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741.
742.
743.
Ozone plays an important role as a disinfectant and oxidant in potable water treatment practice and is increasingly being used as a pre-oxidant before coagulation. The purpose of this study is to obtain insight into the mechanisms that are operative in pre-ozonized coagulation. Effects ofpre-ozonation on organic matter removal during coagulation with IPF-PAC1 were investigated by using PDA (photometric disperse analysis), apparent molecular weight distribution and chemical fractionation. The dynamic formation of flocs during coagulation process was detected. Changes of aquatic organic matter (AOM) structure resulted from the influence of pre-ozonation were evaluated. Results show that dosage of O3 and characteristics of AOM are two of the major factors influencing the performance of O3 on coagulation. No significant coagulation-aid effect of O3 was observed for all experiments using either A1C13 or PAC1. On the contrary, with the application of pre-ozonation, the coagulation efficiency of A1C13 was significantly deteriorated, reflected by the retardation of floc formation, and the removal decreases of turbidity, DOC, and UV254. However, if PACl was used instead of AlCl3, the adverse effects of pre-ozonation were mitigated obviously, particularly when the O3 dosage was less than 0.69 (mg O3/mg TOC). The difference between removals of UV254, and DOC indicated that pre-ozonation greatly changed the molecular structure of AOM, but its capability of mineralization was not remarkable. Only 5% or so DOC was removed by pre-ozonation at 0.6--0.8 mg/L alone. Fractionation results showed that the organic products of pre-ozonation exhibited lower molecular weight and more hydrophilicity, which impaired the removal of DOC in the following coagulation process. 相似文献
744.
745.
746.
高浓度Cu-COD废水处理方法研究 总被引:3,自引:0,他引:3
采用化学凝聚-生物流化床法对含Cu1700—3800mg/L和COD3900—5400mg/L的Cu-COD)废水进行处理试验研究。着重研究了生物流化床挂膜驯化条件和废水停留时间、容积负荷,气水比及化学凝聚条件等与去除COD和Cu的关系。试验结果表明,采用凝聚-生物流化床组合工艺并在控制适宜条件下,处理高浓度Cu-COD废水是有效的,处理后排放水中铜浓度可达0.20—0.82mg/L,COD可达150—180mg/L,铜总去除率可达99.97%,COD总去除率可达95%—96%。 相似文献
747.
絮凝科学的研究与进展 总被引:10,自引:0,他引:10
概述近年来絮凝领域一些重要研究:设计操作图:快速混合的物理模型、最佳絮凝剂投量的预计、无分子絮凝剂、最佳处理方案的选择等。提出了若干尚需研究的课题,它们分属模型研究、性研究、最佳过程设计及絮凝剂新品种开发诸方面。 相似文献
748.
749.
UV/Fenton氧化-混凝联合工艺处理含酚废水 总被引:8,自引:0,他引:8
采用UV/Fenton氧化-混凝联合工艺对模拟苯酚废水进行处理,探讨了UV/Fenton预氧化程度和混凝处理条件对模拟苯酚废水处理效果的影响。结果表明,采用混凝处理,COD去除率仅为14.1%;当UV/Fenton预氧化处理过程中H2O2的质量浓度为150~300mg/L时,废水的混凝性能可提高1.5倍以上;当H2O2质量浓度为450mg/L、光反应时间为30min时,采用UV/Fenton氧化一混凝工艺联合处理后COD去除率达82.7%。苯酚废水采用UV/Fenton预氧化处理后,进行混凝处理过程的适宜pH为6.5,混凝剂Fe^3 的适宜质量浓度为500mg/L. 相似文献
750.
The Yellow River in winter as source water is characterized as high alkalinity, low temperature and low particle concentrations,
which have brought many difficulties to water treatment plants. This study fully examines the optimized coagulation process
of the Yellow River by conventional and pre-polymerized metal coagulants, pH adjustment and polyelectrolytes as the primary
coagulants or coagulant aids. For all the metal coagulants, polyaluminum chlorides are superior to traditional metal coagulants
due to their stable polymeric species and low consumption of alkalinity. The removal of natural organic matter by monomeric
metal coagulants can be improved through pH adjustment, which is in accordance with the higher concentration of polymeric
species formed at corresponding pH value. With the addition of polyelectrolytes as coagulant aids, the coagulation performance
is significantly improved. The effective removal of dissolved organic matter is consistent with high charge density, while
molecular weight is relatively important for removing particles, which is consistent with polyelectrolytes as primary coagulants.
These results suggest that the coagulation mechanisms in the removal of dissolved organic matter and particles are different,
which may be exploited for optimized coagulation for the typical source water in practice. 相似文献