[HPMo][OTAC]2/SiO2的制备及其催化柴油氧化脱硫的研究

采用溶胶-凝胶法制备不同负载量的[HPMo][OTAC]2/SiO2,通过红外光谱、比表面积和孔结构分析对[HPMo][OTAC]2/SiO2进行表征,考察负载量、催化剂用量、氧化剂用量、反应温度和反应时间对模拟柴油脱硫效果的影响。结果表明,掺杂后的催化剂保持了Keggin结构,[HPMo][OTAC]2/SiO2在最佳反应条件下,苯并噻吩的脱除率达到48.3%,二苯并噻吩的脱除率达到67.2%。     

A Biosurfactant-Enhanced Soil Flushing for the Removal of Phenanthrene and Diesel in Sand

In order to examine the potential of biosurfactants in soil remediation, and to investigate the effects of several operating conditions, such as flow rate, biosurfactant concentration and surfactant type, biosurfactant-enhanced soil flushing was conducted. In the biosurfactant-enhanced soil flushing process, the removal efficiency increased as the flow rate decreased. Rhamnolipid showed no effect on the removal efficiency of phenanthrene and diesel from sand in the concentration range 0.3-0.5%. However, rhamnolipid showed higher efficiencies for the removal of phenanthrene and diesel from sand than Tween 80. Based on total recovery, following an equivalent pore volume flush, it was more difficult to remove diesel than phenanthrene. In order to obtain the specific removal efficiency, more pore volumes of surfactant solution may be required in field applications. Under optimum conditions, the biosurfactant removed as much as 70% of the phenanthrene and 60% of the diesel in the sand. These results indicate that the use of biosurfactants in the flushing process is favorable, not only with respect to the environment, but also on removal efficiencies.     

影响柴油在土壤中挥发的因素

石油污染物进入土壤中后经历一系列物理化学和生物过程,其中发生的挥发过程是一种重要的迁移过程。本文以柴油为石油污染物的代表,研究了温度及土壤质地对柴油挥发行为的影响。通过在不同温度下纯柴油的挥发及柴油从四种不同土质的薄层土壤中的挥发试验,对柴油的挥发量与挥发时间的关系进行了模拟,结果表明:在不同温度下,纯柴油及柴油在四种薄层土壤中的挥发量与挥发时间的关系均可采用二次多项式来拟合。通过对比经相近时间柴油从4种不同土壤表面的挥发后,发现柴油挥发量均大于从纯柴油时的挥发量。在有机质质量分数不同的土壤中进行了柴油挥发试验,结果表明高有机质会抑制土壤中的柴油的挥发。     

La1-xCexFe0.7Co0.3O3-δ网状多层纳米纤维对碳烟催化燃烧性能研究

采用静电纺丝法制备了一系列钙钛矿催化剂La_(1-x)Ce_xFe_(0.7)Co_(0.3)O_(3-δ)(x=0、0.1、0.2、0.3和0.4),并采用XRD、SEM、FT-IR、H2-TPR和O_2-TPD等技术分析了Ce掺杂量对催化剂结构、微观形貌及理化特性的影响.同时,采用程序升温氧化(TPO)技术评价了催化剂对碳烟的催化燃烧活性,探讨了催化剂对碳烟的催化燃烧机理.结果表明:在La_(1-x)Ce_xFe_(0.7)Co_(0.3)O_(3-δ)中掺杂适宜的Ce有助于提高催化剂活性,改善催化剂比表面积和孔容积.在催化剂与碳烟松散接触条件下,当Ce掺杂量(质量百分比)为0.3时,所制备的La_(0.7)Ce_(0.3)Fe_(0.7)Co_(0.3)O_(3-δ)对碳烟的起燃温度(T_(ig))、最大燃烧温度(T_m)和燃尽温度(T_f)分别为329.5、409.8和421.1℃,呈现良好的催化氧化活性.碳烟最大转化效率为98.7%,平均活化能为123 kJ·mol~(-1),CO_2选择率为98.2%,实现了对柴油机碳烟排放污染物有效"过滤+催化燃烧"的双重目标.     

异质结型SnO2-TiO2纳米纤维光催化降解柴油机多环芳烃

采用同轴静电纺丝法制备了SnO_2-TiO_2纳米纤维,用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、红外光谱仪(FTIR)和紫外-可见光谱能谱仪(UV-Vis),表征了SnO_2-TiO_2纳米纤维相组成和微观形貌,评价了催化剂表面化学形态和吸光特性,研究了SnO_2含量、光源条件、温度和催化稳定性对降解萘污染物的影响规律.结果表明,催化剂Sn25对萘降解效率最高.在暗光、可见光和紫外光条件下,萘降解效率分别为13.8%、37%和98%.Sn25对萘降解稳定率(标准差率)为0.36%.利用催化剂Sn25对柴油机尾气中多环芳烃(PAHs)排放污染物光催化降解应用发现,Sn25对低苯环PAHs、中苯环PAHs和高苯环PAHs的平均催化降解效率分别为80.2%、75.4%和60.2%.表明SnO_2-TiO_2纳米纤维具有较强光催化降解多环芳烃污染物能力.     

