚀裂隙、管道、落水洞、竖井等高度发育,使含水层更易受地表状况的影响,土地利用/覆被变化在很大程度上影响着地下水的水质、水量,岩溶水质的变化能集中反映人类活动胁迫下岩溶含水层脆弱性程度的增加。以典型岩溶单元--贵州普定后寨河流域为例,分析了流域水文地质背景下的岩溶含水层本质脆弱性,结合流域地下河水近20年的水化学资料,分析了含水层脆弱性对土地利用变化的响应。结果显示：土地利用/覆被变化、农业活动、城镇建设及居民活动都对地下水质变化有明显影响。因此,调整土地利用结构,恢复岩溶植被,改善生态环境是保护和改善岩溶水资源的重要途径。     

Modeling assessment for ammonium nitrogen recovery from wastewater by chemical precipitation

Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium nitrogen (NH4 +-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4 +-N recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4 +-N recovery from coking wastewater was conducted to provide a comparison. Response surface methodology (RSM) was applied to assist in understanding the relative significance of reaction factors and the interactive effects of solution conditions. Thermodynamic modeling indicated that the saturation index (SI) of MAP followed a polynomial function of pH. The SI of MAP increased logarithmically with the Mg2+/NH4 + molar ratio (Mg/N) and the initial NH4 +-N concentration (CN), respectively, while it decreased with an increase in Ca2+/NH4 + and CO3 2??/NH4 + molar ratios (Ca/N and CO3 2??/N), respectively. The trends for NH4 +-N removal at different pH and Mg/N levels were similar to the thermodynamic modeling predictions. The RSM analysis indicated that the factors including pH, Mg/N, CN, Ca/N, (Mg/N) (CO3 2??/N), (pH)2, (Mg/N)2, and (CN)2 were significant. Response surface plots were useful for understanding the interaction effects on NH4 +-N recovery.     

中心组合设计优化S-Cr-TiO2催化剂光降解工艺条件

在确定的温度和光照条件下,采用中心组合设计法研究了固相反应法合成的硫与铬共掺杂二氧化钛(S-Cr-TiO2)光催化剂与水溶苯胺蓝(ANB)可见光降解过程中的三个作用因子:催化剂的浓度、水溶苯胺蓝水溶液的pH值及其初始浓度之间的相互作用关系,得到了影响因子与降解速率之间的回归方程及因素之间相互作用的响应面图.结果表明,S...     

密云水库流域2000-2005年植被覆盖度变化监测

植被是生态系统最重要的组成部分,而植被覆盖度是衡量地表植被状况的一个最重要的指标,是生态系统健康评价的前提和必要的基础。文章利用2000和2005年2个时相的Landsat 7 ETM+遥感影像为数据源,以BP神经网络法为植被覆盖度估算模型,计算了密云水库流域内不同时期的植被覆盖度,生成了该流域2个时相内的植被覆盖度图,以此分析密云水库流域植被覆盖度的时空变化。结果表明,从2000-2005年,密云水库流域内除无植被覆盖类型外(即水域部分),其余土地利用类型的植被覆盖度都呈增加趋势,其中以沙质地和耕地最为明显,分别增长了29.5%和27.3%,并且密云水库流域的平均植被覆盖度不高,尤其西部地区植被覆盖度较差,水土流失和土地沙化情况比较严重。     

塔里木盆地南缘克里雅绿洲土地利用变化对生态系统服务价值的影响研究

以塔里木盆地南缘克里雅绿洲作为典型区,分析1991-2001年土地利用变化对生态系统服务价值的影响。研究结果表明,克里雅绿洲在1991-2001年土地利用变化很明显,生态服务价值从1991年的10．004×10^8元降到20,01年的8．792×10。元,生态服务价值损失了12％,平均每年净损失生态服务价值32．2元／hm^2湿地生态服务价值的变化最大,变化率高达-37．54％。湿地、水体面积变化的绝对量高、生态服务功能价值指数大是导致研究区生态系统服务总价值降低的主要原因。敏感性分析结果表明,克里雅绿洲生态服务价值对生态服务功能指数是缺乏弹性的,研究结果是可信的,可为研究区土地利用规划提供借鉴。     

丽江古城水环境质量变化趋势浅析

通过对丽江古城2002年～2010年水环境质量情况及变化趋势的分析,找出水质不断下降的原因,提出了古城水环境保护的相应对策和措施。