全文获取类型
收费全文 | 2829篇 |
免费 | 393篇 |
国内免费 | 1392篇 |
专业分类
安全科学 | 258篇 |
废物处理 | 218篇 |
环保管理 | 300篇 |
综合类 | 2357篇 |
基础理论 | 532篇 |
污染及防治 | 653篇 |
评价与监测 | 108篇 |
社会与环境 | 138篇 |
灾害及防治 | 50篇 |
出版年
2024年 | 7篇 |
2023年 | 59篇 |
2022年 | 92篇 |
2021年 | 120篇 |
2020年 | 127篇 |
2019年 | 138篇 |
2018年 | 139篇 |
2017年 | 132篇 |
2016年 | 175篇 |
2015年 | 181篇 |
2014年 | 194篇 |
2013年 | 361篇 |
2012年 | 301篇 |
2011年 | 258篇 |
2010年 | 211篇 |
2009年 | 219篇 |
2008年 | 175篇 |
2007年 | 239篇 |
2006年 | 237篇 |
2005年 | 187篇 |
2004年 | 171篇 |
2003年 | 152篇 |
2002年 | 114篇 |
2001年 | 72篇 |
2000年 | 97篇 |
1999年 | 89篇 |
1998年 | 69篇 |
1997年 | 54篇 |
1996年 | 39篇 |
1995年 | 39篇 |
1994年 | 40篇 |
1993年 | 39篇 |
1992年 | 19篇 |
1991年 | 16篇 |
1990年 | 11篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 15篇 |
1981年 | 2篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有4614条查询结果,搜索用时 15 毫秒
321.
We report measurements of solubility limits for benzene, toluene, and TCE in systems that contain varying levels of biomass up to 0.13 g mL−1 for TCE and 0.25 g mL−1 for benzene and toluene. The solubility limit increased from 21 to 48 mM when biomass (in the form of yeast) was added to aqueous batch systems containing benzene. The toluene solubility limit increased from 4.9 to greater than 20 mM. For TCE, the solubility increased from 8 mM to more than 1000 mM. Solubility for TCE (trichloroethylene) was most heavily impacted by biomass levels, changing by two orders of magnitude as the microbial concentrations approach those in biofilms. 相似文献
322.
This study focuses on the verification of test interpretations for different state analyses of diffusion experiments. Part 1 of this study identified that steady, quasi-steady and equilibrium state analyses for the through- and in-diffusion tests with solution reservoirs are generally feasible where the tracer is not highly sorptive. In Part 2 we investigate parameter identifiability in transient-state analysis of reservoir concentration variation using a numerical approach. For increased generality, the analytical models, objective functions and Jacobian matrix necessary for inverse analysis of transient-state data are reformulated using unified dimensionless parameters. In these dimensionless forms, the number of unknown parameters is reduced and a single dimensionless parameter represents the sorption property. The dimensionless objective functions are evaluated for individual test methods and parameter identifiability is discussed in relation to the sorption property. The effects of multiple minima and measurement error on parameter identifiability are also investigated. The main findings are that inverse problems for inlet and outlet reservoir concentration analyses are generally unstable and well-posed, respectively. Where the tracer is sorptive, the inverse problem for the inlet reservoir concentration analysis may have multiple minima. When insufficient measurement data is collected, multiple solutions may result and this should be taken into consideration when inversely analyzing data including that of inlet reservoir concentration. Verification of test interpretation by cross-checking different state analyses is feasible where the tracer is not highly sorptive. In an actual experiment, test interpretation validity is demonstrated through consistency between theory and practice for different state analyses. 相似文献
323.
Bauer RD Maloszewski P Zhang Y Meckenstock RU Griebler C 《Journal of contaminant hydrology》2008,96(1-4):150-168
Various abiotic and biotic processes such as sorption, dilution, and degradation are known to affect the fate of organic contaminants, such as petroleum hydrocarbons in saturated porous media. Reactive transport modeling of such plumes indicates that the biodegradation of organic pollutants is, in many cases, controlled by mixing and therefore occurs locally at the plume's fringes, where electron donors and electron-acceptors mix. Herein, we aim to test whether this hypothesis can be verified by experimental results obtained from aerobic and anaerobic degradation experiments in two-dimensional sediment microcosms. Toluene was selected as a model compound for oxidizable contaminants. The two-dimensional microcosm was filled with quartz sand and operated under controlled flow conditions simulating a contaminant plume in otherwise uncontaminated groundwater. Aerobic degradation of toluene by Pseudomonas putida mt-2 reduced a continuous 8.7 mg L(-1) toluene concentration by 35% over a transport distance of 78 cm in 15.5 h. In comparison, under similar conditions Aromatoleum aromaticum strain EbN1 degraded 98% of the toluene infiltrated using nitrate (68.5+/-6.2 mg L(-1)) as electron acceptor. A major part of the biodegradation activity was located at the plume fringes and the slope of the electron-acceptor gradient was steeper during periods of active biodegradation. The distribution of toluene and the significant overlap of nitrate at the plume's fringe indicate that biokinetic and/or microscale transport processes may constitute additional limiting factors. Experimental data is corroborated with results from a reactive transport model using double Monod kinetics. The outcome of the study shows that in order to simulate degradation in contaminant plumes, detailed data sets are required to test the applicability of models. These will have to deal with the incorporation of existing parameters coding for substrate conversion kinetics and microbial growth. 相似文献
324.
