空气微生物采样方法的比较

对3种空气微生物采样方法进行了比较。结果表明,在室外自然条件下,大气细菌粒子的沉降量与大气细菌粒子的浓度、大气真菌粒子的沉降量与大气真菌粒子的浓度均呈显著的正相关关系。对大气细菌粒子,用平皿沉降法分别与A·S采样器法、THK－201采样器法测定的结果相比,有非常显著的差异。平皿沉降法测定结果比后二者方法高出2.9倍和4.0倍;A·S采样器和THK－201采样器测定结果之间没有显著性差异。对大气真菌粒子,A·S采样器法和平皿沉降法与THK－201采样器法均有非常显著性差异;平皿沉降法与A·S采样器法测定结果之间没有显著性差异。进一步用直线回归分析的方法,得出了大气细菌粒子浓度与大气细菌粒子沉降量及大气真菌粒子浓度与大气真菌粒子沉降量之间的关系式。     

苯胺在水体悬浮颗粒物上吸附特征

通过批量平衡法实验,比较了作为有机碱离子化有机污染物之一的苯胺在酸性、天然水和碱性水体中悬浮颗粒物上的吸附特征,并观察了水体颗粒物中腐殖酸含量对苯胺吸附行为的影响。结果表明,苯胺在水体悬浮颗粒物上的吸附遵守Ｆｒｅ－ｕｎｄｌｉｃｈ方程：在ｐＨ５—１０范围内苯胺被吸附的能力随介质ｐＨ值和颗粒物中有机质含量的升高而增大．     

氧化·热化学脱硫研究

热化学脱硫法因铵盐回收率低、产物不稳定,无法解决实用化问题。氧化热化学法应用超强脉冲电场产生高浓度、高能量的活性粒子,使SO₂在氧化过程中生成H₂SO₄,与NH3进行热化学反应,生成稳定的固体微粒（NH₄）₂SO₄,用电收尘器加以回收。脱除率、回收率可达90％左右,脱除1m³烟气中SO₂耗能为4Wh,实现了干法高效脱硫。一次投资大幅度减少,回收铵盐基本上抵消了药品费和电费。     

Solid state speciation and potential bioavailability of depleted uranium particles from Kosovo and Kuwait

A combination of synchrotron radiation based X-ray microscopic techniques (μ-XRF, μ-XANES, μ-XRD) applied on single depleted uranium (DU) particles and semi-bulk leaching experiments has been employed to link the potential bioavailability of DU particles to site-specific particle characteristics. The oxidation states and crystallographic forms of U in DU particles have been determined for individual particles isolated from selected samples collected at different sites in Kosovo and Kuwait that were contaminated by DU ammunition during the 1999 Balkan conflict and the 1991 Gulf war. Furthermore, small soil or sand samples heavily contaminated with DU particles were subjected to simulated gastrointestinal fluid (0.16 M HCl) extractions. Characteristics of DU particles in Kosovo soils collected in 2000 and in Kuwait soils collected in 2002 varied significantly depending on the release scenario and to some extent on weathering conditions. Oxidized U (+6) was determined in large, fragile and bright yellow DU particles released during fire at a DU ammunition storage facility and crystalline phases such as schoepite (UO₃·2.25H₂O), dehydrated schoepite (UO₃·0.75H₂O) and metaschoepite (UO₃·2.0H₂O) were identified. As expected, these DU particles were rapidly dissolved in 0.16 M HCl (84 ± 3% extracted after 2 h) indicating a high degree of potential mobility and bioavailability. In contrast, the 2 h extraction of samples contaminated with DU particles originating either from corrosion of unspent DU penetrators or from impacted DU ammunition appeared to be much slower (20–30%) as uranium was less oxidized (+4 to +6). Crystalline phases such as UO₂, UC and metallic U or U–Ti alloy were determined in impacted DU particles from Kosovo and Kuwait, while the UO_2,34 phase, only determined in particles from Kosovo, could reflect a more corrosive environment. Although the results are based on a limited number of DU particles, they indicate that the structure and extractability of DU particles released from similar sources (metallic U penetrators) will depend on the release scenarios (fire, impact) and to some extent environmental conditions. However, most of the DU particles (73–96%) in all investigated samples were dissolved in 0.16 M HCl after one week indicating that a majority of the DU material is bioaccessible.     

