家具企业安全管理调查研究——运用行为抽样法调查分析不安全行为

为降低家具企业事故的发生概率,通过对家具企业机加工车间工人的不安全行为的观察,依据其主要表现,将工人的不安全行为分为静态和动态两类;运用行为抽样法对生产现场工人的不安全行为情况进行的抽查,并对其不安全行为进行现状评价;通过分析不安全行为发生的原因,提出相应的改进措施。     

纸片法快速测定水质总大肠菌群

简要介绍了纸片法测定水质总大肠菌群的操作方法,并通过６个实验室的验证试验,研究了纸片法与现行标准方法（多管法）的一致性。结果表明,２种方法的测定结果基本一致,无显著性差异,但纸片法测定周期比多管法缩短了２ｄ,仅需１ｄ即可。     

地下饮用水中痕量NO2-的催化动力学法测定

报道了一种新的测定NO2-的高选择性和高灵敏度的催化光度分析法.基于H3PO4介质中,碘绿与溴酸钾的氧化还原反应受亚硝酸盐的催化使碘绿褪色.据此建立了测定NO2-的新方法.本方法检出限为0.29μg/L,该方法用于地下饮用水、环境标样的测定,相对标准偏差为1.05%～4.80%,加标回收率为95%～117%.     

环境监测报告(记录)的审核原则和方法

从实际工作出发,提出了审核原始记录、数字型监测报告（报表）和文字型监测报告的审核原则和方法。     

石墨炉法测定铅的基体改进剂的选择

通过一系列实验,选择了石墨炉法测定铅的最佳基体改进剂,并确定了使用该基体改进剂的最佳灰化温度和原子化温度。     

博物馆室内微环境中碱性气体的被动采样方法研究

针对博物馆微环境中的碱性污染气体-氨气,采用自行研制的被动采样器,建立了一套适合博物馆馆藏文物保存环境中氨气含量分析的被动采样-离子色谱检测方法,应用于博物馆的实地采样分析,通过与主动法采样对照,获得了被动采样器在博物馆微环境中氨的吸收系数,从而获得采样点空气中氨气的浓度,为博物馆文物保存环境监测提供了可行方法。     

双三角解析法快速配制环境监测分析中的标准溶液

介绍了在环境监测分析中精确配制一定浓度标准溶液的快速方法。利用双三角解析法称量标准物质和配制标准溶液,实验过程快速、准确。在环境监测分析应用中取得较好效果,不确定度无显著差异。     

Extended geometric method: a simple approach to derive adsorption rate constants of Langmuir-Freundlich kinetics

A new and simple equation has been presented here for calculation of adsorption and desorption rate constants of Langmuir-Freundlich kinetic equation. The derivation of new equation is on the basis of extension and correction to the geometric method which has been presented by Kuan et al. [Kuan, W.-H., Lo, S.-L., Chang, C.M., Wang, M.K., 2000. A geometric approach to determine adsorption and desorption kinetic constants. Chemosphere 41, 1741-1747] for the kinetics of adsorption/desorption in aqueous solutions. The correction is to consider that the concentration of solute is not constant and changes as adsorption proceeds. The extension is that we applied Langmuir-Freundlich kinetic model instead of Langmuir kinetic model to consider the heterogeneity and therefore it is more applicable to the real systems. For solving Langmuir-Freundlich kinetic model, some geometric methods and also Taylor expansion were used and finally a simple and novel equation was derived (Eq. (20)) for calculation of adsorption rate constant. This new method was named "extended geometric method". The input data of the obtained equation can be simply derived from initial data of adsorption kinetics. Finally the adsorption of methyl orange onto granular activated carbon was carried out at dynamic and equilibrium conditions and the capabilities of extended geometric method were examined by the experimental data.     

突变级数法在采空区塌陷预测中的应用

基于突变级数理论,分析影响采空区稳定性的因素(包括采空区体积率、距地表的垂深、地质构造复杂程度、煤层倾角、覆盖层厚度、覆盖层类型等),研究采空区塌陷的预测方法.对各影响因素进行排序并确定各因素指标体系,得到各样本的突变级数,从而对采空区稳定性进行预测.实例验证表明,突变级数法的判断结果符合实际,与神经网络分级法的判断结果一致.可见,基于突变级数理论的采空区塌陷预测方法具有科学性和有效性.