吸附气泡分离法脱除废水中微量表面活性剂的数学模型

根据Ｒ．Ｌｅｍｌｉｃｈ提出的吸附气泡分离理论，运用集总参数模型，在连续稳态操作条件下研究了废水中微量表面活性剂ＣＴＡ－Ｂｒ的吸附气泡脱除方法，求得了实验条件下吸附塔中表面活性剂浓度的轴向分布函数及该过程的传质扩散参数。结论表明，在该脱除过程中，废水中表面活性剂的涡流扩散系数远比其分子扩散系数大。脱除过程速率主要受气。液界面液膜侧表面活性剂在膜内的分子扩散速率控制。     

A high-order splitting scheme for the advection-diffusion equation of pollutants

ＩｎｔｒｏｄｕｃｔｉｏｎＷｉｔｈｔｈｅｄｅｖｅｌｏｐｍｅｎｔｏｆｍｏｄｅｒｎｉｎｄｕｓｔｒｙ ,ｖａｒｉｏｕｓｐｏｌｌｕｔａｎｔｓｄｉｓｃｈａｒｇｅｉｎｔｏｔｈｅａｉｒ,ｒｉｖｅｒｓ,ｌａｋｅｓａｎｄｏｃｅａｎｓ,ｗｈｉｃｈｍａｋｅｓｔｈｅｅｎｖｉｒｏｎｍｅｎｔａｌｑｕａｌｉｔｉｅｓｗｏｒｓｅｎａｎｄｈａｓｂａｄｅｆｆｅｃｔｏｎｔｈｅｍａｎｋｉｎｄ’ｓｈｅａｌｔｈａｎｄｔｈｅｓｕｓｔａｉｎｅｄｄｅｖｅｌｏｐｍｅｎｔｏｆｉｎｄｕｓｔｒｙａｎｄａｇｒｉｃｕｌｔｕｒｅ .Ｔｈｅｅｎｖｉｒｏｎｍｅｎｔａｌｐｏ…     

几种典型除尘器收集效率的扩散模型研究

在气流速度均匀假设下用扩散理论建立了在重力沉降室、离心式除尘器和静电除尘器中粉尘粒子的浓度分布，由此浓度分布模型和除尘效率定义得出这3种典型除尘器的分级除尘效率具有相同的表达式：η=1—exp(-Dλ^2L/u)．为了使这一由扩散理论导出的分级效率公式能够用于实际计算，给出了扩散系数D的确定方法和常数λ的计算式．     

应用GIS模拟城市大气污染物浓度分布

从点源大气污染扩散模型出发,借助GIS的栅格与数据库运算功能,结合自已设计的推算流程,对兰州市大气污染物SO2的空间分布情况进行了模拟。经检验,该方法能够较准确的反映出兰州大气污染物的空间分布特征,较应用实测值进行插值的方法简便,具有较好的应用前景。     

连云港市新海地区水污染集中控制系统

本文论述了连云港市新海地区水污染集中控制系统的四个主要问题：尾水最终出口，污水截流工程，污水集中处理工艺、点源治理规划。提出了的近北远南，截流沟道、河滩漫流、排口分级管理的新观点。     

Climate laws in small European states: symbolic legislation and limits of diffusion in Ireland and Finland

ABSTRACT

The past decade has seen the introduction of framework climate change laws in several countries. The development of climate laws in two small European states, Ireland and Finland, both of which introduced national climate laws in 2015, are examined. Two questions are addressed. First, to what extent do later adopters of climate policy instruments draw on the examples of pioneering legislation? Second, how and why are pioneering climate policy instruments modified by later adopters? In both cases, the 2008 UK Climate Change Act was a source of inspiration in the early stages, particularly for civil society campaigns. Thereafter, domestic interests mobilised to remove from legislative proposals the most pioneering and ambitious parts of the UK model. The result, in both cases, was enactment of climate laws that resembled only very loosely the UK Climate Change Act.     