Changes in the upper limits of tree species distribution in the Western Caucasus (Belaya River basin) related to recent climate warming

To estimate the response of tree vegetation to recent climate warming in the Western Caucasus, the population state of several tree species at the upper limit of their distribution has been estimated in three mountain massifs in the Belaya River basin. For this purpose, the average and maximum stem diameters, vitality, and age of trees have been determined in the transitional zone between middle-mountain and high-mountain beech-fir forests (1400–1700 m a.s.l.) and in crooked birch forests growing at the upper timberline (1810–2025 m). The upper limits of Acer platanoides, A. pseudoplatanus, Ulmus glabra, and Betula litwinowii have shown a tendency to rise. The upper limit of Abies nordmanniana has remained unchanged over the past few decades, which may be explained by a decrease in moisture supply during the warm season.     

电焊熔珠对棉布和聚氨酯泡沫的引燃能力研究

研究了加载电压对电焊熔珠数目和粒径分布的影响,在模拟装置上实验了电焊对棉布、聚氨酯泡沫和纸张的引燃性能.结果表明,随着加载电压升高,电焊熔珠的数目逐渐减少,熔珠粒径逐渐增大,引燃能力逐渐增强.固体材料性质对电焊熔珠引燃能力也有很大影响,表面粗糙,易蓄热材料容易被点燃.电焊熔珠引燃棉布、聚氨酯泡沫和纸张的临界电压为37.5V、40V和45V.     

不同恢复年限刺槐林土壤碳、氮、磷含量及其生态化学计量特征

地处西秦岭山地的甘肃天水吕二沟小流域土壤侵蚀问题严重,上世纪五六十年代开始,当地政府在研究区实施了多年的生态恢复措施以保持水土,但目前尚未有植被恢复对土壤生态计量特征的系统调查.分析不同林龄人工林土壤碳、氮、磷含量及其生态化学计量特征可在一定程度上揭示土壤养分的限制情况.选取黄土丘陵沟壑区不同生长年限(5、20、40、...     

The Adsorption of Formaldehyde on Suspended Particles investigated on model systems

Our laboratory investigation aimed at assessing to what extent suspended particles could adsorb formaldehyde, allowing it, when inhaled, to penetrate deeper into the lung. We used two types of pure soot, N-220 and N-660 (the former being a highly active oil furnace soot with smaller particles and a larger surface area than the latter), because of their chemical inactivity and the adsorptive properties. The results obtained in experimental conditions showed that soot particles could bind 2.3 to 50.2% of formaldehyde, depending on the particle size, relative humidity, amount of particles and the duration of the contact. The recovery of formaldehyde from the particles was also tested. Further investigation is planned under realistic conditions.     

不同粒径空气颗粒物中11种多环芳烃的分析测定

将五段多孔冲击分级器 (粒径分级 :≤ 1 .1 ,1 .1～ 2 .0 ,2 .0～ 3 .3 ,3 .3～ 7.0 ,≥ 7.0μm)与大流量采样器连接 ,采集呼和浩特市冬夏两季空气颗粒物样品 ,用高压液相色谱仪 (HPLC)测定样品中的蒽 (An)、菲 (Ph)、萤蒽 (Fl)、芘 (Py)、(Ch)、苯并 [a]蒽 (Ba A)、苯并 [a]芘 (Ba P)、二甲基苯并 [a]蒽 (DMBa A)、二苯并 [ah]蒽 (DBah A)、苯并 [ghi] (Bghi P)和晕苯 (Cor)等 1 1种多环芳烃化合物 (PAHs)。数据表明 :呼和浩特市空气颗粒物中 PAHs的浓度较高 ;有约 97%的 PAHs富集于可吸入颗粒中。     

Assessment of groundwater contamination by nitrate leaching from intensive vegetable cultivation using geographical information system

This study employed the Geographical Information System (GIS) technology to investigate nitrate contamination of groundwater by agrochemical fertilizers in the Kakamigahara Heights, Gifu Prefecture, central Japan. Thematic information and chemical data of groundwater from the Heights were analyzed in a GIS environment to study the extent and variation of nitrate contamination and to establish spatial relationships with responsible land use types. The high and correlated concentrations of Ca(2+), Mg(2+), SO(4)(2-), and NO(3)(-) reflected the polluted nature of the unconfined highly permeable Kakamigahara aquifer. Ninety percent of the water samples showed nitrate concentrations above the human affected value (3 mg/l NO(3)(-)), while more than 30% have exceeded the maximum acceptable level (44 mg/l NO(3)(-)) according to Japan regulations. The spatial analyses indicated that groundwater contamination by nitrate is closely associated with one specific land use class, the "vegetable fields". The nitrate concentration of groundwater under vegetable fields was significantly higher than that under urban land or paddy fields. Most of the unacceptable nitrate levels were encountered in boreholes assigned to "vegetable fields" but a few were also found in boreholes allotted to "urban" class. Therefore, the vegetable fields were considered the principal source of nitrate contamination of groundwater in the Kakamigahara. However, contamination from urban sources is also possible.