全文获取类型
收费全文 | 211篇 |
免费 | 27篇 |
国内免费 | 79篇 |
专业分类
安全科学 | 15篇 |
废物处理 | 18篇 |
环保管理 | 18篇 |
综合类 | 163篇 |
基础理论 | 39篇 |
污染及防治 | 47篇 |
评价与监测 | 4篇 |
社会与环境 | 3篇 |
灾害及防治 | 10篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 5篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 10篇 |
2015年 | 8篇 |
2014年 | 13篇 |
2013年 | 37篇 |
2012年 | 23篇 |
2011年 | 13篇 |
2010年 | 9篇 |
2009年 | 17篇 |
2008年 | 9篇 |
2007年 | 21篇 |
2006年 | 17篇 |
2005年 | 12篇 |
2004年 | 10篇 |
2003年 | 14篇 |
2002年 | 9篇 |
2001年 | 6篇 |
2000年 | 13篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 5篇 |
1996年 | 3篇 |
1995年 | 9篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1982年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有317条查询结果,搜索用时 31 毫秒
21.
22.
K.M.S. Sundaram 《Journal of environmental science and health. Part. B》2013,48(6):1215-1239
Abstract Leaching, downward mobility and persistence of tebufenozide was investigated under laboratory conditions in columns packed with forest litter and soil, after fortification with the analytical grade material (purity > 99.6%) and with two commercial formulations, RH‐5992 2F (aqueous flowable) and RH‐5992 ES (emulsion suspension). Two types of litter and soil were used: one type with relatively high amounts of sand and the other with high amounts of clay. The concentrations eluted in the leachates were lower when the analytical material (dissolved in acetone) was used for fortification, than when the two formulations (diluted with water) were used. The amount leached was higher for RH‐5992 2F than for RH‐5992 ES. The type of substrate, i.e., sandy or clay type, had only marginal influence on the amounts eluted in the leachates. Downward movement of tebufenozide from the top 2‐cm layer to the untreated middle and bottom layers (3‐cm segments) was consistently lower when the analytical material was used for fortification, than when the two formulations were used. Downward movement was higher for RH‐5992 2F than for RH‐5992 ES. Persistence of tebufenozide in substrates, maintained under submerged conditions for 70 days after leaching, indicated an initial 2‐week lag period prior to the onset of degradation. Formulation‐related differences were observed in the half‐life (DT50) values. When the analytical material was used for fortification, the DT50 ranged from ca 54 to 59 d. However, when the formulations were used for fortification, the DT50 showed a higher range, i.e., from ca 62 to 67 d for RH‐5992 2F and ca 70 to 80 d for RH‐5992 ES. Formulation ingredients appear to have caused enhanced adsorption of tebufenozide onto the substrates, thus delaying degradation. 相似文献
23.
Z.A. Khan B.M. Misra K. Raghu 《Journal of environmental science and health. Part. B》2013,48(5):1015-1027
Abstract Interaction of lindane with silty loam and silty clay loam soils was studied in batch tests at 23, 30 and 37° C. Sorption experiments were carried out at four concentrations and for varying time of contact upto 72 hours. This was followed by desorption studies. No desorption was observed. The sorption data was analysed using sorption equations and evaluating the thermodynamic parameters. The sorption was found to be predominantly entropic in nature and a combined effect of adsorption and chemisorption. The effect of organic matter and other chemical and mineralogical constituents of soils has also been discussed. The sorption with single application of lindane with the two soil types indicates that the insecticide is less likely to reach groundwater. 相似文献
24.
25.
采用机械球磨法对膨润土、硅藻土、高岭土3种天然黏土材料进行预处理,通过超声法将纳米TiO_2附着于其上制得复合材料,考察了不同复合材料加入量及养护时间条件下复合材料对电解锰渣中Mn的吸附固定效果。3种天然黏土材料中,硅藻土的平均粒径最小,比表面积和总孔隙度最大,对水中Mn的吸附量也最大。黏土材料附着纳米TiO_2后对电解锰渣中Mn的吸附固定效果较单纯黏土材料有明显改善。在养护时间为12 d、硅藻土附着纳米Ti O_2复合材料加入量为10%(w)的最佳条件下,Mn的TCLP浸出量较原电解锰渣下降了83.04%。 相似文献
26.
