上海制造业产业转移实证研究

区域产业转移是区域经济发展到一定程度后的必然进程。随着资源环境承载压力增加和要素成本不断提升,上海面临产业发展的战略调整期,其中制造业转移是重要部分。通过构建区位熵指标,分析上海制造业转移的必要性和可行性,同时比较安徽、江西和湖北三省区位熵数据,论证各区域在承接产业转移上的比较优势,从而明确上海制造业转移的去向,最终促进上海和三省的区域产业结构升级,加快区域经济发展。     

改性活性炭对石煤提钒废水中低浓度NH3-N和V等的吸附

为研究石煤提钒离交尾水的深度处理技术,利用质量分数为1%、5%和10%的过氧化氢溶液对ZWY15型活性炭进行改性,得到3种改性活性炭即1%AC、5%AC和10%AC;探讨其对该废水中低浓度的NH3-N、V等的吸附效果。实验结果表明:AC或改性AC的加入可使废水的碱度升高,随着吸附时间及吸附剂投加量的增加,升高幅度增大,且不同改性AC对废水碱度提高的幅度不同;相较于未改性活性炭,过氧化氢改性活性炭对V的吸附效果明显提高,去除率最大可提高30%,对NH3-N的去除率提升约11%;当投加量为60 g/L时,10%AC可使废水中V的浓度降低至1.88 mg/L,此时废水中Cr、Cd和Zn的浓度分别降低至0.006、0.010和0.036 mg/L,均低于《钒工业污染物排放标准》(GB26452-2011)所规定的排放限值。     

A Box-Behnken design for determining the optimum experimental condition of the fungicide (Vapam) sorption onto soil modified with perlite

In the present study, response surface methodology (RSM) based on the Box-Behnken design (BBD) was employed to investigate the effects of the different operating conditions on the removal of the fungicide (Vapam) onto soil modified with perlite using sorption process. The process parameters such as pH of the fungicide solution (2, 5 and 8), temperature (15, 25 and 35°C), shaking time (2, 13 and 24 h) and the percentage of perlite in the modified soil (0, 2 and 4 %) were investigated using a four-factor-three-level Box-Behnken design at an initial fungicide concentration of C₀ = 1.6 mg/L as a fixed input parameter. A second-order quadratic model suggested the optimum conditions to be as follows: fungicide solution pH of 3.57, temperature of 15°C, shaking time of 3.5 h and 4% of perlite in the modified soil which resulted in the improvement of Vapam sorption. Under optimum conditions, the fungicide (Vapam) removal was predicted 12.88 μg/g by BBD. The confirmatory experiments were conducted and the results revealed that the fungicide removal was 13.14 μg/g which indicated that the predicted and the observed values of response (Vapam removal) were in close agreement. Therefore, the soil modified with perlite holds good potential for Vapam sorption. This is the first report on fungicide Vapam sorption onto soil modified with perlite using statistical experimental design employing response surface methodology.     

脉冲喷流复合厌氧污泥床技术及应用

介绍了脉冲喷流复合厌氧污泥床技术用于低浓度有机废水处理的实验室及中试效果,以及在农村生活污水处理项目中的应用,结果表明:以该技术为核心的生活污水生物处理系统,在HRT为6～10h,即有机物容积负荷为0.93～0.52kgCOD/m3.d时,COD去除率可稳定达到35%以上,氨氮和总磷去除率可达到17%～25%,具有优化处理系统、强化处理效果、降低后续好氧段能耗及占地面积的特点。     

环境类高职院校工学结合人才培养模式构建

立足当前环境类高等职业教育人才培养中存在的突出问题,以＂以人为本＂、＂需求导向＂、＂特色品牌＂、＂工学结合＂为原则,提出了环境类高职院校应在构建人才培养＂三个平台、四个模块＂的基础上,突出实践能力培养,实施工学结合的人才培养模式。     

Determination of C(5)-C(12) perfluoroalkyl carboxylic acids in river water samples in the Czech Republic by GC-MS after SPE preconcentration

A method employing solid phase extraction followed by gas chromatography-mass spectrometry with negative chemical ionization has been developed for determination of ultratrace concentrations of perfluoroalkyl carboxylic acids in river water. The effects of the experimental parameters, such as the pH, additions of NaCl and an ion-pairing agent (tetraethylammonium bromide) and the kind of the elution agent, on the efficiency of the test acid extraction have been studied. The analyte extraction recoveries and the limits of detection and determination have been found. The method developed has been tested on determinations of perfluoroalkyl carboxylic acids in the waters of the two largest Czech rivers, Vltava and Labe (Elbe). The best extraction results have been attained without any alteration of the sample pH, with an addition of tetrabutylammonium bromide (a concentration of 50 μg mL⁻¹ in the sample) and using methanol as the elution agent. Under these conditions, the recoveries of the test acids in the spiked real samples are within ranges from 60% to 104% and 53% to 111% for analyte concentration levels of 1.40 ng mL⁻¹ and 0.14 ng mL⁻¹, respectively, depending on the lengths of the perfluorinated chains of the acids. In general, the recovery decreases with increasing length of this chain. The method developed exhibits very low limits of detection and determination and the results are fully comparable with those obtained when using more expensive HPLC-MS/MS instrumentation. Typical values amount to tenths to tens of pg mL⁻¹ and units to one hundred pg mL⁻¹ for the limits of detection and determination, respectively; the measuring sensitivity increases with increasing length of the analyte chain. The analyzes of real samples from the Vltava and Elbe rivers have demonstrated that the results obtained are similar to the values published for contamination of the Elbe and other rivers in western and central Europe. The concentrations determined are of the order of units to tens of pg mL⁻¹ and the C₈-C₁₀ acids occur most often.     

