电缆燃烧产烟影响因素的试验研究

利用锥形量热仪和烟密度仪通过试验分别测量了ZR-VV 4×6、ZR-YJV 4×6、YJV 4×6三种型号的电缆在一定辐射强度下烟气的释放速率、质量损失速率以及有效燃烧热等火灾参数,分析、比较了它们之间的关系,并通过改变电缆的附着基材、燃烧时环境的氧浓度得到这些因素对电缆的产烟有不同程度的影响,该研究为实际工程中电缆的敷设以及电缆火灾的扑救提供了依据.     

云模型在城镇空气质量评价中的应用

空气质量评价是当前城镇环境评价的一个重要环节,这一过程存在着很强的模糊性和随机性。云模型把模糊性和随机性完全集成,构成定性与定量之间的映射。文章将云模型引入空气质量评价,结合空气质量评价标准,建立了云模型空气质量评价方法,并通过对比验证了该方法的有效性。     

A quantitative correlation of evaluating the flame speed for the BST method in vapor cloud explosions

In recent decades, vapor cloud explosions (VCEs) have occurred frequently and resulted in numerous personnel injuries and large property losses. As a main concern in the petrochemical industry, it is of great importance to assess the consequence of VCEs. Currently, the TNT equivalency method (TNT EM), the TNO multi-energy method (TNO MEM), and the Baker-Strehlow-Tang (BST) method are widely used to estimate the blast load from VCEs. The TNO MEM and BST method determine the blast load from blast curves based on the class number and the flame speed, respectively. To quantitatively evaluate the flame speed for the BST method, the experimental data is adopted to validate the confinement specific correlation (CSC) for the determination of the class number in the TNO MEM. As a bridge, a quantitative evaluation correlation (QEC) between CSC correlation and the flame speed is established and the blast wave shapes corresponding to different flame speeds are proposed. CFD software FLACS was used to verify the quantitative correlation with the numerical models of three geometrical scales. It is found that the calculated flame speeds by the QEC are in good agreement with the simulated ones. A petrochemical plant is selected as a realistic scenario to analyze the TNT EM, TNO MEM, BST method and FLACS simulations in terms of the positive-phase side-on overpressure and impulse at different distances. Compared with the flame speed table, the predicted overpressure from BST curves determined by the proposed QEC is closer to that from FLACS and more conservative. Furthermore, the predicted results of different methods are compared with each other. It is found that the estimated positive-phase side-on overpressure and impulse by the TNO MEM are the largest, and the estimated impulse by the TNT EM is the smallest. Moreover, the estimated overpressure and impulse are larger in the higher reactivity gas.     

基于融合权集对云的煤矿安全评价及应用*

为合理评价煤矿安全状态,针对煤矿安全影响因素多、指标体系关联度复杂等问题,提出融合权与集对云的安全评价模型。运用云理论特征值修饰集对分析联系度,兼顾系统的模糊性与不确定性,并引入融和后的各指标最优权重,得出系统综合云联系度;绘制等级云图判定系统安全状态及偏向趋势;结合煤矿实例进行验证。结果表明:案例煤矿所处安全状态为较安全,有偏向一般安全状态微势。分析结果与实际相符,且充分考虑煤矿安全评价体系的随机性,该模型可为煤矿安全评价提供理论指导。     

A simple formula for calculating the ionization potential of two-electron ions

The ionization potential of one-electron ions can be calculated from a well-known simple equation, but no such equation has been available for calculating the ionization potential of multi-electron ions. I report here an equation that accurately gives the ionization potential of helium-like (i.e., two-electron) ions as a function of the atomic number, the relative difference from experimental values being below 1% for all ions for which reliable experimental data were found (Z = 3–29). The equation also predicts the stability of the negative hydrogen ion (the hydride ion), H⁻, although with twice too large a value for the ionization potential.     