廖金凤 《生态与农村环境学报》1998,(4)
海南省位于我国热带地区,草本植物微量元素组成可反映热带区域生物地球化学特点。海南植物微量元素含量属正常范围值,仅个别植物Cd、Hg含量偏高。植物Zn、Cu、Mo含量大多在5mg/kg以上,Pb、Cu、Cd含量一般低于2mg/kg,Hg、As、Ni通常不足1mg/kg。雀稗(Paspalumcommersoni)、地胆草(Elephantopusscaber)等微量元素含量普遍较高。红裂稃草(Schizachyriumsanguineum)、白茅(Imperatacylindrica)等微量元素含量一般较低。植物微量元素组成与植物种类及其生境条件有关。生物吸收系数反映植物摄取元素的强度,Mo、Cd、Hg、Zn、Cu的生物吸收系数通常大于1.0,属强积聚元素,Pb、Cr、Ni、As的生物吸收系数大多低于0.3,是弱摄取元素。 相似文献
325.
垂直面绿化植物遮阳系数与叶面积指数研究 总被引:6,自引:0,他引:6
李娟 《城市环境与城市生态》2001,14(5):4-5
比较、分析了农业研究中提出的叶面积指数LAI与用于建筑节能领域的垂直面绿化植物叶片遮阳系数SCPVW两个概念的异同和各自的应用范围。指出城市绿化采用水平或垂直绿化方式时,由于下垫面差异,植物叶片的遮阳系数应当分别采用LAI和SCPVW进行计算。 相似文献
326.
杀虫单降解菌的筛选分离与降解特性研究 总被引:8,自引:0,他引:8
从农药厂废水排放沟污泥中分离到一株对杀虫单有较强降解能力的菌株LY-4,经鉴定为巨大芽孢杆菌(Bacillus megaterium)。其生长的最适pH为7,最适温度为30℃。该菌对杀虫单有很强的耐受性,在杀虫单浓度ρ=5000mg/L时,仍能较好地生长并发挥降解作用。当杀虫单初始浓度高于一定值时,一定量的菌剂对杀虫单的降解率随底物浓度的提高而降低,而绝对去除量则随底物浓度的提高而提高。与不加菌的对照相比,加入LY-4后,可使杀虫单浓度在很短的时间内降到很低的水平。图5表1参6 相似文献
327.
328.
329.
邓继 《环境监测管理与技术》2014,26(1):66-70
选取上海市7家未安装气-气换热器的国控燃煤电厂作为研究对象,从煤质、除尘器、脱硫协同脱除作用以及锅炉工况负荷等方面探讨对颗粒物浓度排放系数 K值产生的影响,得出上述因素通过改变脱硫进口颗粒物浓度值影响 K值,当脱硫进口颗粒物浓度较低、波动范围较小时,其 K值也维持相对稳定的状态;当脱硫进口颗粒物浓度较高、波动范围较大时,其 K值也会发生较大的变化等结论。 相似文献
330.
采用EPAMethod29方法、冷原子吸收光谱法和电感耦合等离子体质谱法采集和分析一台超低排放燃煤机组污泥掺烧前后的原燃料、烟气和副产物样品中各痕量元素浓度,研究污泥掺烧对燃煤电厂痕量元素排放特性的影响.结果表明:污泥中富含Zn、Cu元素,浓度分别是煤样中的18.81倍和17.64倍.污泥掺烧使掺配后入炉煤中痕量元素含量普遍升高.污泥掺烧前后整个系统、锅炉系统和全流程大气污染控制设施的痕量元素质量平衡率均在可接受范围内.污泥掺烧对痕量元素的分布特征无明显影响,随粉煤灰排放是痕量元素的主要排放去向.通过烟囱排放到大气环境的痕量元素排放量占比很小,不超过0.43%.污泥掺烧前后SCR入口烟气中痕量元素除Hg外主要以颗粒态形式存在.污泥掺烧后各痕量元素在粉煤灰和底渣中的相对富集系数未显著改变.经过全流程大气污染控制设施协同控制后,污泥掺烧前后烟囱总排口痕量元素排放浓度分别为0~12.76,0~14.97μg/m3.污泥掺烧后痕量元素排放浓度均满足美国燃煤发电机组有害大气污染物排放标准、上海市燃煤耦合污泥电厂大气污染排放标准和生态环境部生活垃圾焚烧污染控制标准的限值要求.... 相似文献