Seasonal trend of ambient PCDD/Fs in Tianjin City, northern China using active sampling strategy

The spatial concentrations, seasonal trends, profiles and congener pairs of ambient polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were investigated within a seasonally active sampling scheme during Jun 2008 and Jan 2009 in Tianjin City, northern China. The PCDD/F concentrations ranged 14.2-172 fg I-TEQ/m³ (average 69.3 fg I-TEQ/m³) in summer and (89.8-1.01) × 10³ fg I-TEQ/m³ (average 509 fg I-TEQ/m³) in winter, respectively, except for the E-waste dismantling site where much higher values were observed (1.04 × 10³ fg I-TEQ/m³ in summer and 7.123 × 10³ fg I-TEQ/m³ in winter). The results indicated a significantly seasonal trend with higher TEQ values in winter as compared with summer, which could be related to increased emission sources and seasonal variations of the atmospheric boundary layer height. 2,3,4,7,8-PeCDF was the dominant contributor to the total PCDD/F toxic equivalents, and 2,3,7,8-TCDD was detected at almost all the sampling sites in winter. Most of the similarly substituted PCDD/F congener pairs exhibited high correlations, suggesting that they might have similar environmental fate or sources. But different seasonal and spatial distributions of PCDD/F concentrations indicated that the emission sources might be intermittent.     

Characteristics and recent trends of sulfur dioxide at urban, rural, and background sites in North China: Effectiveness of control measures

SO₂ measurements made in recent years at sites in Beijing and its surrounding areas are performed to study the variations and trends of surface SO₂ at different types of sites in Northern China. The overall average concentrations of SO₂ are (16.8 ± 13.1) ppb, (14.8 ± 9.4) ppb, and (7.5 ± 4.0) ppb at China Meteorological Administration (CMA, Beijing urban area), Gucheng (GCH, relatively polluted rural area, 110 km to the southwest of Beijing urban area), and Shangdianzi (SDZ, clean background area, 100 km to the northeast of Beijing urban area), respectively. The SO₂ levels in winter (heating season) are 4-6 folds higher than those in summer. There are highly significant correlations among the daily means of SO₂ at different sites, indicating regional characteristics of SO₂ pollution. Diurnal patterns of surface SO₂ at all sites have a common feature with a daytime peak, which is probably caused by the downward mixing and/or the advection transport of SO₂-richer air over the North China Plain. The concentrations of SO₂ at CMA and GCH show highly significant downward trends (-4.4 ppb/yr for CMA and -2.4 ppb/yr for GCH), while a less significant trend (-0.3 ppb/yr) is identified in the data from SDZ, reflecting the character of SDZ as a regional atmospheric background site in North China. The SO₂ concentrations of all three sites show a significant decrease from period before to after the control measures for the 2008 Olympic Games, suggesting that the SO₂ pollution control has long-term effectiveness and benefits. In the post-Olympics period, the mean concentrations of SO₂ at CMA, GCH, and SDZ are (14.3 ± 11.0) ppb, (12.1 ± 7.7) ppb, and (7.5 ± 4.0) ppb, respectively, with reductions of 26%, 36%, and 13%, respectively, compared to the levels before. Detailed analysis shows that the differences of temperature, relative humidity, wind speed, and wind direction were not the dominant factors for the significant differences of SO₂ between the pre-Olympics and post-Olympics periods. By extracting the data being more representative of local or regional characteristics, a reduction of up to 40% for SO₂ in polluted areas and a reduction of 20% for regional SO₂ are obtained for the effect of control measures implemented for the Olympic Games.     

2002～2012年乌江渡水库水质变化趋势分析

为了解乌江渡水库水质变化趋势,对2002～2010年乌江渡水库水质监测结果进行了分析。采用综合营养状态指数法、污染分担率法、秩相关系数法,对水库富营养化等状况进行评价。结果表明,近年来,乌江渡水库总磷和总氮污染分担率之和达78%,是水库主要污染物,水库水质从大岭岗、偏岩河口到大坝,富营养程度逐渐加重;水库中总氮、氨氮、粪大肠菌群和五日生化需氧量也均呈显著上升趋势。建议加大乌江渡水库水质中总磷和总氮等的监测力度,加强防护与控制管理。     

