改进灰色系统模型在城市噪声预测中的应用

把城市噪声作为一个灰色系统,分别通过GM(1,1)模型和改进灰色系统模型GM'(1,1),对城市噪声进行预测,并进行精度检验.改进的灰色系统模型GM'(1,1)在精度上均优于GM(1,1)模型,但是GM'(1,1)在计算上比较复杂,需要通过计算机迭代来实现.     

固相微萃取-毛细管气相色谱法测定水中有机污染物

固相微萃取是一种快速、简便、集萃取浓缩于一体的样品前处理技术,具有分析快速、灵敏度高、无需有机溶剂的优点。用固相微萃取-毛细管气相色谱分析水中甲醇、丙酮、异丙醇、乙醇、乙腈、丙烯腈,检出限可达0.003～0.03mg/L。     

Spatial variations in daily average CO2 concentrations above wetland surface of Xianghai National Nature Reserve, China

Horizontal and vertical variations of daily average CO2 concentration above the wetland surface were studied in Xianghai National Nature Reserve of China in August, 2000. The primary purpose was to study spatial distribution characteristics of CO2 concentration on the four levels of height(0.1 m, 0.6 m, 1.2 m and 2 m) and compare the differences of CO2 concentration under different land covers. Results showed that daily average CO2 concentration above wetland surface in Xianghai National Natural Reserve was lower than that above other wetlands in northeast China as well as the worldwide average, suggesting that Xianghai wetland absorbed CO2 in August and acted as“sink” of CO2. The horizontal variations on the four levels of height along the latitude were distinct, and had the changing tendency of“decreasing after increasing” with the increase of height. The areas with obvious variations were consistent on different levels of height,and those with the highest variations appeared above surface of shore, sloping field, Typha wetland and Phragmites wetland; the vertical variations were greatly different, with the higher variations in Phragmites wetland and Typha wetland, and the lands near the shore and the sloping field with the lower variations. Spatial variations of daily average CO2 concentrations above wet!and surface were affected by surface qualities and land covers.     

SiO_2-TiO_2纳米管的制备及其光催化性能的研究

文章采用水热法制备SiO2-TiO2纳米管,通过扫描电镜(SEM)和透射电镜(TEM)考察了该纳米管的结构形态,并用X-射线衍射考察其晶体结构。实验结果表明所制得的纳米管是锐钛晶型,其两端开口,具有多层管壁;管径为8nm左右,管壁厚1～2nm。光催化降解酸性橙Ⅱ实验表明:SiO2-TiO2纳米管光催化速率比TiO2纳米管高出10%。这可能是因为Si元素的存在增大了钛纳米管的比表面积,同时SiO2的存在能降低光生电子和空穴的复合率。     

兰炼烷基化废酸处理工艺选择

对目前四种烷基化硫酸处理工艺进行了分析比较，认为兰炼应依托现有硫酸装置，采用裂解制硫酸工艺来处理烷基化废酸。     

石油化工厂区土壤中总石油烃分布的研究

为了进行石油化工厂区地下环境的现场评估，利用气相色谱法（EPA8015B）对其土壤中总石油烃（TPHs)进行了测定，测定结果以柴油范围的有机物（DRO）和润滑油范围的有机物（ORO）表示。结果表明：土壤各层DRO检出率在58％－72％之间，ORO检出率在82％－89％之间，大多数检出点位的DRO、ORO含量小于500mg/kg；个别点位的DRO、ORO高达30000mg/kg。     

加强工业污染防治 实现环保全面达标

对燕化公司开展环保全面达标工作做了综述和总结，几年的综合污染防治工作证明，加强环保管理、持续推行清洁生产和较先进的污染治理技术促进了燕化公司经济和生产的发展，同时降低了废物排放，取得了明显的效果。     

新型负载型纳米TiO_2光催化降解苯酚的试验研究

以岩棉为载体制备一种新型负载型纳米TiO2,对有机污染物苯酚的降解效果较好。岩棉对苯酚有一定的吸附作用。经过120min的处理,苯酚基本上被完全降解。流速对降解率的影响较大,本试验选择流速为5mL/min。初始浓度越小,苯酚的降解效果越好。通入O2和加入适量H2O2均有利于苯酚的降解,且少量的H2O2可使苯酚的降解率大大提高。苯酚在pH=4.5时降解效果最好。     

厦门西港海水质量对鱼卵胚胎发育畸形率的影响

以养殖场培育的花尾胡椒鲷受精卵为实验材料测试了厦门西域5个站位的表层水水样对花尾胡椒鲷受精卵的胚胎发育毒性，并运用GC－MS手段分析了水样中的美国EPA优控的16PAHs组分的含量。结果表明：3号站位（厦门市工业和生活污水主要排放口的外侧）和4号站位（厦门西港的港区）的水样对鱼卵的胚胎发育的毒性最强。8号站位（位于主航道并濒临嵩屿电厂）的水样对鱼卵胚胎发良的毒性次之，1号站位（湾口）和5号站位（内港）的水样对鱼卵的胚胎发育的毒性较小。水样中的PAHs含量分析结果表明，仅用水样中的PAHs含量不能全面地反映水样对鱼卵胚胎发育的毒性。最后，对本实验方法应用于海洋环境生物监测的有效性进行了探讨。