Photocatalytic degradation with immobilised TiO(2) of three selected neonicotinoid insecticides: imidacloprid, thiamethoxam and clothianidin

This research focused on photocatalytic degradation of imidacloprid, thiamethoxam and clothianidin employing a tailor-made photoreactor with six polychromatic fluorescent UVA (broad maximum at 355 nm) lamps and immobilised titanium dioxide (TiO₂) on glass slides. The disappearance was followed by high pressure liquid chromatography (HPLC-DAD) analyses, wherein the efficiency of mineralization was monitored by measurements of total organic carbon (TOC). Within 2 h of photocatalysis, all three neonicotinoids were degraded following first order kinetics with rate constants k = 0.035 ± 0.001 min⁻¹ for imidacloprid, k = 0.019 ± 0.001 min⁻¹ for thiamethoxam and k = 0.021 ± 0.000 min⁻¹ for clothianidin. However, the rate of mineralization was low, i.e. 19.1 ± 0.2% for imidacloprid, 14.4 ± 2.9% for thiamethoxam and 14.1 ± 0.4% for clothianidin. This indicates that several transformation products were formed instead. Some of them were observed within HPLC-DAD analyses and structures were proposed according to the liquid chromatography-electro spray ionization tandem mass spectrometry analyses (LC-ESI-MS/MS). The formation of clothianidin, as thiamethoxam transformation product, was reported for the first time.     

The dynamics of landfill diversion: Economic drivers, policy factors and spatial issues: Evidence from Italy using provincial panel data

Waste disposal is an issue that is becoming increasingly important in policy terms in the European Union, and in Italy, a country showing strong geographical heterogeneity in waste management. This paper analyses the process of decoupling/delinking between economic growth and landfilling trends in a framework where economic, policy, geographical elements and spatial issues are all considered as drivers behind the phenomenon. We exploit an original and very rich provincial panel dataset over 1999–2005 for the 103 Italian provinces. Evidence shows that the observed ‘absolute’ decoupling between economic growth and landfilling is driven by a mix of structural factors. Among the main factors, population density, more than the provincial income level, emerges as a crucial driver: local opportunity costs and landfill externalities matter in shaping waste policies and local commitment to a transition away from landfilling of waste (landfill diversion). However, not only structural factors are relevant. If on the one hand landfill taxes are not a significant driver of the phenomenon, waste management tools, such as separated collection for recycling, and the tariff system connected to waste services, bring about significant effect on the amount of landfilled waste. Moreover, regarding the analysis of spatial interrelations across provinces, we note that the presence of incinerators in nearby provinces increases landfill diversion, due probably to free riding behaviour or intra-provinces ‘agreements’ on waste management; this is not true for nearby landfill sites, that cause for a given province a strong lock in effect. Future research could strengthen the analysis of policy effectiveness at regional level, focusing on policy endogeneity, and the full investigation of spatial correlations in waste disposal performances.     

应急决策的理论与方法探讨

围绕基于模板的规划、组织决策协调与基于Agent系统的协调机制以及马尔可夫决策规划等应急决策的关键理论与方法,对国内外相关研究进行分析与总结;提出以决策理论规划为应急决策研究的主要建模和分析框架;采用逻辑程序与规划相结合的思想,研究基于应急预案模板的应急决策规划方法;基于应急处置任务的时间、资源约束关系,研究应急处置任务的多Agent马尔可夫决策建模及求解方法。基于决策理论规划的应急决策理论可以很好地用于应急决策的多阶段动态过程建模,而且能够利用预案模板降低模型求解的难度。上述研究完善和丰富了应急决策的理论和方法,为科学的应急决策实践以及应急决策支持系统提供了一种理论和方法。     

地基液化导致沉箱码头破坏及地基加固方法的非线性数值分析

地震作用引发的地基液化,往往导致沉箱基础的破坏。本文基于Biot两相饱和多孔介质动力耦合理论,采用FE-FD耦合数值分析方法,对液化海床沉箱基础的地震反应进行非线性有效应力分析。在数值分析过程中,建立了以土骨架位移和超静孔隙水压力表达的us-pw动力固结方程和循环弹塑性本构模型,该方法能够很好地模拟地震作用下沉箱码头的动力特性及液化破坏的影响。通过数值模拟计算,分析了采用碎石桩进行置换砂区域的防液化加固方法,并就碎石桩处理区域的选择提出了建议。