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81.
J. Juri Ayub D.E. Di Gregorio H. Velasco H. Huck M. Rizzotto F. Lohaiza 《Journal of environmental radioactivity》2009
The 7Be wet deposition has been intensively investigated in a semiarid region at San Luis Province, Argentina. From November 2006 to May 2008, the 7Be content in rainwater was determined in 58 individual rain events, randomly comprising more than 50% of all individual precipitations at the sampling period. 7Be activity concentration in rainwater ranged from 0.7 ± 0.3 Bq l−1 to 3.2 ± 0.7 Bq l−1, with a mean value of 1.7 Bq l−1 (sd = 0.53 Bq l−1). No relationship was found between 7Be content in rainwater and (a) rainfall amount, (b) precipitation intensity and (c) elapsed time between events. 7Be ground deposition was found to be well correlated with rainfall amount (R = 0.92). For the precipitation events considered, the 7Be depositional fluxes ranged from 1.1 to 120 Bq m−2, with a mean value of 32.7 Bq m−2 (sd = 29.9 Bq m−2). The annual depositional flux was estimated at 1140 ± 120 Bq m−2 y−1. Assuming the same monthly deposition pattern and that the 7Be content in soil decreases only through radioactive decay, the seasonal variation of 7Be areal activity density in soil was estimated. Results of this investigation may contribute to a valuable characterization of 7Be input in the explored semiarid ecosystem and its potential use as tracer of environmental processes. 相似文献
82.
Soil and atmospheric concentrations, dry deposition and soil-air gas exchange of organochlorine pesticides (OCPs) were investigated at an industrial site in Aliaga, Izmir, Turkey. Current-use pesticides, endosulfan and chlorpyrifos, had the highest atmospheric levels in summer and winter. Summertime total (gas + particle) OCP concentrations in air were higher, probably due to increased volatilization at higher temperatures and seasonal local/regional applications of current-use pesticides. Particle deposition fluxes were generally higher in summer than in winter. Overall average dry particle deposition velocity for all the OCPs was 4.9 ± 4.1 cm s−1 (average ± SD). ΣDDXs (sum of p,p′-DDT, p,p′-DDD, and p,p′-DDE) were the most abundant OCPs in Aliaga soils (n = 48), probably due to their heavy historical use and persistence. Calculated fugacity ratios and average net gas fluxes across the soil-air interface indicated volatilization for α-CHL, γ-CHL, heptachlorepoxide, cis-nonachlor, trans-nonachlor, and p,p′-DDT in summer, and for α-CHL, γ-CHL, trans-nonachlor, endosulfan sulfate, and p,p′-DDT in winter. For the remaining OCPs, soil acted as a sink during both seasons. Comparison of the determined fluxes showed that dry particle, gas-phase, and wet deposition are significant OCP input mechanisms to the soil in the study area. 相似文献
83.
Influence of temporally variable groundwater flow conditions on point measurements and contaminant mass flux estimations 总被引:2,自引:0,他引:2
Arno Rein Sebastian Bauer Peter Dietrich Christof Beyer 《Journal of contaminant hydrology》2009,108(3-4):118-133
Monitoring of contaminant concentrations, e.g., for the estimation of mass discharge or contaminant degradation rates, often is based on point measurements at observation wells. In addition to the problem, that point measurements may not be spatially representative, a further complication may arise due to the temporal dynamics of groundwater flow, which may cause a concentration measurement to be not temporally representative. This paper presents results from a numerical modeling study focusing on temporal variations of the groundwater flow direction. “Measurements” are obtained from point information representing observation wells installed along control planes using different well frequencies and configurations. Results of the scenario simulations show that temporally variable flow conditions can lead to significant temporal fluctuations of the concentration and thus are a substantial source of uncertainty for point measurements. Temporal variation of point concentration measurements may be as high as the average concentration determined, especially near the plume fringe, even when assuming a homogeneous distribution of the hydraulic conductivity. If a heterogeneous hydraulic conductivity field is present, the concentration variability due to a fluctuating groundwater flow direction varies significantly within the control plane and between the different realizations. Determination of contaminant mass fluxes is also influenced by the temporal variability of the concentration measurement, especially for large spacings of the observation wells. Passive dosimeter sampling is found to be appropriate for evaluating the stationarity of contaminant plumes as well as for estimating average concentrations over time when the plume has fully developed. Representative sampling has to be performed over several periods of groundwater flow fluctuation. For the determination of mass fluxes at heterogeneous sites, however, local fluxes, which may vary considerably along a control plane, have to be accounted for. Here, dosimeter sampling in combination with time integrated local water flux measurements can improve mass flux estimates under dynamic flow conditions. 相似文献
84.
