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141.
朱忠林  蔡道基 《环境化学》1994,13(2):129-134
本文详细阐述了用碎片常数与结构因子法估测农药在正辛醇与水相体系中分配系数的方法,并对60种农药分配系数的估测结果与用经典的摇瓶测试法得到的实测值进行了比较,结果表明:估测结果与实测值基本吻合,碎片常数和结构因子估测法可以作为获得农药分配系数的另一种途径。  相似文献   
142.
为了揭示出海洋纤毛虫在人工海水中及不同温度下的种群动力学,利用实验生态学方法,就4种培养液及2种(17℃和23℃)温度对海洋纤毛虫扇形游仆虫(Euplotes vannus Mailer,1786)种群增长的影响进行了初步探讨.结果显示:①该种纤毛虫原生动物在4种人工海水培养液中的种群增长率大小顺序为:牛肉浸膏培养液〉米粒培养液〉酵母粉培养液〉蛋白胨培养液;②种群密度大小顺序依次为:米粒培养液〉牛肉浸膏培养液〉酵母粉培养液〉蛋白胨培养液;③指数增长期及稳定期在米粒培养液中均长于牛肉浸膏培养液;④随着培养温度的升高,种群增长率增大,指数增长期及稳定期缩短;⑤温度系数(Q10)的大小顺序为:蛋白胨培养液〉牛肉浸膏培养液〉米粒培养液〉酵母粉培养液.结果表明,米粒人工海水培养液不仅适合于保种培养,而且适合于种群的扩大培养,而牛肉浸膏培养液更适合于种群的快速扩大培养,其他两种培养液则只适合于保种培养.图2表4参13  相似文献   
143.
多氯联苯的气相色谱相对保留时间和理化性质预测模型   总被引:1,自引:0,他引:1  
  相似文献   
144.
农药和其它有机化合物环境参数的相关性及其预测   总被引:5,自引:0,他引:5  
莫汉宏  杨克武 《环境化学》1994,13(5):401-408
农药和其它有机化合物的水溶解度、正辛醇/水分配系数、有机碳吸附常数和生物浓缩因子等物化参数之间存在着明显的相关性,有机化合物的水溶解度与其正辛醇/水分配系数、有机碳吸附常数和生物浓缩因子呈负相关;正辛醇/水分配系数与有机碳吸附常数和生物浓缩因子呈正相关。本文所建立的数学关系式能较好地预测未知化合物的环境特性。  相似文献   
145.
Why do blue-eyed men prefer women with the same eye color?   总被引:1,自引:0,他引:1  
The human eye color blue reflects a simple, predictable, and reliable genetic mechanism of inheritance. Blue-eyed individuals represent a unique condition, as in their case there is always direct concordance between the genotype and phenotype. On the other hand, heterozygous brown-eyed individuals carry an allele that is not concordant with the observed eye color. Hence, eye color can provide a highly visible and salient cue to the child’s heredity. If men choose women with characteristics that promote the assurance of paternity, then blue-eyed men should prefer and feel more attracted towards women with blue eyes. To test these predictions, close-up photos of young women and adult men with either blue or brown eyes were rated for their attractiveness by young women and men observers with either blue or brown eyes (N=88). The eye color in the photographs of each model was manipulated so that a same face would be shown with either the natural eye color (e.g., blue) or with the other color (e.g., brown). Both blue-eyed and brown-eyed female participants showed no difference in their attractiveness ratings for male models of either eye color. Similarly, brown-eyed men showed no preference for either blue-eyed or brown-eyed female models. However, blue-eyed men rated as more attractive the blue-eyed women than the brown-eyed ones. We interpret the latter preference in terms of specific mate selective choice of blue-eyed men, reflecting strategies for reducing paternity uncertainty. In a second study, a group of young adults (N=443) of both sexes and different eye colors (blue, brown, and green) were asked to report the eye and hair color of their romantic partners. Their responses indicated the presence of assortative mating by eye color as well as, to a less degree, for hair color. Most importantly, blue-eyed male respondents were the group with the largest proportion of partners of same eye color. These findings 1) indicate that blue-eyed men do prefer women with the same eye color and 2) specifically suggest the presence of a male adaptation for the detection of extra-pair paternity based on eye color, as a phenotypically based assurance of paternity (i.e., when the father’s and offspring’s phenotypes match) as well as a defense against cuckoldry (i.e., when the phenotypes do not match).Electronic supplementary material Supplementary material is available in the online version of this article at and is accesseble for authorized users.  相似文献   
146.
