全文获取类型
收费全文 | 857篇 |
免费 | 65篇 |
国内免费 | 155篇 |
专业分类
安全科学 | 71篇 |
废物处理 | 33篇 |
环保管理 | 96篇 |
综合类 | 496篇 |
基础理论 | 98篇 |
环境理论 | 1篇 |
污染及防治 | 69篇 |
评价与监测 | 179篇 |
社会与环境 | 24篇 |
灾害及防治 | 10篇 |
出版年
2024年 | 2篇 |
2023年 | 12篇 |
2022年 | 15篇 |
2021年 | 20篇 |
2020年 | 19篇 |
2019年 | 15篇 |
2018年 | 18篇 |
2017年 | 23篇 |
2016年 | 24篇 |
2015年 | 22篇 |
2014年 | 54篇 |
2013年 | 69篇 |
2012年 | 53篇 |
2011年 | 61篇 |
2010年 | 55篇 |
2009年 | 54篇 |
2008年 | 29篇 |
2007年 | 63篇 |
2006年 | 41篇 |
2005年 | 41篇 |
2004年 | 45篇 |
2003年 | 47篇 |
2002年 | 51篇 |
2001年 | 29篇 |
2000年 | 35篇 |
1999年 | 27篇 |
1998年 | 22篇 |
1997年 | 30篇 |
1996年 | 32篇 |
1995年 | 16篇 |
1994年 | 14篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1985年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1077条查询结果,搜索用时 796 毫秒
611.
612.
613.
614.
615.
616.
A. Kunwar 《International Journal of Green Energy》2016,13(4):335-343
High penetration level of wind power has significant impact on the dynamic performance of power system. Power system with existing high-voltage direct current (HVDC) link may influence the stability of power system at high penetration level of wind power. This article investigates the stability issues of power system with existing HVDC link for different penetration level of doubly fed induction generator (DFIG) and direct drive synchronous generator (DDSG) based wind farms. The small signal stability analysis shows that power system with HVDC link has improved the stability of the power system for increased penetration of DFIG- and DDSG-based wind farms. 相似文献
617.
Cloud point extraction coupled with HPLC-UV for the determination of
phthalate esters in environmental water samples 总被引:3,自引:0,他引:3
A method based on cloud point extraction was developed to determine phthalate esters including di-ethyl-phthalate (DEP), di- (2-ethylhexyl)-phthalate (DEHP) and di-cyclohexyl-phthalate (DCP) in environmental water samples using high-performance liquid chromatography separation and ultraviolet detection (HPLC-UV). The non-ionic surfactant Triton X-114 was chosen as extraction solvent. The parameters affecting extraction efficiency, such as concentrations of Triton X-114 and Na2SO4, equilibration temperature, equilibration time and centrifugation time were evaluated and optimized. Under the optimum conditions, the method can achieve preconcentration factors of 35, 88, 111 and detection of limits of 2.0, 3.8, 1.0 ng/ml for DEP, DEHP and DCP in 10-ml water sample, respectively. The proposed method was successfully applied to the determination of trace amount of phathalate esters in effluent water of the wastewater treatment plant and the lixivium of plastic fragments. 相似文献
618.
N,O-bis(trimethylsily)trifluoroacetamide (BSTFA) and N-methyl-N(trimethylsily) trifluoroacetamide (MSTFA) are common derivatization reagents used in the GC-MS analysis of estrogen steroids such as estrone (E1) and 17(-ethinylestradiol (EE2). In this study, three trimethylsilyl (TMS) steroid derivatives, mono-and di-trimethylsilyl EE2 and mono-trimethylsilyl E1, were observed during the derivatization of EE2 with BSTFA or MSTFA and/or GC separation. Factors influencing the production of multiple TMS derivatives and their relative abundance were examined. It was found that both methanol and bisphenol A competed with estrogenic esteroids when reacting with silylation reagents, and thus affected the formation of TMS derivatives and their relative abundance in the derivatization products. Methanol was found to be more reactive than bisphenol A with the BSTFA reagent. None of the three solvents tested in this study could prevent the generation of multiple TMS derivatives during the derivatization of EE2 with BSTFA, followed by GC analysis. A similar result was observed using MSTFA as the derivative reagent followed by GC analysis. Thus, the suitability of BSTFA or MSTFA as the derivatization reagent for the determination of E1 and EE2 by GC-MS, under the conditions reported here, is questionable. This problem can be solved by adding trimethylsilylimidaz (TMSI) in the BSTFA reagent as recommended, and the performance of the method has been proved in this study. 相似文献
619.
Black carbon (BC) can strongly adsorb hydrophobic organic compounds (HOCs).The HOC sorption to coated BC could be attenuated in soil and sediment compared with that of the parent BC.To study the potential causes of the sorption attenuation,humic acid (HA) and BC were isolated.Phenanthrene (PHE) was selected as the representative of HOCs.BC was coated with the precipitated HA.The PHE sorption to the HA-coated BC was determined.The HA coatings on BC could result in the significant sorption attenuation of PHE to BC.The attenuation varied in different HA origin and was positively correlated to the aromaticity of HA.The attenuation could be explained by the direct competition between HA and PHE for the available sorption sites on BC and the reduction of the available sorption sites as a result of the pore blockage of BC caused by the HA coatings.Therefore,the HA coatings on BC was one potential cause of the attenuation of HOC sorption to BC in soil and sediment. 相似文献
620.
Anoxic biodegradation of dimethyl phthalate (DMP) by activated sludge cultures under nitrate-reducing conditions 总被引:3,自引:0,他引:3
Worldwide extensive use of plasticized plastics has resulted in phthalates pollution in different environment. Nitrates from industry and agriculture are also widely disseminated in the soils, natural waters and wastewaters. Dimethyl phthalate (DMP) biodegradation by activated sludge cultures under nitrate-reducing conditions was investigated. Under one optimized condition, DMP was biodegraded from 102.20 mg/L to undetectable level in 56 h under anoxic conditions and its reaction fitted well with the first-order kinetics. Using the high-performance liquid chromatography (HPLC) and liquid chromatography mass spectrometry (LC-MS) analysis, mono-methyl phthalate (MMP) and phthalic acid (PA) were detected as the major intermediates of DMP biodegradation. When combined with the determination of chemical oxygen demand (CODCr) removal capacity and pH, DMP was found to be mineralized completely under anoxic conditions. The biodegradation pathway was proposed as DMP → MMP → PA → … → CO2 H2O.The molar ratio of DMP to nitrate consumed was found to be 9.0:1, which agrees well with the theoretical stoichiometric values of DMP biodegradation by nitrate-reducing bacteria. The results of the non-linear simulation showed that the optimum pH and temperature for the degradation were 7.56 and 31.4℃, respectively. 相似文献