Modelling of silica diffusion experiments with Si in Boom Clay

A mathematical model describing the dissolution of nuclear glass directly disposed in clay combines a first-order dissolution rate law with the diffusion of dissolved silica in clay. According to this model, the main parameters describing the long-term dissolution of the glass are ηR, the product of the diffusion accessible porosity η and the retardation factor R, and the apparent diffusion coefficient D_app of dissolved silica in clay.For determining the migration parameters needed for long-term predictions, four Through-Diffusion (T-D) experiments and one percolation test have been performed on undisturbed clay cores. In the Through-Diffusion experiments, the concentration decrease after injection of ³²Si (radioactive labelled silica) was measured in the inlet compartment. At the end of the T-D experiments, the clay cores were cut in thin slices and the activity of labelled silica in each slice was determined. The measured activity profiles for these four clay cores are well reproducible.Since no labelled silica could be detected in the outlet compartments, the Through-Diffusion experiments are fitted by two In-Diffusion models: one model assuming linear and reversible sorption equilibrium and a second model taking into account sorption kinetics. Although the kinetic model provides better fits, due to the sufficiently long duration of the experiments, both models give approximately similar values for the fit parameters. The single percolation test leads to an apparent diffusion coefficient value about two to three times lower than those of the Through-Diffusion tests.Therefore, dissolved silica appears to be strongly retarded in Boom Clay. A retardation factor R between 100 and 300 was determined. The corresponding in situ distribution coefficient K_d is in the range 25–75 cm³ g⁻¹. The apparent diffusion coefficient of dissolved silica in Boom Clay is estimated between 2×10⁻¹³ and 7×10⁻¹³ m² s⁻¹. The pore diffusion coefficient is in the range from 6×10⁻¹¹ to 1×10⁻¹⁰ m² s⁻¹.     

Anomalous transport of colloids and solutes in a shear zone

Transport experiments with colloids and radionuclides in a shear zone were conducted during the Colloid and Radionuclide Retardation experiment (CRR) at Nagra's Grimsel Test Site. Breakthrough curves of bentonite colloids and uranine, a non-sorbing solute, were measured in an asymmetric dipole flow field. The colloid breakthrough is earlier than that of uranine. Both breakthrough curves show anomalously long late time tails and the slope of the late time tails for the colloids is slightly higher. Anomalous late time tails are commonly associated with matrix diffusion processes; the diffusive interaction of solutes transported in open channels with the adjacent porous rock matrix or zones of stagnant water. The breakthrough curves for different colloid size classes are very similar and show no signs of fractionation due to their (size-dependent) diffusivity. It is proposed that tailing of the colloids is mainly caused by the structure of the flow field and that for the colloid transport, matrix diffusion is of minor importance. This has consequences for the interpretation of the uranine breakthrough. Comparisons of experimental results with numerical studies and with the evaluation of the colloid breakthrough with continuous time random theory imply that the tailing in the conservative solute breakthrough in this shear zone is not only caused by matrix diffusion. Part of the tailing can be attributed to advective transport in fracture networks and advection in low velocity regions. Models based on the advection-dispersion equation and matrix diffusion do not properly describe the temporal and spatial evolution of colloid and solute transport in such systems with a consistent set of parameters.     

Simultaneous estimation of effective and apparent diffusion coefficients in compacted bentonite

Effective diffusion coefficients (D(e)) are usually measured by means of "through-diffusion" experiments in which steady state is reached, and the "time-lag" methods are used to estimate the apparent diffusion coefficient (D(a)). For sorbing radionuclides (as caesium), the time needed to reach steady-state conditions is very large, and the precision in D(a) determinations is not satisfactory. In this paper, a method that allows determining simultaneously effective and apparent diffusion coefficients in compacted bentonite without reaching steady-state conditions is described. Basically, this method consists of an "in-diffusion" experiment in which the concentration profile in the bentonite sample is used to estimate D(a), and the temporal evolution of the solute concentration in the reservoir is used to estimate D(e). This method has several advantages over the typical "through-diffusion" experiments, in particular: (a) experiment duration is significantly shorter, (b) D(a) values are measured with greater precision and (c) it is not necessary to maintain a constant solute concentration in the reservoir. This new method has been used to estimate the effective and apparent diffusion coefficients for caesium in FEBEX bentonite and in order to validate it, the results have been compared with results previously obtained with standard methods. Experimental results have been satisfactorily modelled using a simple model of diffusion in porewater and the measured value of D(e)(Cs) is very similar to D(e)(HTO) in the same bentonite. There is no evidence of "surface diffusion" in FEBEX bentonite for caesium.     

秦岭Ⅰ号隧道围岩压力的理想弹塑性分析

影响洞室稳定性的因素很多,但岩体自身的受力情况是至关重要的。在不考虑支护反力的条件下,将弹塑性应力半径作为变量,分析秦岭Ⅰ号隧道弹塑性区应力随半径的变化规律,为隧道的施工及支护提供参考。