Sally R. Gadsdon Sally A. Power 《Environmental pollution (Barking, Essex : 1987)》2009,157(10):2845-2852
NO2 and NH3 concentrations were measured across a Special Area for Conservation in southern England, at varying distances from the local road network. Exceedances of the critical levels for these pollutants were recorded at nearly all roadside locations, extending up to 20 m away from roads at some sites. Further, paired measurements of NH3 and NO2 concentrations revealed differences between ground and tree canopy levels. At “background” sites, away from the direct influence of roads, concentrations were higher within tree canopies than at ground level; the reverse pattern was, however, seen at roadside locations. Calculations of pollutant deposition rates showed that nitrogen inputs are dominated by NH3 at roadside sites. This study demonstrates that local traffic emissions contribute substantially to the exceedance of critical levels and critical loads, and suggests that on-site monitoring is needed for sites of nature conservation value which are in close proximity to local transport routes. 相似文献
85.
Ranjan Mukherjee Animita Barua Ujjaini Sarkar Bijay Kumar De Alak Kumar Mandal 《International Journal of Greenhouse Gas Control》2009,3(5):664-672
The rice fields, depleted of O2, contain large amount of moisture and organic substrates to provide an ideal anaerobic environment for methanogenesis and are one of the principal anthropogenic sources of methane. In order to mitigate this emission Alternative Electron Acceptors (AEA) were altered in the soil. The experiments were carried out in four seasons at the site of Balarampur, near Baruipur, South 24 Parganas, West Bengal, namely September–December, 2005 (Cultivar: Sundari), February–May, 2006 (Cultivar: Sundari), September–December, 2006 and February–May, 2007 (Cultivar: Swarna-Pankaj). The seasonal average methane flux (Fe treated), for the cultivar type “Sundari” (season: September–December, 2005), is 4.41 t ha−1, as compared to the value of 6.40 t ha−1 for the untreated soil. Similarly for February–May, 2006, the seasonal average methane flux (Fe treated) is 5.52 t ha−1, whereas the untreated flux is 5.69 t ha−1. In the third and fourth seasons we had two treatments with Ammonium Thiosulphate and Ferric Hydroxide. The seasonal average methane flux (treatment: Ammonium Thiosulphate) is 4.35 t ha−1 and 5.41 t ha−1 respectively, whereas for the ferric hydroxide treated soil it is 4.35 t ha−1 and 6.14 t ha−1 respectively. The properties related to the nutrient quality of the harvested paddy seeds supplement these results. 相似文献
86.
David Moncoulon Anne Probst Liisa Martinson 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):307-316
To evaluate the acid deposition reduction negotiated for 2010 within the UNECE LRTAP Gothenburg Protocol, sulphur and nitrogen
deposition time-series (1880–2100) were compared to critical loads of acidity on five French ecosystems: Massif Central basalt
(site 1) and granite (2); Paris Bassin tertiary sands (3); Vosges mountains sandstone (4) and Landes eolian sands (5). The
SAFE model was used to estimate the response of soil solution pH and ratio to the deposition scenario. Among the five sites, critical loads were exceeded in the past at sites 3, 4 and 5. Sites
3 and 4 were still expected to exceed in 2010, the Protocol year. Further reduction of atmospheric deposition, mainly nitrogen,
would be needed to achieve recovery on these ecosystems. At sites 3, 4 and 5, the delay between the critical load exceedance
and the violation of the critical chemical criterion was estimated to be 10 to 30 years in the top soil and 50 to 90 years
in the deeper soil. At site 5, a recovery was expected in the top soil in 2010 with a time lag of 10 years. Unexpectedly,
soil pH continued to decrease after 1980 in the deeper soil at sites 2 and 5. This time lag indicated that acidification moved
down the soil profile as a consequence of slow base cation depletion by ion exchange. This delayed response of the soil solution
was the result of the combination of weathering rates and vegetation uptake but also of the relative ratio between base cation
deposition and acid compounds. 相似文献
87.
