紫外导数分光光度法直接测定饮用水中的硝酸根含量

在酸性条件下,用二阶导数及零交技术,取２２３．５ｎｍ处的导数值可消除水中常见离子的干扰。该法的线性范围为０－１３０μｇ－５０ｍｌ,检出限为０．０８μｇ．ｍｌ＾－１,加标回收率在９５％－１０１％之间,适用于自来水,井水及泉水等饮用水中ＮＯ＾－３含量的测定。     

Simultaneous Determination of O- and P- Nitrophenol by First Derivative Spectrophotometry

A simple method by first derivative spectrophotometry is proposed for the simultaneous determination of o-nitrophenol and p-nitrophenol. The analytes were separated from samples by liquid-liquid extraction (pH = 7.4) as tetrabutylammonium ion pairs into the 1,2-dichloroethane organic phase and subsequently the extracts were evaluated directly by derivative spectrophotometry. Simultaneous determination of both analytes could be carried out using the zero-crossing and the graphical methods for o-nitrophenol and p-nitrophenol, respectively. The determination ranges were found to be between 0.115 to 3.00 ppm and 0.130 to 3.00 ppm for o-nitrophenol and p-nitrophenol, respectively. The relative standard deviations were in all instances less than 2.0%. The proposed method was applied to the determination of these compounds in fruit juices.     

电导滴定法快速测定不同水中硫酸根的含量

采用电导法，用氯化钡标准溶液滴定水样中硫酸根的含量对测定结果的影响因素进行了探讨，本方法测定的回收率在９８￣１０２％之间，装置简单，试样测定时间仅需几分钟，准确度较高，适用范围广，如海水，卤水，自来水、深井水、雨水和部分工业废水等硫酸根含量的测定。     

衍生气相色谱法在环境监测中的应用

衍生化气相色谱法就是利用化学反应改变目标化合物分子中的原子或官能团,通过检测新生产物对目标化合物进行气相色谱定性和定量分析,具有高灵敏度、良好的分离效果和绿色环保等优点。通过对衍生化与气相色谱联用在环境监测中特别是有机污染物的应用,具体介绍了该技术在醛酮类、酚类、酸类化合物及其他有机污染物分析中的应用及反应原理,并提出了该技术的注意事项及应用展望。     

关于改进非甲烷总烃测定方法的探讨

根据非甲烷总烃排放标准、分析方法和实际监测情况,对非甲烷总烃定义、总烃峰型异常、氧峰干扰、方法检出限测定和采样容器选择等方面存在的问题进行了探讨。结果表明：气态烃的衍生物属于非甲烷总烃,烃的衍生物和色谱柱类型是导致总烃峰型异常的主要原因,使用除烃空气作载气可消除氧峰干扰,非甲烷总烃为差值结果,应按照EPA SW-846标准测定检出限,PVF气袋本底低、气密性和化学惰性好,是最佳的非甲烷总烃采样容器。     

Improving the dynamic response of frequency and power in a wind integrated power system by optimal design of compensated superconducting magnetic energy storage

The frequency deviation and power fluctuation need to be controlled in a wind-integrated power system (WIPS) for keeping the balance between system power generation and demand, which support the quality and stability of overall power system. The present paper addresses this problem while concerning the integration of intermittent wind power and load disturbance into the WIPS. With this intent, it proposes the compensated superconducting magnetic energy storage (CSMES) system with proportional integral derivative (PID) controller for improving the frequency and power deviation profile. A novel swarm intelligence-based artificial bee colony (ABC) algorithm is used for optimal design of PID-CSMES system. Robustness of the proposed ABC-based PID-CSMES control strategy is tested in WIPS under various disturbance patterns of load and wind power. To demonstrate the improved dynamic response, their simulation results are compared with particle swarm optimization-based PID-CSMES, PID with SMES, and only PID controller technique. The performance indices and transient response characteristics of frequency and power deviation are used to evaluate and compare the accuracy and efficiency of each controller. Stability of various system configurations is analyzed using eigenvalue location. Comparing the results of different controller in WIPS indicates a substantial improvement in the dynamic response of system frequency and power deviations by utilizing the proposed control strategy.     

导数恒能量同步荧光法同时分析咔唑、苯并(a)芘、苝和2,3-苯并蒽

建立了咔唑、苯并(a)芘、苝和2,3-苯并蒽四组分同时测定的导数恒能量同步荧光分析法,该法简便快速,无需对混合物进行分离,只需一次扫描,就可实现四组分的同时鉴别和定量测定．该方法用于海水、自来水和大气飘尘的分析,取得了良好的效果,回收率分别为94％-104％,91．7％-104％和82．3％-112．5％．     

工矿商贸行业较大以上次生衍生事故分析研究

通过对2012~2015年6月全国工矿商贸行业发生的较大以上次生衍生事故行业分布、地域分布、时段分布、空间分布等特征的分析,归纳总结了次生衍生事故发生的规律和特点,根据事故致因理论,对次生衍生事故原因进行了分析,并提出对策措施,为降低工矿商贸次生衍生事故发生率、减少人员伤亡提供理论支撑。     

UASB及其衍生反应器的运行性能研究

UASB及其衍生反应器是厌氧生物处理技术中最重要的处理工艺和处理装置,在有机废水处理中发挥着重要作用。在对UASB及其衍生反应器的运行性能进行比较分析的基础上,研究了影响UASB反应器运行性能的主要控制因素,并对其工艺发展进行了探讨,以利于对UASB及其衍生反应器的科学选择和厌氧处理工艺的创新研究。     

关于气相色谱法测定水中丙烯酰胺的研究

研究并建立了毛细柱气相色谱-微池电子捕获检测器测定水中丙烯酰胺的方法。水样中丙烯酰胺经溴化衍生后,用乙酸乙酯萃取,经气相色谱法分析,取l00ml水样时方法检出限为0．017μg／L。丙烯酰胺在0．50～12．50μg／L范围内线性良好,在低、中、高3个添加水平,平均加标回收率为99．3％～114％,相对标准偏差为0．4％-3．5％。本方法准确度高、精密度好,适用于水中丙烯酰胺测定。