气相色谱法估算多环芳烃的辛醇/水分配系数   总被引:2,自引:0,他引:2  
通过对2-6环多环芳烃(PAHs)气相色谱保留时间(RGC)与HPLC保留值及与辛醇/水分配系数(KOW)对应关系的研究,发现RGC与HPLC保留值主KOW间存在明显的线性相关关系,建立了RGC与KOW间的一元回归方程,并对包括EPA16种优先控制的PAHs在内的33种多环芳烃化合物的KOW值进行估算,估算值的相对误差为0.10%-12.10%,平均值为4.51%。  相似文献   
147.
Adsorption of hydrophobic contaminants at the particle/water interface is one of the key processes controlling their fate in the aquatic environment. The sorption of the natural female hormones oestrone and 17-oestradiol has been studied under simulated riverine conditions. Both the kinetics and the effects of varying fundamental environmental parameters (e.g. sediment properties) on the thermodynamic equilibrium partition coefficient (K p) have been studied in continuous and batch sorption experiments, respectively. Results showed that the sorption of oestrone and 17-oestradiol by sediment was relatively slow, reaching equilibrium in 50 days. In addition, relatively small adsorption of both oestrone and 17-oestradiol onto the sediment was observed, with K p values between 200 and 250 mL g–1. The comparable K p values of the two compounds reflect their structural similarity. It can be concluded that the two endocrine disruptors, oestrone and 17-oestradiol remain primarily in association with the aqueous phase.  相似文献   
148.
蔬菜对土壤镉铜锌富集能力的研究   总被引:3,自引:0,他引:3  
调查了福建部分污染严重地区不同蔬菜对镉、锌、铜的富集能力。结果表明蔬菜对镉的平均富集系数为0.017,锌的平均富集系数为0.116.铜的平均富集系数为0.014。蔬菜对镉的富集系数的品种间差异最大,达315倍,远高于锌和铜的富集系数的品种间差异。茭白、豇豆和莲藕对镉的富集能力较低,可作为镉污染土壤优先选种的蔬菜品种,而青包菜、白包菜、芥菜、空心菜、芋头等对镉的富集系数较高,不宜在镉污染土壤上栽培。  相似文献   
149.
For more than a decade, evidence has been accumulating that points to the fact that the microscopic roughness of the footwear soling surface is a major determinant of slip-resistance on lubricated surfaces, but conclusive experimental proof has been lacking. This article describes an experiment in which five pairs of shoes were soled with the same rubber compound. Four of the pairs were abraded by different grades of grit to produce a range of roughness values. The coefficient of friction (CoF) of the five solings was then measured repeatedly by the walking traction method on wet surfaces including glazed wall tiles, vinyl asbestos coated with the wax floor polish, and both sides of a sheet of float glass. The Kruskal-Wallis statistical test proved beyond doubt that the soling roughness is a major factor in determining the CoF of this rubber soling material; p < 10−5. Nearly all of the grip was due to surface roughness of the soling material on these atypically smooth floors, although the surface roughness of the floors also had a significant effect on CoF; p < 0.003. Float glass is shown to be a promising reference floor material for the measurement of CoF of footwear; there was no statistical difference between results for the two sides of the glass sheet. Float glass could be used in the development of a standard CoF test method because new sheets of glass from the same manufacturer are identical and extremely smooth. The specification of CoF values for solings/floors combinations in lubricated conditions is of little value unless associated with roughness measurements and knowledge of how wear will affect the surface roughness of the sole. This article reports the first evidence that any specification of flooring by measuring CoF based on dry surfaces could lead to an increase in the number of injuries caused by slipping on the wet surfaces. Published by Elsevier Science Ltd  相似文献   
150.
本文建立了准确预测多环芳烃(PAHs)及其烷基衍生物的正-辛醇/水分配系数(Kow)模型。模型表明PAHs的分配性质可用零阶价分子连接性指数(~°x~v)描述,~°x~v数值与PAHs的logKow成正比。应用本模型可以预测大范围PAHs的logKow值。  相似文献   
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