高位铁皮水箱供水质量及影响因素

我们于１９９５年３月￣４月调查了武汉市高位铁皮水箱的供水质量。结果表明：高层住宅水箱近年虽曾清洗消毒，但高层用户龙头水及水箱水中游离性全氯未达标比例较大，分别为７３．３％和６６．７％。个别底层住户水样中铁超标。高位水箱水样中细菌总数超标比例为２０％。反映了高层住宅二次供水中在水的输送、贮存过程中有二次污染存在。经水样监测指标相关性和灰色关联性分析，认为游离性余氯可作为常规监测高层住宅二次供水质量的     

田湾核电站外围辐射环境监测工作的质量保证

总结了田湾核电站外围辐射环境监测中的质量保证实施情况，包括：人员培训和考核，仪器设备溯源，样品采集、运输、贮存及生物样品前处理的质控，样品分析和现场监测的质控，数据的记录处理和管理要求等，最后提出几点建议。     

排污申报数据审核的一般方法

排污申报登记工作具有数据量大、逻辑性强、专业要求高的特点,环保部门必须力求通过强化数据的审核来获得完整、准确的排污申报数据。     

Spatial inhomogeneity in pollutant concentrations, and their implications for air quality model evaluation

The Southern California Air Quality Study database provides a valuable resource with which to test urban-scale photochemical models and to achieve a better understanding of the atmospheric dynamics of pollutant formation. The CIT model was evaluated using the SCAQS database according to traditional model performance guidelines. A first application, reported previously, focused on model enhancement and application of the model to the 27–29 August 1987 episode. This study evaluates the CIT model using the 24–25 June SCAQS episode, providing further evaluation of the model. Results show that the CIT airshed model can follow the diurnal variations of reactive species and the transport for relatively unreactive species. The normalized gross error for ozone was 31 % in June compared to 38% in August. However, to fully judge model performance in proper perspective, a question arises: “How well do the measurements reflect the air quality surrounding the monitoring station, not just in that location?” This is an important but seldom quantitatively considered factor, not only in model evaluation but in the study of health effects as well. Analyses indicate that individual concentration measurements only approximately represent the true volume-averaged concentrations within a computational grid cell and that significant spatial variations exist. Thus any evaluation of models using these data sets should take these local variations into consideration. A series of tests found that the local inhomogeneities had a normalized gross error in the range of 25–45% depending on the pollutant. In this context, the performance of the CIT model is consistent with known modeling limitations such as emissions inventories and sub-grid scale variation of observations.     

京津冀民用燃煤减排对大气中BaP污染影响评估

运用空气质量模型CMAQ模拟评估民用燃煤减排政策对京津冀大气中BaP污染状况的改进效果,模拟包括作为基准情景的2014年和低消减和高消减2个减排情景.模拟结果表明：基准情景下,京津冀BaP年均浓度为2.54ng/m³,超过国家空气质量标准（1ng/m³）,呈现1月 > 4月 > 10月 > 7月的季节变化特点,反映出冬季供暖燃煤的影响;京津冀南部BaP浓度高于北部,推测原因是南部BaP排放量较高.1月削减民用燃煤排放量对降低该地区BaP浓度和沉降量效果最显著,低削减和高削减下,北京、保定、廊坊BaP浓度分别比基准情景降低30%和40%以上;4、7、10月削减民用燃煤排放量对该地区BaP浓度和沉降量的变化影响不大.京津冀民用燃煤联防联控能更加有效地降低该地区BaP浓度.     

城市黑臭水体的吸收特性分析

黑臭水体是城市水环境的一个严重问题,对城市黑臭水体光学特性进行分析,是利用遥感技术手段进行黑臭识别的前提与基础.2016~2017年采集了长沙、南京和无锡的城市黑臭水体共计85个样点,非黑臭水体共计80个样点,并对水样的悬浮物等水质参数浓度以及水体组分的吸收系数进行了测量.结果表明:(1)黑臭水体的总颗粒物吸收系数、非色素颗粒物吸收系数总体上高于非黑臭水体.(2)黑臭水体与非黑臭水体的CDOM吸收系数有明显的差异.由此可用CDOM吸收特征波段440 nm和不同波段范围内拟合的吸收系数曲线斜率对黑臭水体进行区分.城市黑臭水体吸收特性的分析,将为黑臭水体的遥感识别和监测提供有效的技术支撑.黑臭水体中的高CDOM浓度,可以作为遥感识别黑臭水的一个重要参考.     