Marcos A. dos Santos Cynthia F. Illanes Adalgiza Fornaro Jairo J. Pedrotti 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):85-92
During the period from July 2002 to June 2004, the chemical characteristics of the rainwater samples collected in downtown São Paulo were investigated. The analysis of 224 wet-only precipitation samples included pH and electrical conductivity, as well as major ions (Na+, $ \rm NH^{ + }_{4} During the period from July 2002 to June 2004, the chemical characteristics of the rainwater samples collected in downtown
S?o Paulo were investigated. The analysis of 224 wet-only precipitation samples included pH and electrical conductivity, as
well as major ions (Na+, , K+, Ca2+, Mg2+, Cl−, , ) and carboxylic acids (acetic, formic and oxalic) using ion chromatography. The volume weighted mean, VWM, of the anions
, and Cl− was, respectively, 20.3, 12.1 and 10.7 μmol l−1. Rainwater in S?o Paulo was acidic, with 55% of the samples exhibiting a pH below 5.6. The VWM of the free H+ was 6.27 μmol l−1), corresponding to a pH of 5.20. Ammonia (NH3), determined as (VWM = 32.8 μmol l−1), was the main acidity neutralizing agent. Considering that the H+ ion is the only counter ion produced from the non-sea-salt fraction of the dissociated anions, the contribution of each anion
to the free acidity potential has the following profile: (31.1%), (26.0%), CH3COO− (22.0%), Cl− (13.7%), HCOO− (5.4%) and (1.8%). The precipitation chemistry showed seasonal differences, with higher concentrations of ammonium and calcium during
autumn and winter (dry period). The marine contribution was not significant, while the direct vehicular emission showed to
be relevant in the ionic composition of precipitation. 相似文献
88.
Kuang YW Zhou GY Da Wen Z Liu SZ 《Environmental science and pollution research international》2007,14(4):270-275
Goal, Scope and Background Rapid urbanization and the expansion of industrial activities in the past several decades have led to large increases in emissions
of pollutants in the Pearl River Delta of south China. Recent reports have suggested that industrial emission is a major factor
contributing to the damages in current natural ecosystem in the Delta area. Tree barks have been used successfully to monitor
the levels of atmospheric metal deposition in many areas, but rarely in China. This study aimed at determining whether atmospheric
heavy metal deposition from a Pb-Zn smeltery at Qujiang, Guangdong province, could be accurately reflected both in the inner
bark and the outer bark of Masson pine (Pinus massoniana L.). The impact of the emission from smeltery on the soils beneath the trees and the relationships of the concentrations
between the soils and the barks were also analyzed.
Methods Barks around the bole of Pinus massoniana from a pine forest near a Pb-Zn smeltery at Qujiang and a reference forest at Dinghushan natural reserve were sampled with
a stainless knife at an average height of 1.5 m above the ground. Mosses and lichens on the surface barks were cleaned prior
to sampling. The samples were carefully divided into the inner bark (living part) and the outer bark (dead part) in the laboratory,
and dried and ground, respectively. After being dry-ashed, the powder of the barks was dissolved in HNO3. The solutions were analyzed for iron (Fe), manganese (Mn), copper (Cu), zinc (Zn), chromium (Cr), nickel (Ni) and cobalt
(Co) by inductively coupled plasmas emission spectrometry (ICP, PS-1000AT, USA) and Cadmium (Cd) and lead (Pb) by graphite
furnace atomic absorption spectrometry (GFAAS, ZEENIT 60, Germany). Surface soils (0–10 cm) beneath the sample trees were
also collected and analyzed for the selected metals.