氨法烟气脱硫系统雾滴浓度测定方法

对于烟气脱硫系统,准确测定烟气中雾滴浓度是完成脱硫系统性能考核的必备技术,目前国内尚无脱硫系统除雾器性能测试统一标准规范。介绍了氨法烟气脱硫系统雾滴浓度的测定方法———硫酸根离子法,阐述了该方法的原理与特点,方法步骤,为氨法烟气脱硫工程考核除雾器性能提供了一种有效的参考方法。     

微生物在土壤中迁移物化参数的确定

以甲基叔丁基醚高效降解菌Chryseobacterium sp.A-3为研究对象,对污染场地生物修复中微生物在土壤中迁移的重要相关物化参数做了详细的描述和实验研究,包括土壤物性参数以及微生物在土壤中的吸附等温参数、吸附动力学、有效扩散系数和生长项系数.结果表明,微生物在土壤中的吸附等温线可与Freundlich方程很好地拟合,相关性达到99.5%,指数常数为1.1,该指数常数在统计上与1差别不大,因此可以用线性方程来描述平衡吸附过程.实验测得该菌在砂质壤土中的平衡吸附系数为0.98 mL/g.滞膜理论能够预测土壤中微生物的动力学吸附行为,同时也说明吸附过程是可逆的,得到土壤中微生物吸附的动力学参数,即可逆吸附常数为0.004 s-1,可逆解吸常数为0.002 s-1.膜池理论与分形理论分析得到微生物在土壤中的扩散系数为3.66×10-6 cm2/s,有效扩散系数为5.18×10-7cm2/s.通过对微生物降解甲基叔丁基醚过程进行拟合得到微生物的最大比增长速率为0.01 h-1,基质半饱和常数为134 mg/L以及细胞得率为0.33.本研究所提出的微生物在土壤中物化参数的确定方法可普遍应用于实验室和现场的微生物...     

基于撞击法的喷雾射流粒径研究*

为解决我国光学法仪器价格昂贵,操作复杂,在消防领域未能大范围应用的问题。基于撞击法的采样原理,提出新测试方法,并将其应用于消防领域喷雾射流现场测试。在不同的喷孔数量条件下,通过改变喷雾射流出口压力,观察并统计水雾携带的雾滴在载玻片上留下的印记,根据其直径和数量得出雾滴粒径的分布。研究结果表明:喷雾射流雾滴粒径值与平均直径预测模型的预测值和马尔文粒度仪测得的粒径值相近,水雾粒径随着出口压力的增大而减小,研究结果可为喷雾水枪性能测试和优化改造提供技术支持。     

基于多维云模型的埋地并行油气管道风险评价研究*

为提高风险评价准确性以有效支撑管道完整性维护,保证油气管道在多管并行敷设下安全运行,提出1种基于博弈论-多维云模型的风险评价方法。首先,从并行间距、土壤压实度、土壤导热系数、介质流速、管径、埋深、应急响应时间、上下游截断阀间距等方面建立并行管道风险评价指标体系,为降低传统赋权方法的主观性,通过结合熵权法改进层次分析法（AHP）,从而确定主客观权重,再经博弈论组合赋权法综合计算指标权重;其次,运用多维云模型理论确定风险等级,通过修正各风险评分项的等级区间结合指标权重,计算出各级的综合确定度,并进行等级评判;最后,将该方法应用于工程实例。研究结果表明:所评价管段的指标风险处于中等风险水平,风险可接受,管段的整体风险评价结果良好,有利于并行管道安全管理;实例证明该评价方法具有较好的适用性。     

温和地区高校宿舍冬季室内热舒适性评价

以昆明理工大学某学生宿舍作为研究对象,对室内热环境进行现场测试和问卷综合分析,根据测试和调查结果选取了有效温度作为衡量指标,基于MTS和PMV-PPD模型分析的方式对研究对象存在的冬季室内热环境较差、温度低、湿度高的问题进行了热舒适评价,旨在为昆明高校宿舍热环境的研究和改善提供参考。