高压旋喷灌浆法是本世纪70 年代发展起来的地基处理新技术,在砂性土和粘性土等软弱地层加固工程中已得到广泛应用,但在含有碎石的淤泥质土及穿过它对其下淤泥的加固尚少见,笔者简要介绍了采用钻灌分开两大工序的新双管法及其成功完成加固任务的事例。 相似文献
27.
南京粉质粘土与粉砂互层土及粉细砂的抗液化性能试验研究 总被引:5,自引:1,他引:4
南京粉质粘土与粉砂互层土为粉质粘土与粉细砂交互沉积,呈现“千层饼”状外貌;南京粉细砂是一种以片状颗粒成分为主的粉细砂,与通常的圆形颗粒石英砂有一定区别,片状颗粒成分使得南京粉细砂具有各向异性的性质。通过南京粉质粘土与粉砂互层土及粉细砂对比液化试验,对其试验成果进行分析,从中发现:无论是偏压固结还是均压团结,当固结压力α_2=100 kPa时,南京粉质粘土与粉砂互层土的液化剪应力比比南京粉细砂的大得多;而当固结压力α_2=200kPa时,两种土的液化剪应力比相当接近。因而,对于重大工程应该慎重考虑它们的液化可能性。 相似文献
28.
鉴于碗窑碾压混凝土重力坝个别变形测点测值异常现象,依据大坝变形观测资料,通过变形规律时空分析和统计模型的建立,以及影响因子的分解,合理地解释了其变形成因,从而得出碗窑水库大坝变形性态总体正常的结论。为确保大坝安全运行,通过建立有限元力学模型和混合模型,拟定了典型坝段坝顶水平位移的一级监控指标,进而更有效地监控大坝的安全性态。另外,就个别测点坝段时效有呈逐年缓慢上升的趋势,建议管理单位加强观测,并及时分析,确保工程安全运行。 相似文献
29.
30.
S. POLATI S. ANGIOI V. GIANOTTI F. GOSETTI M. C. GENNARO 《Journal of environmental science and health. Part. B》2013,48(4):333-344
Pesticides and other organic species are adsorbed by soil via different mechanisms, with bond strengths that depend on the properties of both the soil and the pesticide. Since the clay fraction in soil is a preferential sorbent for organic matter, reference kaolinite and montmorillonite are useful models for studying the mechanism and the strength of sorption. This paper presents the results of batch experiments to investigate the interactions of kaolinite KGa-1 and montmorillonite SWy-1 with the following pesticides and organic species resulting from the natural degradation of pesticides in the environment: atrazine (1-chloro-3-ethylamino-5-isopropylamino-2,4,6-triazine), simazine (1-chloro-3,5-bisethylamino-2,4,6-triazine), diuron [1,1-dimethyl-3-(3,4-dichlorophenyl)urea], aniline, 4-chlorophenol, 2,4-dichlorophenol, and 2,4,6-trichlorophenol. Each of these chemicals has different hydrophilicity. Systems containing 2.0 g of clay were put in contact with 100.0 mL of solutions of the pesticides at known concentration ranging from 1.0 to 5.0 mg/L, and the amount of solute adsorbed was evaluated through RP-HPLC analysis of the pesticide still present in the aqueous suspension. To test for electrostatic interactions between the clay surface and the pesticides, potentiometric titration was used to determine the permanent surface charge of clays. Experiments were performed at different pH values. The results indicate that, for the chemicals studied, neutral molecules are preferentially retained relative to ionized ones, and that montmorillonite is a more effective sorbent than kaolinite. 相似文献