Results and Discussion Concentrations of the selected metals in soils at Qujiang were far above their environmental background values in the area,
except for Fe and Mn, whilst at Dinghushan, they were far below their background values, except for Cd and Co. Levels of the
metals, in particular Pb and Zn, in the soils beneath the sample trees at Qujiang were higher than those at Dinghushan with
statistical significance. The result suggested that the pine forest soils at Qujiang had a great input of heavy metals from
wet and dry atmospheric deposition, with the Pb-Zn smeltery most probably being the source.
Levels of Cu, Fe, Mn, Zn, Ni and Pb at Qujiang, both in the inner and the outer bark, were statistically higher than those
at Dinghushan. Higher concentrations of Pb, Fe, Zn and Cu may come from the stem-flow of elements leached from the canopy,
soil splash on the 1.5 m height and sorption of metals in the mosses and lichens growing on the bark, which were direct or
indirect results from the atmospheric deposition. Levels of heavy metals in the outer barks were associated well with the
metal concentrations in the soil, reflecting the close relationships between the metal atmospheric deposition and their accumulation
in the outer bark of Masson pine. The significant (p<0.01) correlations of Fe-Cu, Fe-Cr, Fe-Pb, Fe-Ni, Pb-Ni, and Pb-Zn in
the outer barks at Qujiang again suggested a common source for the metals. The correlation only occurred between Pb and Ni,
Cd and Co in the outer barks at Dinghushan, which suggested that those metals must possibly have other uncommon sources.
Conclusions Atmospheric deposition of the selected metals was great at Qujiang, based on the levels in the bark of Pinus massoniana and on the concentrations in the soils beneath the trees compared with that at Dinghushan. Bark of Pinus massoniana, especially the outer bark, was an indicator of metal loading at least at the time of sampling.
Recommendations and Perspectives The results from this study and the techniques employed constituted a new contribution to the development of biogeochemical
methods for environmental monitoring particularly in areas with high frequency of pollution in China. The method would be
of value for follow up studies aimed at the assessment of industrial pollution in other areas similar with the Pearl River
Delta. 相似文献
89.
吴淞工业区大气降尘变化规律及趋势 总被引:2,自引:1,他引:1
吴淞工业区是重工业聚集区,烟(粉)尘的排放量非常大,造成该地区空气污染严重.为了解降尘的污染特征、变化规律及趋势,以近10 a监测数据为依据,运用方差分析等数理统计方法对工业区降尘量进行分析,检验不同季节降尘的差异并简要分析原因,使用秩相关系数法对其进行趋势分析.结果表明,工业区降尘量较混合区与清洁区明显不同; 工业区与混合区的降尘受本地源的影响较大,4季的降尘量没有明显差异,相反清洁区的4季降尘呈显著差异.10 a来工业区及其周边地区的降尘量下降了56%,说明环境综合整治取得了显著效果,使区域环境空气质量得到改善. 相似文献
90.
Gerosa G Marzuoli R Desotgiu R Bussotti F Ballarin-Denti A 《Environmental pollution (Barking, Essex : 1987)》2008,152(2):274-284
An Open-Top Chambers experiment on Fagus sylvatica and Quercus robur seedlings was conducted in order to compare the performance of an exposure-based (AOT40) and a flux-based approaches in predicting the appearance of ozone visible injuries on leaves. Three different ozone treatments (charcoal-filtered; non-filtered; and open plots) and two soil moisture treatments (watered and non-watered plots) were performed. A Jarvisian stomatal conductance model was drawn up and parameterised for both species and typical South Alpine environmental conditions, thus allowing the calculation of ozone stomatal fluxes for every treatment. A critical ozone flux level for the onset of leaf visible injury in beech was clearly identified between 32.6 and 33.6 mmolO3 m(-2). In contrast, it was not possible to identify an exposure critical level using the AOT40 index. Water stress delayed the onset of the leaf visible injuries, but the flux-based approach was able to take it into account accurately. 相似文献