Ecotoxicological assessment of diffuse pollution using biomonitoring tool for sustainable land use in Thailand

As a developing country, Thailand has a significant issue with diffuse pollution of the soil ecosystem due to an indiscriminate use of agrichemicals and poorly regulated disposal of a wide variety of hazardous wastes. Practical risk assessment tools based on locally-occurring species are needed to assess the effects of diffuse pollutants on the soil ecosystem in Thailand because reliance on soil criteria developed for overseas conditions may provide inadequate protection. Native soil organisms in Thailand may be more or less sensitive to contaminants compared to overseas test species. This article described a biological indicator approach for ecological risk assessment of diffuse pollution in the soil ecosystem of Thailand from pesticide application with the aim of developing standardized protocols using native species and locally generated data to better evaluate the ecological risks of non-point source soil pollution. It was found that ecotoxicological assessment provided a better understanding of the ecological impacts that diffuse pollution induced on Thai environmental conditions. Thai soil biota species were more sensitive to soil contaminants than similar species overseas. Soil series also had an influence on the ecotoxicology of contaminants to soil biota. Collembolan, Cyphoderus sp., was demonstrated as a useful alternative test species to Folsomia Candida (international test species) for terrestrial ecotoxicological testing of Thai soils. In addition, the soil biota activities such as soil respiration and earthworm avoidance including soil biodiversity and the litter bag decomposition technique are also good tools to assess the effects of diffuse pollution by pesticides on the soil ecosystem of Thailand.     

基于光漫反射的真空皮带脱水机滤布纠偏原理

介绍了湿法脱硫系统中真空皮带脱水机滤布的一种光漫反射纠偏装置,包括其主要部件如光漫反射传感器、电动推杆驱动装置、滤布控制滚轮等,重点阐述了光漫反射纠偏装置的工作原理及纠偏过程。光漫反射纠偏装置的主要原理是通过光漫反射传感器的输出信号来判断滤布的跑偏,根据光漫反射传感器的输出信号,DCS控制系统发送指令启动可伸缩的电动推杆装置来伸长和收缩推杆,从而控制滤布滚轮围绕着旋转点进行相应的倾斜调整,使滤布回到其中心位置。     

Fully integrated approach: an alternative solution of coupling a GIS and diffuse pollution models

As a tool for management, query, visualization and analysis of spatially referred information, GIS has been recognized as a method to aid the modeling of diffuse pollution and visualize the results in a spatial context. A common question in integrating diffuse pollution models and GIS is to choose a suitable coupling approach, in which the feature of diffuse pollution models should be taken into account. In this paper, we report on our experience in coupling a distributed diffuse pollution model with a GIS. A prototype of fully integrated system is developed in this paper. This system has high flexibility, extendibility and great data management efficiency. Differences in applicability of loose coupling, tight coupling and fully integrated approaches are addressed. It is concluded that the fully integrated approach can avoid tanglesome data exchange and routine execution and more robust than loose and tight coupling approaches and is suitable for distributed diffuse pollution modes.     

基于水下光场结构的巢湖初级生产力评价

根据2009年6月巢湖32个样点的实测数据以及归一化PAR强度数据,探讨巢湖水体的水下光场结构,并计算该水域的真光层深度,在此基础上结合叶绿素a浓度评价其初级生产力.结果表明,巢湖水体水下光强随着深度的增加呈现出指数衰减趋势,水深1 m处光强只有表层光强的0.07%～15.17%;且不同水深处的光场分布总体呈现出西部湖...     

基于GOCI影像的太湖水体漫衰减系数遥感反演

漫衰减系数是水体光学中的一个重要参数.采用2006~2009年的太湖野外实测数据,分析了太湖水体漫衰减系数光谱特性及其影响因子,在此基础上,结合GOCI传感器数据,分别构建漫衰减系数经验模型和半分析模型,寻找适合GOCI影像的太湖漫衰减系数反演模型,并分析太湖水体漫衰减系数的时空变化特征.结果表明:1太湖水体漫衰减系数主要受非色素颗粒物吸收主导,以GOCI第4、5、7波段构建的多元线性模型反演漫衰减系数,效果最好;2太湖水体漫衰减系数值域主要分布在0~15 m-1,大体可以分为3个等级,低值区:0~4 m-1,中值区:4~8 m-1,高值区:8~15 m-1,部分高值区高于15 m-1;3太湖水体漫衰减系数存在一定时空差异性,从空间上来说,太湖水体漫衰减系数呈现一定的梯度性,从东部到西部逐渐变高;从时间上来说,早上太湖漫衰减系数相对较高,从上午到下午,大体上呈现逐渐降低的趋势.     

贫燃条件Ag-Rh/CeO2-ZrO2-Al2O3协同催化C3H6选择性还原NO的原位红外研究

将Ag-Rh浸渍到共沉淀法合成的Ce-Zr-Al上,制备出Ag(0.04)-Rh(x)/Ce0.5Zr0.5O2-75%Al2O3系列催化剂,采用BET比表面积、X射线衍射光谱(XRD)和原位漫反射傅里叶变换红外光谱(DRIFTS)对催化剂进行表征,并探讨催化剂在贫燃条件下选择性还原NO的活性和反应机理.结果表明,Ag-Rh双组分催化剂的活性较单组分Ag、Rh催化剂的高.Rh负载量为0.7%(质量分数)时,NO转化率达最佳(90.3%),且反应的起燃温度低、活性温度范围宽(300～500℃).DRIFTS结果显示,Rh的添加不仅有利于催化剂表面NO的吸附,而且能促进Ag催化生成关键反应中间体—CO—NH—,进而显著提高NO的转化率.     

漫反射光谱手工与机器制样方法测试结果与对比分析

矿物含量及其变化有可能蕴藏着环境信息。赤铁矿和针铁矿是常见的两种化合物,在各种类型的沉积物中基本都有分布。在古气候研究中,赤铁矿和针铁矿的含量变化可以用来指示气候的干湿变化。漫反射光谱方法(DRS)可以进行赤铁矿和针铁矿含量测算,具有灵敏度高、速度快、准确度高等特点。这种方法虽然很实用,但是对于样品量比较大的研究来说,其手工磨样速度比较慢,而用机器研磨则会大幅提高样品制备效率,但是机器研磨是否会对分析结果产生影响尚未有研究报道。本文对30个河流相和湖泊相样品进行了漫反射光谱对比分析实验,发现手工和机器磨样在磁性矿物浓度上的变化趋势基本一致,但是两者之间存在一定的差异。因此,如果研究目的是希望从整体变化趋势来反演气候变化的过程,用机器研磨方法可以达到要求且效率明显提高;如果是进行浓度含量等其它方面的研究,则传统的手工方法是优先选择。