城市生活垃圾现状与治理动态

主要阐述了我国城市生活垃圾的现状、现有处理城市生活垃圾的几种方法,并就治理趋势进行探讨。     

盐河淮阴区段水质污染现状评价及防治对策

水污染是困扰淮阴区工农业发展的问题之一。因此对盐河淮阴区段近几年来的水质状况进行了评价，分析了水体污染形成的原因及发展趋势，阐述了污染特征和程度，并提出了改善水环境的对策。     

环境化学中有机化合物毒性的QSAR研究方法

定量结构—活性相关 (QSAR)研究具有重要的理论和实际意义。在前人大量相关研究的基础上分析了目前国内外普遍实用的七种QSAR研究方法 ,并讨论了各方法的优缺点及适用范围 ,以利于各方法的进一步推广。同时简要介绍了QSAR的发展趋势。     

水资源约束下西北干旱区城市扩张特征与变动趋势分析——以西陇海兰新经济带城市为例

论文以西北干旱区陇海兰新经济带城市为例,分析了城市水资源利用状况及其短缺程度,认为绝大多数城市“缺水又费水”,城市发展具有明显的“旱生性”。在水资源约束下,西陇海兰新经济带城市的发育程度远远落后于东部地区城市,也落后于全国城市平均水平,略好于西部地区城市,但明显好于西北地区城市,城市扩张的总体特征表现为以总量扩张为主,“农转非”空间和用地拓展空间大,以高耗低效扩张为主,水土资源投入产出效益普遍低下,城市发展处在主要依靠资源开发拉动经济增长的低级阶段,扩张质量有待提高。城市发展具有明显的外部推动性。未来20a,在水资源短缺的继续约束下,经济带城市扩张步伐将比较缓慢,扩张幅度将不会有大的变化。表现为将净增城市非农业人口6.31×106人,城市化水平将提高到35.97%,20a共净增7.21%,特大城市数量将保持西安、兰州和乌鲁木齐3个不变;大城市从无到有,将建成宝鸡、咸阳、铜川、天水、石河子和库尔勒6个;中等城市数量将会显著增加,由2000年的10个增加到2020年的14个,在不考虑“县改市”的前提下,小城市的数量将会进一步减少。为了确保经济带沿线城市的有序扩张,建议在城市建设过程中以人为本,以水为生命线,以经济发展为动力,以城市规划为法定依据。     

Trends in the Water Chemistry of High Altitude Lakes in Europe

Here we present the chemical trends of seven high altitude lakes, analysed within the AL:PE and MOLAR Projects of the EU (1999) and selected on the basis of the availability of complete and reliable data for the period 1984–1999. The lakes are representative of the Scandinavian Alps, the Cairngorm Mountains in Scotland, the Alps and the Pyrenees. Significant trends were identified for some indicators of acidification, for instance pH and alkalinity, but not all lakes reacted similarly to decreasing depositions of sulphate and base cations. Differences in lake response are discussed in relation to recent variations of atmospheric deposition chemistry and associated changes in climatic conditions. Beside individual variations of the studied lakes, depending, among other things, on altitude and morphology, catchment characteristics and climate trends play a major role for the reaction of high altitude lakes on changes in atmospheric depositions.     

西辽河上游河水水质污染趋势分析与防治对策

文中利用市及旗县区监测站近几年监测数据对西辽河上游的污染程序进行了讨论 ,并进行了趋势分析 ,提出污染防治对策 ,旨在为辽河治理提供参考     

长江经济带开发构想与发展态势

长江经济带是我国国土开发和经济建设中极其重要的开发轴线,近年来已经上升为新一轮的国家战略,肩负着参与国际竞争、协调东中西3大区域、推进双向开放、建设生态文明的使命。在国际国内经济社会发展新形势下,长江经济带发展机遇与挑战并存。以流域经济发展为视角,从长江经济带提出的背景出发,回顾了长江经济带战略构想及20世纪80年代以来开发历程,从经济地位、产业集聚、航运建设、岸线开发、沿江交通等5个方面分析了长江经济带发展态势,并重点分析了长江经济带重化工业发展与布局、生态环境影响、港口建设与发展、城市群培育等方面面临的主要问题,最后从改革考核机制、破除行政壁垒、强化流域协调机构与建立流域管理法律法规等方面提出了对策思路,以期为新时期长江经济带开发建设提供参考借鉴。