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281.
282.
大气中SO2的液相氧化研究 总被引:2,自引:0,他引:2
大气中SO2液相氧化是形成酸雨的重要途径,降雨中含有各种无机离子和有机物质,它们可能催化或抑制液相氧化反应的进行。本文根据四川酸雨样品组成,进行了SO2在模拟雨水及实际雨水中的氧化实验,考查了V,Fe,Mn等离子对SO2氧化的催化作用,H2O2对SO2的氧化以及降水中有机物质甲醛对各反应的影响。实验结果为了解酸雨的成固,研究酸雨控制对策提供了科学依据。 相似文献
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284.
介绍了利用溶胶凝胶方法制备铜系催化剂,并考察了制备过程中各个工艺参数对铜系催化剂稳定性的影响。通过优化催化剂的设计和制备方法,可有效地改善Cu^2+的溶出问题,使该类催化剂具有广阔的应用前景。 相似文献
285.
催化湿式氧化法处理吡虫啉农药废水 总被引:2,自引:0,他引:2
自制了Cu/Mn,Cu/Ce,Cu/Ni,Ce/Mn,Ce/Ag等催化剂,经过性能比较,选择催化活性较高且金属溶出量较小的Cu/Ni作催化剂。用催化湿式氧化法处理吡虫啉农药废水,考察了各种因素对处理效果的影响。实验结果表明:在进水pH为6.93、Cu/Ni加入量为4.0g、反应温度为190oC、氧分压为1.6MPa、反应时间为120min的条件下,COD去除率为95%;处理后废水的BOD5/COD从0.093增至0.590,可生化性明显改善。 相似文献
286.
US/Fenton试剂协同处理焦化废水的研究 总被引:2,自引:0,他引:2
采用US (超声波)协同Fenton试剂氧化法处理焦化废水,考察了H2O2投加量、Fe2 投加量、废水的pH、反应时间和超声波功率对处理效果的影响,确定了最佳工艺条件.结果表明,在H2O2投加量7.0 g/L;Fe2 投加量500 mg/L;pH=3.0; 反应时间 40 min; 超声波功率 600 W 的条件下,COD、NH3-N、CN-和色度的去除率分别达95.8%、71.3%、69.5%和75.2%,出水COD降至41.0 mg/L.在相同条件下,US/Fenton试剂协同法的处理效率比单独Fenton试剂氧化法的处理效率提高了约20%,且反应时间显著缩短. 相似文献
287.
Glen W. Hess Byung R. Kim Philip J.W. Roberts 《Journal of the American Water Resources Association》1989,25(2):359-365
ABSTRACT: The presence of manganese in natural waters (>0.05 mg/L) degrades water-supply quality. A model was devised to predict the variation of manganese concentrations in river water released from an impoundment with the distance downstream. The model is one-dimensional and was calibrated using dissolved oxygen, biochemical oxygen demand, pH, manganese, and hydraulic data collected in the Duck River, Tennessee. The results indicated that the model can predict manganese levels under various conditions. The model was then applied to the Chattahoochee River, Georgia. Discrepancies between observed and predicted may be due to inadequate pH data, precipitation of sediment particles, unsteady flow conditions in the Chattahoochee River, inaccurate rate expressions for the low pH conditions, or their combinations. 相似文献
288.
真空碳酸钾脱硫工艺碱洗段废液因含有高浓度硫化物、COD等有毒成分而影响焦化废水后续生物处理。以焦化企业实际碱洗段废液为研究对象,选用化学沉淀和电催化氧化的组合方式对其进行预处理。结果表明,室温下当氧化铜的投加量为65 g/L、反应时间60 min时废液中S2-去除率可达93%,且经过高温灼烧可实现Cu O沉淀剂的再生使用。沉淀后出水经电催化氧化处理,在电流10 A、电压4.9 V、电解时间120 min的条件下,出水COD可降至2 400 mg/L,满足常规生化系统进水的要求。 相似文献
289.
The longwall gob (mined-out) area is one of the main places that are prone to coal spontaneous combustion and most of the residual coal in it is in oxygen-depleted air as it is a semi-enclosed space. A DSC (Differential scanning calorimetry) test system was designed to accurately test the heat generation of coal oxidation in different oxygen concentration atmosphere, based on which the kinetics parameters (activation energy and pre-exponential factor) of coal low-temperature oxidation in oxygen-depleted air were solved out. The results show that the kinetics parameters present obvious stage features and the lower the oxygen concentration is, the smaller is the difference of the kinetics parameters that in different oxidation stages. When the oxygen concentration is lower than 5% and 3% for jet coal and meagre coal respectively, the kinetics parameters of slow oxidation start to be greater than that of rapid oxidation. Both in the slow oxidation and rapid oxidation stage, with the decrease of oxygen concentration, kinetics parameters present significant decline on the whole while in different oxygen concentration range, the decline rate is different. It's concluded that when assessing the residual coal's self-heating risk, we need to use the corresponding kinetics parameters of coal oxidation in the oxygen concentration of the location where the residual coal is and the safety factor will be greater to only use the kinetics parameters of coal oxidation in slow oxidation stage. This study is of great significance for the assessment and control of the self-heating risk of coal that in different oxygen concentration atmospheres of the longwall gob areas. 相似文献
290.
OMS-2 nanorod catalysts were synthesized by a hydrothermal redox reaction method using MnSO4 (OMS-2-SO4) and Mn(CH3COO)2 (OMS-2-AC) as precursors. SO42 −-doped OMS-2-AC catalysts with different SO42 − concentrations were prepared next by adding (NH4)2SO4 solution into OMS-2-AC samples to investigate the effect of the anion SO42 − on the OMS-2-AC catalyst. All catalysts were then tested for the catalytic oxidation of ethanol. The OMS-2-SO4 catalyst synthesized demonstrated much better activity than OMS-2-AC. The SO42 − doping greatly influenced the activity of the OMS-2-AC catalyst, with a dramatic promotion of activity for suitable concentration of SO42 − (SO4/catalyst = 0.5% W/W). The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectroscopy (ICP-OES), NH3-TPD and H2-TPR techniques. The results showed that the presence of a suitable amount of SO42 − species in the OMS-2-AC catalyst could decrease the Mn–O bond strength and also enhance the lattice oxygen and acid site concentrations, which then effectively promoted the catalytic activity of OMS-2-AC toward ethanol oxidation. Thus it was confirmed that the better catalytic performance of OMS-2-SO4 compared to OMS-2-AC is due to the presence of some residual SO42 − species in OMS-2-SO4 samples. 相似文献