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Simultaneous elution of polycyclic aromatic hydrocarbons and heavy metals
from contaminated soil by two amino acids derived from β-cyclodextrins 总被引:1,自引:0,他引:1
Chengjian Yang Qingru Zeng Yunzhong Wang Bohan Liao Jian Sun Hui Shi Xingdou Chen 《环境科学学报(英文版)》2010,22(12):1910-1915
Two highly water-soluble amino acids,which derived from β-CDs,i.e.,glutamic acid-β-cyclodextrin (GluCD) and ethylene-diamineβ-cyclodextrin (EDCD),were synthesized and were examined for their effect on solubilization of anthracene (ANT),complexation of cadmium (Cd2+),and elution removal of ANT and Cd2+ in soil.The results showed that GluCD and EDCD were powerful complexant for ANT and Cd2+.In the presence of 10 g/L GluCD and EDCD,the solubilization of ANT increased by 47.04 and 23.85 times compared to the control,respectively.GluCD resulted in approximately 90% complexation of Cd2+ while 70% complexation was observed for EDCD.Simultaneously,GluCD and EDCD could greatly enhance the elution removal of ANT and Cd 2+ from soil.GluCD resulted in the highest elution efficiency of ANT and Cd2+.With the addition of 10 g/L GluCD,53.5% of ANT and 85.6% of Cd2+ were eluted,respectively.The ANT had a negligible effect on the Cd2+ removal due to different complexing sites of ANT and Cd2+,while Cd2+ enhanced the ANT removal under the addition of GluCD because Cd2+ neutralized the-COOH group of GluCD.Adversely,the removal of ANT was decreased with Cd2+ under the addition of EDCD,this was due to the fact that Cd2+ enhanced the polarity of EDCD molecule and inhibited the complexation between ANT and EDCD.The study suggested that GluCD could be preferred and be successfully applied to remediation of heavy metals or organic compounds in contaminated soil. 相似文献
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采用新型聚酰胺胺一环糊精共聚物(PAMAM—CD)静态吸附模拟废水中的2,4-二氯酚(DCP)。通过单因素和正交实验,研究了吸附时间、pH值、PAMAM—CD投加量(W)、溶液体积(V)、吸附温度(T)、溶液初始浓度(C0)等因素对吸附的影响,初步探讨了PAMAM—CD对DCP的吸附机理。实验结果表明:吸附条件对吸附容量(qe)的影响顺序为:C0〉W〉V〉T。最佳吸附条件:Co=150mg/L,W=25mg,V=75mL,T=15℃。在此条件下的qe平均值达105.6mg/g,说明PAM-AM—CD对DCP吸附能力强,吸附机理主要是因PAMAM-CD对DCP的包合、氢键等作用。 相似文献
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