Evaluation of thermal hazard characteristics of four low temperature reactive azo compounds under isothermal conditions

The polymerization reaction can lower the threshold of the required energy by the initiator to improve the efficiency of the overall process reaction. Emerging polymerization initiators are also a major focus of process improvement and technological progress. Azo compounds (azos), which used in dyeing applications, are subsequently used in polymerization reactions due to their highly exothermic reaction characteristics. Although higher heat release can promote polymerization and modify the product, heat generation may also cause process hazards.These thermal hazard parameters were studied by selecting dimethyl 2,2′-azobis(2,4-dimethylvaleronitrile) (ABVN), 2,2′-azobis(2-methyl propionate) (AIBME), 2,2′-azobis(2-methylpropionamide) dihydrochloride (AIBA), and 2,2′-azobis(isobutyronitrile) (AIBN), which are common azo initiators at present. Thermal hazards are closely related to the reaction kinetics of the substance itself. The form of the reaction, the apparent activation energy and the thermodynamic parameters of the exothermic mode were also obtained.Kinetic analysis of the actual process using the experimental data of the isothermal calorimetry model is rarely used in the evaluation of related thermal hazard characteristics. The simulation results revealed the kinetic azo models and were further applied to calculate the runaway situations of azo under specific boundary conditions.     

不同冲击速度下硬煤的力学特性试验研究

为了研究硬煤破坏过程中的动态力学特性，采用Φ50 mm变截面分离式霍普金森压杆（SHPB）试验系统，对45#钢制薄壁套筒施加环向约束的硬煤试件进行不同加载速率的冲击压缩试验，得到被动围压下轴向应力-应变曲线、径向应力-应变曲线及最大被动围压和冲击速度的关系。研究结果表明:峰值应力、峰值应变随着冲击速度的增大而增大，最大被动围压值与冲击速度呈幂次增长的关系；被动围压下的硬煤试件变形受到限制，试件延性、抗压能力显著提高；随着冲击速度的增大，薄壁套筒对试件的约束也逐渐增大，达到峰值后，冲击速度对被动围压的影响减小，筒壁厚度影响着被动围压效果。     

湖北省湖泊资源特点及开发利用

通过对湖北省境内主要湖泊（面积大于１０ｋｍ＾２）的调查与分析，阐述了湖泊资源的几个特点，探讨了湖泊资源利用中存在的问题，并就湖泊资源的合理开发利用途径提出了建议。     

硅烷的危险特性及安全操作

硅烷作为一种提供硅组分的气体源 ,广泛应用于微电子、光电器件以及高纯度多晶硅生产 ,潜在应用前景更为广阔。随着硅烷应用领域的扩大 ,硅烷安全使用和处理已成为首要的问题。通过对硅烷着火的研究和事故分析表明 ,硅烷的危险特性在于它与氧反应的极强活性 :自燃 ,着火下限低 ,燃烧能量大。由于硅烷的自燃特性 ,对它的安全防范 ,与一般的易燃易爆物质相比 ,除一些共同点之外 ,还有显著的不同之处。在操作中必须预防高浓度硅烷与氧接触发生自燃着火。同时还必须防止硅烷泄漏在有限的空间内与氧混合 ,形成不稳定爆炸性气团。笔者综合分析和研讨了硅烷着火和爆炸的最新进展和成果 ,在实践经验和分析典型硅烷事故的基础上 ,提出了处理和使用硅烷的安全操作要点。     

苏北闵桥地区含油玄武岩中皂石的矿物学特征

作为储油层的沉积岩中蒙皂石矿物学特征报道较多，而作为储油层的火山岩中蒙皂石矿物学特征报道则较少。本文较详细地阐述了苏北闵桥地区含油玄武岩中主要蚀变矿物－皂石的形态、成分及X射线衍射、差热、红外特征，总结了鲍休皂石的形态特征，并对皂石的分布和成因作了探讨。认为加强皂石在油气地质，尤其是火山岩作为储油层中的应用研究十分必要。     

Environmental characteristics of sandstorm in Minqin Oasis in China for Recent 50 years

IntroductionAsandstormis a kind of severe weather phenomenawhere strong winds blowa huge amount of sand and dust intothe air ,reducing the horizontal visibility to less than 1 km( Wang, 2003a) . It is not only an important process ofaccelerating land dese…     

昆明市工业固体废弃物污染特征与控制对策研究

通过对昆明市工业固体废弃物排放与处理处置现状调查,深入系统地分析了昆明市工业固体废弃物产生量、构成、来源、综合利用率和处置率等污染特征,并对工业固废的增长趋势进行了预测。从立法、执法、管理等方面提出了相应的控制对策和建议。     

Electrochemical reduction characteristics and mechanism of nitrobenzene compounds in the catalyzed Fe-Cu process

The reduction of the nitrobenzene compounds （NBCs） by the catalyzed Fe-Cu process and the relationship between the electrochemical reduction characteristics of NBCs at copper electrode and reduction rate were studied in alkaline medium（pH=11）. The catalyzed Fe-Cu process was found more effective on degradation of NBCs compared to Master Builder＇s iron. The reduction rate by the catalyzed Fe-Cu process decreased in the following order： nitrobenzene 〉4-chloro-nitrobenzene ≥m-dinitrobenzene ：〉 4-nitrophenol ≥2,4-dinitrotoluene 〉2-nitrophenol. The reduction rate by Master Builder＇s iron decreased in the following order： m-dinitrobenzene ≥4-chloro-nitrobenzene 〉4-nitrophenol 〉2,4-dinitrotoluene ≈nitrobenzene 〉2-nitrophenol. NBCs were reduced directly on the surface of copper rather than by the hydrogen produced at cathode in the catalyzed Fe-Cu process. The reduction was realized by the hydrogen produced at cathode and Fe（OH）2 in Master Builder＇s iron, It is an essential difference in reaction mechanisms between these two technologies. For this reason, the reduction by the catalyzed Fe-Cu depended greatly on NBC＇s electron withdrawing ability.     

对防震减灾工作依法行政的探讨

《中华人民共和国防震减灾法》等一系列法律、规章的出台实施，规范了防震减灾的管理体制、行政执法，并将地震部门作为行政主体推向了依法行政的前沿。笔者结合自己在行政办事中心“窗口”的工作实际，对防震减灾依法行政工作的特点和存在问题进行一些简单的探讨。     

浅析绿色制造的战略环境评价

绿色制造的战略环境评价是实现可持续发展的关键技术 ,是协调环境与社会经济发展的重要手段。它要求在绿色制造初期———绿色设计阶段就考虑整个制造过程的环境影响 ,从决策源头上控制环境污染的产生和生态环境的破坏。本文从绿色制造的广义内涵入手 ,分析了绿色制造战略环境评价的理论基础和综合集成特性 ,并提出了战略环境评价的指标体系和综合集成评价方法。