冷原子吸收法测汞用干燥剂的选择

冷原子吸收法测定样品中汞含量时,需要对汞蒸气进行干燥,本文就实验中常用的几种干燥剂的性能以及不同的干燥剂对方法灵敏度的影响进行了实验和探讨。     

在PVA_(124)─TritonX-100协同作用下Ag~+─邻菲啰啉─溴邻苯三酚红体系显色反应研究及应用

在PVA124－TritonX－100协同作用HAc-NaAc缓冲体系（pH6.5）中,Ag+与邻菲罗林-溴邻笨三酚红形成2：4：1紫红色三元络合物,其λmax=620nm,ε620＝7.0×104,Ag+浓度在0~14μg／25ml内遵循比耳定律。方法用于漂定液中微量银的测定,结果满意。     

Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - Principles and Purposes -

A voluntary programme on risk assessment for chlorinated chemicals was initiated by Euro Chlor (the European Chlorine Producers Federation). The study was targeted on the marine environment, starting with the North Sea, and the methodology used was based on the European Union risk assessment principles. Details of the method used are described in this paper. A first set of five compounds is published in this special issue: chloroform, 1,2-dichloroethane, 1,1,2-trichloroethane, trichloroethylene, tetrachloroethylene.     

基于SD-ABMS方法的航空应急医疗转运任务仿真系统

为解决我国航空应急医疗转运演练成本高昂及我国航空医疗转运任务执行机理相关研究不足的问题,依据真实的医疗转运场景,抽象出病患、飞行员、医护、机务、医院负责人、安保、环境等共16种Agent和详细的医疗转运流程;使用ABMS方法对各Agent的离散行为及Agent间的协同行为进行建模,使用SD方法对各Agent的连续行为进行建模, 从微观视角刻画并实现航空应急医疗转运任务仿真模型,并基于Anylogic实现航空应急医疗转运任务系统可视化原型。研究结果展示了航空应急医疗转运任务执行机理,可降低相关演练成本,也可为航空应急医疗转运实时任务评估提供支持。     

高分子除氯剂对水中氯离子的吸附机理

采用高分子除氯剂吸附水中的氯离子,考察了除氯剂投加量、反应时间、反应温度、竞争离子等对氯离子去除率的影响。实验结果表明:随着除氯剂投加量增加,氯离子去除率不断提高;吸附动力学符合拟二级动力学模型,表明化学吸附可能是氯离子吸附过程的速率控制步骤;Elovich模型表明除氯剂表面吸附的氯离子存在非均相扩散的吸附-脱附过程;Freundlich等温吸附模型能更好地描述吸附过程,结合热力学计算表明该过程是一个自发进行的吸热熵增的化学吸附过程,温度越高自发程度越大。     

Pesticides impact on Clavibacter michiganensis ssp. sepedonicus biofilm formation

The effect of various pesticides on the biofilm formation by the phytopathogenic bacterium Clavibacter michiganensis ssp. sepedonicus (Cms), the potato ring rot causative agent, was explored for the first time. Systemic herbicides: 2,4-D, diuron, glyphosate, clopyralid, fluorodifen, as well as the commercial preparations “Lazurite,” “Ridomil Gold,” and the mitochondria inhibiting pesticides analog, sodium monoiodoacetate, were studied. These pesticides' effect on the Cms biofilm formation was shown to be distinct and dependent on the agent under question. Cms biofilm formation was reduced when exposed to sodium monoiodoacetate, as well as “Lazurite” preparation, that could be due to the bactericidal effect of these agents. 2,4-D and “Ridomil Gold” preparation stimulated the biofilm formation. Systemic herbicides diuron, glyphosate, clopyralid, fluorodifen did not exert appreciable influence on the process of bacterial biofilm formation.     

Research on multilevel information loss of the sharing process for safety information

To reveal the mechanism of information loss in the flow of safety information, and to derive an evaluation method for describing this information loss, this paper analyzes the flow of safety information based on research in safety informatics and cognitive psychology. Theoretical analysis shows that the flow of safety information can be divided into four stages: transformation, transmission, perception, and cognition. This paper describes a simplified model of the flow of safety information based on these four stages. Then, the concept of adaptive subjects is introduced, and the sources and losses of safety information are explored. In addition, a model of safety information flow loss is constructed. This model is used to analyze the connection between the information loss at each stage of the sharing process, and then a “ladder hierarchical” model for the loss of safety information is developed. Comprehensive analysis of this ladder hierarchical model of safety information leads to a formal mathematical model of safety information loss. Finally, according to the various development stages of the safety information sharing process, four key factors that affect the multilevel information loss of the safety information sharing process are extracted by the hierarchical method.     

高压水射流卸压防治复合动力灾害机理及应用

为研究高压水射流卸压防治复合动力灾害的可行性,以余吾煤业高瓦斯矿井东翼采区内首采N2105工作面工程地质条件为背景,通过现场调研、理论分析、数值模拟和工业性试验等方法,对N2105进风平巷两帮采取高压水射流卸压防治效果进行了研究。结果表明:对巷帮煤体采取高压水射流卸压技术,煤体在高压水射流的冲击力和扰动应力波共同作用下瞬间发生破坏;巷帮侧支承应力分布曲线由原有的“单高峰值”转变为“内低外高双峰值”,受以上支承应力变化的影响,底板煤岩体内难以形成范围较大且连续的塑性应力状态区;现场电磁辐射和矿压监测结果表明高压水射流技术对煤层卸压增透效果显著,降低了巷道发生复合动力灾害的可能性。研究结果可为同类矿井复合动力灾害的防治提供参考和借鉴。     

中草药复合诱食剂对锦鲤的生长影响

选用80尾初始体长4.7cm左右、体色均一健康的锦鲤,随机分为4个组。其中,Ⅰ为对照组,饲喂基础饲料;Ⅱ、Ⅲ、Ⅳ为实验组,分别在基础饲料中添加100mL/kg、150mL/kg、200mL/kg的中草药复方。研究一副中草药复方对锦鲤诱食活性的影响,记录试验数据,并用Excel和SPSS软件进行分析。饲喂15d的结果表明,本实验所用该副中草药复方对锦鲤具有诱食反应。其中,Ⅱ组P=0.0010〈0.05、Ⅲ组P=0.0042〈0.05、Ⅳ组P=0.016〈0.05,说明其诱食效果有显著意义。不同浓度的中草药复方对锦鲤生长效果的影响差异很大,其中Ⅲ对锦鲤有显著的促生长作用。与对照组相比,增重率提高了23.090%,饵料系数降低了0.459。     

加入多孔球形颗粒微生物燃料电池的性能研究

设计了一个典型的双室微生物燃料电池,并考察了在阳极室加入多孔球形颗粒条件下对人工合成污水产电性能的影响。实验发现,加入多孔球形颗粒后,最高电压从不加颗粒的253 mV提高到280 mV,持续产电时间从5.5 d提高到8 d,COD去除率从78%提高到82.6%。进一步的实验发现,加入多孔球形颗粒后,系统内阻从286Ω降低到199.4Ω,最大功率密度从78.6 mW/m2提高到114.3 mW/m2。结果表明,微生物易于在多孔球形颗粒上附着和生长,颗粒通过均匀搅拌与阳极表面产生持续碰撞,有利于胞外电子传递到阳极,这一过程大大减小阳极的内阻,增大电池的输出电压进而增大输出功率,从而显著提高电池的产电性能。