Performance of a diesel engine with water emulsified diesel prepared with optimized process parameters

An attempt has been made to produce stable water–diesel emulsion with optimal formulation and process parameters and to evaluate the performance and emission characteristics of diesel engine using this stable water–diesel emulsion. A total of 54 samples were prepared with varying water/diesel ratio, surfactant amount and stirring speed and water separation was recorded after 24 and 48 hr of emulsification. The recorded data were used in artificial neural network (ANN)-particle swarm optimization (PSO) technique to find the optimal parameters to produce water–diesel emulsion for engine testing. The predicted optimal parameters were found as 20% water to diesel ratio, 0.9% surfactant and 2200 rpm of stirrer for a water separation of 14.33% in one day with a variation of 6.54% against the actual value of water separation. Water–diesel emulsion fuel exhibited similar fuel properties as base fuel. The peak cylinder gas pressure, peak pressure rise rate and peak heat release rate for water–diesel were found higher as compared to diesel at medium to full engine loads. The improved air-fuel mixing in water–diesel emulsion enhanced brake thermal efficiency (BTE) of engine. The absorption of heat by water droplets present in water–diesel emulsion led to reduced exhaust gas temperature (EGT). With water–diesel emulsion fuel, the mean carbon monoxide (CO), unburned hydrocarbon and oxides of nitrogen (NO_x) emissions reduced by 8.80, 39.60, and 26.11%, respectively as compared to diesel.     

油气长输管道施工企业清洁生产研究

清洁生产在油气长输管道施工领域涉及较少,观念和方法还未完全推广。油气长输管道施工企业与传统生产型企业有许多不同之处,以某企业清洁生产审核为例,就如何通过清洁生产审核挖掘清洁生产潜力来做探索性、建议性的研究。实践证明,该企业清洁生产机会的突破口为柴油消耗,通过柴油消耗平衡图的建立和重点耗油设备运行状况的调查,找到了降低柴油消耗的清洁生产方案,使企业达到了“节能、降耗、减污、增效”的目的。     

包覆型纳米零价铁活化过硫酸处理柴油污染土壤

采用Tween-20作为包覆材料对纳米零价铁(n ZVI)进行改性(T-n ZVI),并利用T-n ZVI活化过硫酸盐(PS)降解柴油,同时与未改性纳米零价铁活化过硫酸盐体系(n ZVI/PS)进行对比.结果显示,在n ZVI/PS体系中,柴油降解率随着n ZVI及PS用量的增加而增加.在T-n ZVI/PS体系中,反应90 d后,柴油最大降解率为78%.与n ZVI/PS体系相比,T-n ZVI/PS体系所有组别的柴油降解率均有所提升,但提升幅度不大.同时对T-n ZVI活化PS的机理进行了推测.     

不同后处理器对DMCC发动机PM排放的影响

在一台整车排放达到国Ⅲ标准的YC4D140电控单体泵增压中冷柴油机上加装甲醇喷射系统,改成柴油甲醇组合燃烧(DMCC)发动机.使用AVL 415S烟度计和DMS 500快速颗粒物光谱仪研究不同后处理器对DMCC发动机颗粒物(PM)排放的影响.试验结果表明,各工况下单独CDPF、DOC+CDPF基本可以消除发动机产生的干炭烟.DOC+CDPF后处理方式与单独CDPF相比,颗粒物捕集效率明显提高,且前者对颗粒物中核态部分的捕集效果更加突出.甲醇掺烧后,炭烟和颗粒物几何平均直径降低.经CDPF和DOC+CDPF处理,415S烟度计测得的炭烟进一步降低;DMS颗粒物光谱仪显示的颗粒物粒径,因其中核态部分大部被氧化捕集而仅余较大几何平均直径的部分.小负荷时经CDPF和DOC+CDPF处理,颗粒物的几何平均直径会增大,大负荷时则相反.各工况下相比于CDPF,DOC+CDPF对核态颗粒物捕集更有效.     

DOC+CDPF对生物柴油燃烧颗粒排放特性的影响

以一台满足国五排放法规的车用柴油机为样机,研究加装氧化催化转化器DOC与催化型颗粒捕集器CDPF(DOC+CDPF后处理装置)前后,柴油机燃用B20燃料(燃料含20%体积掺混比的生物柴油)的颗粒排放特性.结果表明,在未加装该后处理装置时,该机排气颗粒数量浓度的粒径分布呈双峰形态,B20燃料的排气颗粒数量浓度的峰值粒径在10nm和50nm附近,纯柴油的排气颗粒数量浓度的峰值粒径在50nm和200nm附近.在颗粒粒径小于120nm的区域,该机燃用B20燃料的排气颗粒数量浓度大于纯柴油.加装该后处理装置后,该机排气颗粒数量浓度的粒径分布呈多峰形态,峰值粒径在10nm、20nm和60nm附近.加装DOC+CDPF后,不论是柴油还是B20燃料,与原机相比,柴油机排气颗粒总数量下降明显,其中60~200nm粒径范围的颗粒数量浓度降幅更为显著.在相同工况下,DOC+CDPF对柴油机燃用B20燃料的颗粒总数量净化效率高于纯柴油.