天然黏土材料附着纳米TiO2对 电解锰渣中锰的吸附固定

采用机械球磨法对膨润土、硅藻土、高岭土3种天然黏土材料进行预处理,通过超声法将纳米TiO_2附着于其上制得复合材料,考察了不同复合材料加入量及养护时间条件下复合材料对电解锰渣中Mn的吸附固定效果。3种天然黏土材料中,硅藻土的平均粒径最小,比表面积和总孔隙度最大,对水中Mn的吸附量也最大。黏土材料附着纳米TiO_2后对电解锰渣中Mn的吸附固定效果较单纯黏土材料有明显改善。在养护时间为12 d、硅藻土附着纳米Ti O_2复合材料加入量为10%(w)的最佳条件下,Mn的TCLP浸出量较原电解锰渣下降了83.04%。     

建筑材料及制品燃烧性能试验规范概述

建筑材料和制品燃烧性试验规范对保证建筑物内人的生命安全和财产安全是极为重要的。笔者对美国、加拿大、欧盟、日本以及中国的建筑材料燃烧性能试验规范进行分析、比较和综述。通过研究认为美国和加拿大对建筑材料燃烧性能的要求和试验方法基本相似,他们主要针对材料的燃烧性、火焰传播进行检测;欧盟于2001年颁布了新的燃烧性分级体系,该分级体系包括专门针对铺地材料部分和针对其他所有建筑构件材料和产品部门;日本采用锥形量热计法(ISO5660)将内装饰材料分为不燃、准不燃和阻燃材料3个等级;我国对建筑材料的试验方法包括不燃性试验方法、墙和天花板内装饰材料的三级分级体系和铺地材料两级分级体系。     

一种机(针)织物与非织造布网络互穿复合材料的研究

本文主要对机织物与非织造布复合材料的网络互穿结构进行了描述,并从材料选择、单体试制、复合工艺方面进行了实践,研制出了较高透气性能和剥离强度的复合材料。     

遥感在生态与环境监测中的主要应用领域

遥感是一种以物理手段、数学方法和地学分析为基础的综合应用技术 ,具有宏观、综合、动态和快速的特点。在解决宏观尺度的环境问题时 ,卫星遥感可重复获取多种空间、不同时相和不同波谱分辨率的地球信息 ,是适宜于调查和研究这些主题的唯一的、最有效的工具。本文通过对遥感在环境与生态监测的主要应用领域进行概要阐述 ,旨在抛砖引玉 ,推动遥感在环境与生态监测中的广泛应用。     

Mitigation of peroxidative stress for barley exposed to cadmium in the presence of water-extractable organic matter from compost-like materials

The effects of water-extractable organic matter (WEOM) from compost-like materials on peroxidative stress were investigated for hydroponic culture of barley exposed to Cd. In the presence of WEOM, lipoxygenase activity and malondialdehyde, indices of peroxidative stress in barley, were significantly reduced, compared to those with Cd alone (5 μM) for a 30-d culture (p < 0.05). In addition, Cd uptake in the presence of WEOM samples was significantly lower than that in their absence (p < 0.05). These results indicate that the addition of WEOM can be effective in mitigating the peroxidative stress in barley exposed to Cd. Of the total Cd in the solution, 7–8% was complexed with WEOM, indicating that the complexation of Cd with WEOM is a minor factor in reducing Cd-induced stress in barley. The WEOM sample was purified by cation-exchange column and ultrafiltration to remove the nutrient minerals, such as Ca, Mg and Fe. When the purified WEOM was employed for hydroponic culture in the presence of Cd, significant decreases in peroxidative stress and Cd uptake were observed (p < 0.05). These results show that the organic components in WEOM contribute to the mitigation of peroxidative stress in barley exposed to Cd.     

Climate change,adaptation and Eco-Art in Singapore

Eco-Art has recently emerged as a potential means to place emphasis on environmental issues such as climate change, recycling and the metabolism of the city experienced both materially and conceptually within local, regional and global contexts. Such art presents the possibility of shaping civic practices in arenas beyond those of traditional planning domains. Adopting a pragmatic approach, which recognises the contextual pluralism that exists in debates regarding climate change, this paper is interested in how Eco-Art projects encourage the re-imagining of urban spaces within the context of sustainability, and flows of materials and the recycling of plastic in art specifically.     