产品生命周期可得性水足迹计算方法

水足迹方法试图量化评价人类活动对水资源可得性的影响,从而为水资源可持续利用提供科学的依据.水足迹的评价方法尚未统一,目前全球应用最为广泛的是WFN（water footprint network,水足迹协作网络）水足迹计算方法.基于LCA（life cycle assessment,生命周期评价）方法的基本框架,围绕水资源可得性的水量、水质和空间分布3个因素,在分析现有水足迹计算公式的基础上,指出了WFN水足迹计算方法的不足.根据国际水足迹标准（ISO 14046）的原则和要求,改进了WFN的水足迹计算公式,提出了产品生命周期WAF（water availability footprint,可得性水足迹）定义和评价方法,其中包括单元过程数据计算、背景过程数据处理和生命周期汇总.通过方法对比和案例研究得到:WAF方法统一了水消耗量与水污染量定义中的水质基准,可以明确区分水污染和水净化两类过程,还可以反映区域水资源稀缺程度的影响;采用WAF方法,在现有LCA数据库和软件的支持下可以更为规范地完成生命周期水足迹建模与计算但目前单元过程数据计算中各种污染物的基准浓度选取有不可避免的主观性,将直接影响到水足迹计算结果及其客观性,有待进一步研究.      

Are current Chinese national ambient air quality standards on 24-hour averages for particulate matter sufficient to protect public health?

With rapid economic development and urbanization in recent decades, China has experienced the worsening of ambient air quality. For better air quality management to protect human health, Chinese government revised national ambient air quality standards(NAAQS) for particulate matter(PM) in 2012(GB3095-2012). To assess the effectiveness of current NAAQS for PM on public health in Chinese population, we conducted a metaanalysis on published studies examining the mortality risk of short-term exposure to PM with aerodynamic diameters less than 10 and 2.5 μm(PM_(10) and PM_(2.5)) in China. The reported24-hour concentrations of PM_(10) and PM_(2.5) in studies ranged from 43.5 to 150.1 μg/m~3 and 37.5 to 176.7 μg/m~3. In the pooled excess, mortality risk estimates of short-term exposure to PM.In specific, per 10 μg/m~3 increase in PM_(10), we observed increases of 0.40%(95%CI: 0.33%,0.47%), 0.57%(95%CI: 0.44%, 0.70%) and 0.49%(95%CI: 0.40%, 0.58%) in total, respiratory and cardiovascular mortality, per 10 μg/m~3 increase in PM_(2.5), we observed increases of 0.51%(95%CI: 0.38%, 0.63%), 0.62%(95%CI: 0.52%, 0.73%) and 0.75%(95%CI: 0.54%, 0.95%) in total,respiratory and cardiovascular mortality. Finally, we derived 125 μg/m~3 for PM_(10) and 62.5 μg/m~3 for PM_(2.5) as 24-hour recommendation values based on the pooled estimates. Our results indicated that current Chinese NAAQS for PM could be sufficient in mitigating the excess mortality risk from short-term exposure to ambient PM. However, future research on longterm exposure cohort studies in Chinese population is also essential in revising annual averages for PM in Chinese NAAQS.     

三峡库区EFDC模型集成与应用

为满足三峡库区大尺度的水质预测需求,降低专业水质模型使用门槛,实现模型业务化运行,采用涵盖"模型封装-接口服务-系统集成"全过程的模型封装集成技术方法,开展了EFDC模型集成研究,并在三峡库区水质安全评估与预警系统中进行验证和应用.结果表明:①基于实例化模型建立的模型预置参数库,是模型业务化运行中参数简化的前提,可有效解决模型本地驯化及模型实例的基础数据复用问题;②依据参数识别结果,将模型参数识别为"必调参数、可调参数、默认参数"三类,并采用B/S架构对输入文件、输出文件和主控文件中的不同参数进行分类封装,达到参数简化目的;③采用半紧密型方式建立的基于Web services的EFDC模型集成接口服务及标准,可为信息系统提供通用的EFDC模型计算服务;④该方法在EFDC模型与三峡库区水质安全评估与预警系统集成中得到验证,实现了全库区干流及主要支流COD_Cr、总磷、总氮等污染因子的长时间序列水动力水质预测联机在线运算,满足了用户在水质影响预测预警中低修改量、高运算效率和良好用户体验等需求,实现了模型的业务化运行.