动物性食品中PCBs的生物有效性及人体日暴露评估

通过测定上海市售动物性食品中PCBs的浓度和生物有效性,评估该地区PCBs的人体日暴露量.结果表明,不同种类食品中PCBs的浓度在未检出~3734.3pg/g(湿重)之间,3~6氯PCBs为主要同系物.鱼类中PCBs浓度高于畜类、禽类和软体类.鱼类PCBs的浓度水平遵循以下两规律:海水鱼>淡水鱼;肉食性鱼>杂食性鱼>草食性鱼.采用模拟人体胃肠消化过程测得PCBs的生物有效性,由于食品中脂肪含量与PCBs的生物有效性具有显著的线性关系,故可用于计算样品中PCBs的生物有效性.该地区居民每天通过动物性食品摄入的PCBs量为24439.3pg/d,以PCBs的生物有效性计量为5034.5pg/d.对不同暴露源(包括灰尘和大气颗粒物)的分析表明,鱼类是PCBs人体暴露的主要贡献者,约占人体PCBs日暴露的60%.     

黄山山底大气气溶胶数浓度日变化

利用美国MSP公司生产的宽范围粒径谱仪(WPS)于2011年5月至9月在黄山山底(寨西)采集的气溶胶观测数据,分析了黄山山底大气气溶胶数浓度的日变化特征.结果表明晴天气溶胶数浓度日变化特征明显,气溶胶粒子总数浓度在6:00,12:00和18:00达到峰值.人为活动,湍流混合及山谷风是影响黄山山底气溶胶日变化的主要因素.剔除交通污染时段后,气溶胶粒子数平均浓度减少319个/cm3,即减少12.17%.其中,0.01~0.02μm,0.02~0.05μm,0.05~0.1μm,0.1~0.5μm,0.5~1.0μm,1.0~2.5μm粒径段气溶胶粒子数浓度分别降低了31.32%,20.29%,6.59%,7.49%,1.23%,2.51%.机动车尾气排放对0.01~0.05μm粒径段气溶胶的影响最明显,其气溶胶浓度降低百分比为25.81%.     

Fish as an indicator of aquatic environment: Multielemental neutron activation analysis of nutrient and pollutant elements in fish from Indian coastal areas

Fish is the main food in coastal areas and its analysis for toxic metals has been used as an indicator of the pollution status of the aquatic environment. Several different fish species from the three Indian coasts, Visakhapatnam in the east, Mumbai in the west and Mangalore in the south west and also inland freshwater fish from Nagpur in the central region for comparison were analyzed for up to 20 elements (As, Au, Ba, Br, Cl, Co, Cr, Cu, Fe, Hg, K, Mn, Na, P, Rb, Sb, Sc, Se, Sr, Zn) by instrumental neutron activation analysis (INAA). Dried fish samples in powdered form were irradiated with thermal neutrons in a nuclear reactor followed by high resolution gamma ray spectrometry at different intervals. Several Reference Materials (RMs) of biological origin were analyzed for quality assurance and data validation. Elemental contents in different fish species vary in a wide range depending on the species, its size, location, and aquatic environment. Fish from Mangalore showed highest mean contents of Cr (14.8?±?29.9?µg?g^?1), Cu (1005?±?643?µg?g^?1) and Sb (849?±?888?ng?g^?1) whereas those from Mumbai exhibited highest Hg (2066?±?2146?ng?g^?1) and P (20.3?±?4.63?µg?g^?1) but lowest Cu (6.30?±?3.10?µg?g^?1) contents. Fish from all the regions showed significant amounts of nutrient elements such as Na, K, P, Mn, Fe, Se and Zn as well as some pollutant elements (Br, Cr, Sb, Hg). No regularity in variation of elemental contents with the size was observed. Prawn (Panaeus latisulcatus), a popular fish species from four different regions showed wide variation in elemental contents of Cr, Mn, Fe, Zn, Se, P including toxic pollutants, Sb and Hg. An attempt has been made to calculate daily dietary intake (DDI) for some nutrient elements from Indian fish. Elemental data for Cr, Cu, Fe, Hg, Se, and Zn have been compared with those from other fish exporting countries.     