An Analysis of the Effects of Land Use and Land Cover on Flood Losses along the Gulf of Mexico Coast from 1999 to 2009

Major coastal flooding events over the last decade have led decision makers in the United States to favor structural engineering solutions as a means to protect vulnerable coastal communities from the adverse impacts of future storms. While a resistance‐based approach to flood mitigation involving large‐scale construction works may be a central component of a regional flood risk reduction strategy, it is equally important to consider the role of land use and land cover (LULC) patterns in protecting communities from floods. To date, little observational research has been conducted to quantify the effects of various LULC configurations on the amount of property damage occurring across coastal regions over time. In response, we statistically examine the impacts of LULC on observed flood damage across 2,692 watersheds bordering the Gulf of Mexico. Specifically, we analyze statistical linear regression models to isolate the influence of multiple LULC categories on over 372,000 insured flood losses claimed under the National Flood Insurance Program per year from 2001 to 2008. Results indicate that percent increase in palustrine wetlands is the equivalent to, on average, a $13,975 reduction in insured flood losses per year, per watershed. These and other results provide important insights to policy makers on how protecting specific types of LULC can help reduce adverse impacts to local communities.     

Reducing Fertilizer‐Nitrogen Losses from Rowcrop Landscapes: Insights and Implications from a Spatially Explicit Watershed Model

We present conceptual and quantitative models that predict changes in fertilizer‐derived nitrogen delivery from rowcrop landscapes caused by agricultural conservation efforts implemented to reduce nutrient inputs and transport and increase nutrient retention in the landscape. To evaluate the relative importance of changes in the sources, transport, and sinks of fertilizer‐derived nitrogen across a region, we use the spatially explicit SPAtially Referenced Regression On Watershed attributes watershed model to map the distribution, at the small watershed scale within the Upper Mississippi‐Ohio River Basin (UMORB), of: (1) fertilizer inputs; (2) nutrient attenuation during delivery of those inputs to the UMORB outlet; and (3) nitrogen export from the UMORB outlet. Comparing these spatial distributions suggests that the amount of fertilizer input and degree of nutrient attenuation are both important in determining the extent of nitrogen export. From a management perspective, this means that agricultural conservation efforts to reduce nitrogen export would benefit by: (1) expanding their focus to include activities that restore and enhance nutrient processing in these highly altered landscapes; and (2) targeting specific types of best management practices to watersheds where they will be most valuable. Doing so successfully may result in a shift in current approaches to conservation planning, outreach, and funding.     

石墨烯材料去除重金属及放射性核素的研究

石墨烯及其改性材料具有比表面积大、吸附能力强、抗辐射性能好、耐高温、耐酸碱等优点,近年来在去除重金属和放射性核素领域得到了广泛关注.本文简要介绍了石墨烯的合成及改性方法,综述了石墨烯材料去除水中重金属离子和放射性核素的研究进展,包括吸附容量、影响因素、吸附动力学、吸附热力学模型和吸附机理,分析了该研究领域目前存在的问题,探讨了今后的研究方向.     

Immobilization of lead in anthropogenic contaminated soils using phosphates with/without oxalic acid

Understanding the effects of oxalic acid(OA) on the immobilization of Pb(Ⅱ) in contaminated soils by phosphate materials, has considerable benefits for risk assessment and remediation strategies for the soil. A series of phosphate amendments with/without oxalic acid were applied to two anthropogenic contaminated soils. We investigated the immobilization of Pb(Ⅱ) by KH2PO4, phosphate rock(PR), activated phosphate rock(APR) and synthetic hydroxyapatite(HAP) at different phosphate:Pb(P:Pb) molar ratios(0, 0.6, 2.0 and 4.0) in the presence/absence of 50 mmol oxalic acid/kg soil, respectively. The effects of treatments were evaluated using single extraction with deionized water or Ca Cl2, Community Bureau of Reference(BCR) sequential extraction and toxicity characteristic leaching procedure(TCLP)methods. Our results showed that the concentration of water extractable, exchangeable and TCLP-Pb all decreased with incubation time. The concentration of water-extractable Pb after120 days was reduced by 100% when soils were amended with APR, HAP and HAP + OA, and the TCLP-Pb was 5 mg/L for the red soil at P:Pb molar ratio 4.0. Water-soluble Pb could not be detected and the TCLP-Pb was 5 mg/L at all treatments applied to the yellow-brown soil. BCR results indicated that APR was most effective, although a slight enhancement of water-soluble phosphate was detected at the P:Pb molar ratio 4.0 at the beginning of incubation. Oxalic acid activated phosphates, and so mixing insoluble phosphates with oxalic acid may be a useful strategy to improve their effectiveness in reducing Pb bioavailability.