碘化阶层孔氧化硅纳米球对水中典型有机氯污染物的吸附性能研究

采用共缩聚法,成功地原位合成了碘改性的阶层多孔氧化硅纳米球（SiO₂-I）,研究了其基于卤键作用对典型有机氯污染物六六六的吸附性能,并考察了改性剂I-硅烷含量和pH值对吸附效果的影响.实验结果表明,该纳米材料对六六六表现出优异的吸附富集性能,吸附速率快,60 min内对六六六的去除率为71.6%,240 min内达到吸附平衡,去除率可达98.3%,最大吸附量为178.6 mg·g^-1;吸附动力学符合拟二级动力学模型;碘物种的加入提高了阶层多孔氧化硅的吸附速率和吸附效率.另外,为了便于纳米吸附材料的分离,本研究对SiO₂-I纳米球进行了磁性化.研究发现,磁性化修饰后,SiO₂-I纳米材料仍然保留对六六六优异的吸附富集性能,240 min时的吸附去除率达90.3%.     

火焰原子吸收分光光度法测定水中锶

研究了用空气/乙炔火焰原子吸收分光光度法测定水中锶时酸的影响,以及铝和钙的干扰及消除,线性范围0.05～5.00mg/l,最低检测浓度为0.04mg/l,回收率为98.2％～101.4％。     

粉煤灰预处理及其对染料单体脱色效果的研究

介绍了一种粉煤灰预处理的方法-用8mol/L的H2SO4处理，可较好地改善其表面状况，并用预处理后的粉煤灰对染料单体进行脱色试验，寻找了最佳的处理方案，脱色效果较好，建立了Langmuir吸附等温模型。探讨了其脱色机理，为实际开发利用粉煤灰处理印染废水提供基础研究。     

活性炭吸附与生物活性炭脱臭效果的比较研究

针对污水收集与处理系统中恶臭气体的组成与特性,比较分析不同情况下活性炭吸附与生物活性炭的脱臭效果。当干活性碳总处理气量达到1.3m~3/g时,出现穿透。将吸附饱和的活性炭填料塔转为生物滴滤反应器后,仍能较快的实现挂膜生长,达到满意的处理效果。直接运行的生物活性炭滴滤器对H_2S的处理效率在95％以上,并具有较强的恢复能力。H_2S平均出口浓度为0.052mg/m~3。循环液pH值与盐度在一定范围内对系统影响不大。     

活性炭性质对其吸附水中硝基苯性能的影响

通过对活性炭进行HNO3氧化及热处理改性,研究了活性炭性质对其吸附硝基苯性能的影响.以低温液氮(N2/77 K)吸附测定活性炭的比表面积和孔容、孔径分布;以Boehm滴定、零电荷点pHPZC的测定及元素分析定量表征活性发表面含氧官能团变化.结果表明:经改性后,活性炭比表面积及总孔容略有减小,表面性质发生较大变化.改性活性炭对硝基苯的吸附容量明显改变,吸附容量大小依次为:AC1′＞AC0′＞AC0＞AC1.经硝酸氧化后,比表面积下降、存在过多表面含氧官能团是导致AC1吸附硝基苯能力降低的主要原因;而AC1'表面适量酚羟基所提供的氢键吸附是其对硝基苯吸附量增加的主要原因.     

CrⅥ adsorption on four typical soil colloids: equilibrium and kinetics

It is observed that the adsorption of chromium are greater on kaolinite minerals, red soil (R) and laterite (L) colloids than that on montmorillonite, indicotic black (IB) and yellow brown (YB) soil colloids. The adsorption process of CrⅥ on these media can be further described by Langmuir or Freundlich equation quite well. The adsorption reaction of CrⅥ is fast, and the adsorption equilibrium can be reached within the first two hours in moderate temperature. The adsorption quantity of CrⅥ to kaolinite mineral increased with the increasing pH in the range of 2.0 to 7.0, then decreased at higher pH. But it showed some consistence among the four soil colloids. The lower the pH, the stronger the adsorption. The possible mechanisms are further discussed here. Meanwhile the influence of temperature on CrⅥ adsorption on different soil colloid and clay minerals are also investigated.     

Protozoan colonization on artificial substrates in relation to water quality in a tropical Indian harbour

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Adsorption selectivity of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents

Both bottle-point and column-feeding experiments involving different solutes and sorbents were carried out to investigate the adsorption selectivity and separation performance of salicylic acid and 5-sulfosalicylic acid. Their adsorption isotherms onto such hypercrosslinked polymeric adsorbents as NDA-100 and NDA-99 could be well described by the Freundlich equations whose characteristics describe extrathermic and favorable adsorption processes. The adsorption towards NDA-100 mainly depended on the π-π interaction, while that towards NDA-99 was extremely influenced by the static-electric interaction. Additionally, the adsorptive capacity of salicylic acid on NDA-99 decreased while it increased on NDA-100 with the presence of 5-sulfosalicylic acid in the adsorptive environment as the competitive component. Comparatively, the adsorption capacity of 5-sulfosalicylic acid decreased on both resins with salicylic acid as the competitive component. In fact, the difference in the interaction between adsorbent and adsorbate resulted in the straight antagonism on the effective adsorption sites on the adsorbent. In conclusion, the adsorption selectivity of salicylic acid onto NDA-100 was obviously larger than that onto NDA-99 with the existence of 5-sulfosalicylic acid in the adsorptive environment. A satisfactory separation and recovery of tested solutes in aqueous phase could be foreseeably achieved by the sequencing adsorption technique involving NDA-100 as well as NDA-99. Translated from Environmental Pollution & Control, 2005, 27(8): 570–574 [译自: 环境污染与防治]     

天然矿石毒重石吸附硫酸盐废水的试验研究

利用天然矿石毒重石对硫酸盐废水进行吸附处理，在废水的pH=9，停留时间为80min左右时，该吸附剂具有较好的吸附效果。且该离子交换吸附法具有成本低、操作简单、无二次污染的优点。     

竞争吸附方程的修正和应用

以竞争吸附的一般模式为基础,修正了竞争吸附方程。研究了不同实验条件下修正竞争吸附方程的变化形式,为改进实验设计提供了理论依据。修正竞争吸附方程应用于描述pH对土壤吸附钴的影响,取得了满意的结果。