基于日平均养殖量的畜禽养殖排污系数法的改进

传统的畜禽养殖排污系数污染负荷计算方法受养殖规模浮动影响,计算结果精度不高,只能计算整年污染负荷且无法计算某时段污染负荷。在分析传统畜禽产污系数法缺陷的基础上,探讨了日平均养殖量取代年养殖量的计算模式。依据不同类型畜禽养殖的周期特点,提出了各种类型畜禽养殖排污系数污染负荷计算公式和方法。最后,利用2008—2009年天津市宁河县生猪养殖污染负荷计算实例,对比分析了两种计算方法。结果表明,基于日平均养殖量的产污系数计算方法可以有效地减少由于养殖规模波动造成的计算误差,同时还适用于年内某时段污染负荷的计算,克服了传统方法只能以年为计算基本单元的弊端。     

Work‐related flow and energy at work and at home: A study on the role of daily recovery

In this diary study, we aimed to examine the moderating effects of the following: (i) recovery efforts at work and (ii) detachment from work on the relationship between work‐related flow and energy after work. Specifically, we hypothesized that flow would be beneficial for energy after work when employees failed (versus managed) to recover during work breaks. Additionally, we predicted that when employees experience flow at work, they would be more vigorous (and less exhausted) at the end of the day when they detached from work in the evening compared with days when they failed to detach. The study tracked 83 participants who completed daily surveys over four consecutive days. Results of multilevel analyses indicated that some characteristics of flow, such as absorption and enjoyment, were significantly associated with energy after work. Recovery at work and detachment from work moderated the relationship between flow (specifically the enjoyment component) and after‐work energy. Copyright © 2011 John Wiley & Sons, Ltd.     

基于均一化降水资料的中国极端降水特征分析

论文利用中国1961—2012年602个测站均一化的日降水资料,基于世界气象组织定义的11个极端降水指数,分析了近52 a中国极端降水事件的时空分布特征。结果表明：年极端降水指数长期变化趋势表明,大部分极端降水指数在我国西北和长江中下游地区（除CDD）以及东南沿海和华南大部分地区均呈现增加趋势,而在华北地区为减少趋势。极端降水指数随时间的变化表明,各指数具有明显的年际和年代际变化,从2000年开始大部分指数表现为不同程度的增加趋势,即极端降水事件从2000年开始偏多。     

我国政府应急管理日常机构的设置模式与制度架构

应急管理日常机构既负责政府应急管理的日常事务,又负责政府应急响应中的具体协调。当前,我国各级政府的应急办存在着权力过小、层级过低、能力有限、和其他机构职权冲突等问题,将其简单扩充、升级又会导致新问题,需要加以改革。在应急管理日常机构的各种代表性设置模式中,美国的FEMA值得借鉴。我国政府应当组建一个综合性的应急管理部门,整合部分职能单一的应急机构,并对其他履行应急管理职能的部门行使协调权,同时承担政府应急办公机构的职能。     

北京女性尿液中双酚A及氯代双酚A的浓度和风险评价

建立了有机相丹酰化衍生-UPLC-MS-MS人体尿液样品中双酚A(BPA)及4种氯代双酚A(氯代BPA)的检测方法,对北京地区40个女性尿液样品进行了检测.结果表明:BPA和一氯、二氯、三氯、四氯BPA的检出率分别为90%、96%、90%、52%和45%;浓度分别为(1.30±1.24),(0.40±0.37),(0.41±0.51),(0.18±1.49),(0.46±0.35) ng/mL,4种氯代BPA的总浓度为1.45ng/mL,和BPA浓度相仿.4种氯代BPA的BPA等当量浓度为4.84ng/mL,是BPA浓度的2.2倍. 40个尿液样本BPA等当量浓度符合对数正态分布,超过BPA的糖尿病发生阈值(0.05%发病风险)5.7ng/mL的概率为19.2%.人体暴露氯代BPA的健康风险应该引起重视.     

中国西南地区时雨量分布特征与时月变化

利用2005-2017年夏半年国家大监站的逐小时降水量资料,14个要素被设计来进行多角度分析。多数要素与地形高度有良好的负相关关系。时段雨量最大值主要集中地是四川盆地西部,其次是贵州南部,云南南部边缘地带有少许站点,云贵高原主体及其与青藏高原交接带内没有最大值出现。多个要素在9到12时出现日变化最高峰。月际变化一般在7月出现最大值。随月份推进,强降水区会在贵州西南部、云南南部边缘出现后,跳跃到川渝地区出现。时段累积雨量最大值随时间增加而增加,多个要素的时间增加一倍时雨量增大10%到20%。以小时而言,西南地区降水几率平均为1/10,最多的可以达到1/4,最少的不到1/14。6月份降水时数最多,10月的雨时数仅次于6月,4月最少。连续时段与标准日界时段雨量的显著差异出现在川渝地区;白天12 h降水与夜间12 h降水的显著差异也出现在川渝地区。总体而言,连续时段的累积雨量大于标准日界的相同时间长度的累积雨量,白天降水量大于夜间降水量。     

连续采样和间断采样监测大气中SO2平均浓度的研究

本文通过对连续采样和间断采样监测大气ＳＯ２浓度的对比实验数据进行分析，认为２４ｈ逐时间断采样的ＳＯ２浓度平均值和连续采样的ＳＯ２日平均浓度之间没有偏差，而几个时刻间断采样的平均值与连续值采样的日平均浓度存在显著性差异。