某石油炼制企业VOCs排放源强反演研究

选取我国北方某石油炼制企业为研究对象,针对其挥发性有机物(VOCs)排放,于春季3月开展了厂界周边大气VOCs环境浓度监测,并利用ISCST-3空气质量模型反推出该企业VOCs排放源强.监测结果表明,厂外上风向背景点与下风向受体点TVOCs浓度平均值分别为28.6×10-9和88.3×10-9,且2个区域VOCs还存在化学组分特征差异,背景点以乙烷、丙烷、乙烯为主,而受体点化学组分中丙烯、异丁烷、丁烷、异戊烷、戊烷的体积浓度百分比显著上升,说明该炼油厂VOCs排放体量大,对局地环境影响显著.扣除背景点VOCs,获得了该炼油厂VOCs排放化学成分谱,其主要成分体积浓度百分比:乙烷(23.4%)、丙烷(11.8%)、丁烷(10.4%)、异丁烷(9.0%)、戊烷(5.3%)、异戊烷(6.4%)、丙烯(11.5%),成分谱特征与国内相关文献相似.ISCST-3模型反演结果显示,该炼油厂TVOCs年排放量平均值为(2201.6±1011.9) t/a,折合排放因子约0.73g VOCs/kg原油.该计算结果偏低,原因可能在于:其一,测试季节为春季,较低的环境温度致使了炼油厂挥发散逸环节的排放低于全年平均水平;其二,ISCST-3模型为扩散模型,未考虑VOCs化合物在局地范围的化学衰减.     

Emissions of volatile hydrocarbons from floating roof tanks and their local dispersion: Considerations for normal operation and in case of damage

This work investigates the release and dispersion of volatile organic hydrocarbons, which may escape from external floating roof tanks (EFRT) during normal operation or in case of damage. The dispersion will be described using CFD simulations in close range of the EFRT where hazardous areas are assigned. The aim of this work is to investigate which events can lead to emissions in dangerous quantities and to estimate the corresponding likelihood with regard to explosion protection. An emission in hazardous amount is present if the lower explosion limit has been exceeded and if the extent of this emission is not too low. It is discussed in particular whether the used zoning of potentially explosive areas is conservative or over-conservative.     

Assessing the impact of air pollution sources in Hong Kong, a densely populated city

As the simple dispersion model tested is not sufficiently accurate to predict the SO2 concentration in complex terrain commonly encountered amongst high rise buildings in Hong Kong, and the lack of comprehensive local wind data at most sites prevents the use of more advanced dispersion model to assess the impact of major air pollutant sources, a receptor model approach is adopted for the apportionment of air pollution sources in Hong Kong. The preliminary results obtained are presented and discussed.     

恒定横流底部多孔排放近区污水稀释扩散效果因素研究

借助于人工模型试验，分析了恒定横流底部多孔排放时扩散器设计参数（射流角度、射流速度、喷口个数）、上升管间距）及环境参数（环境水深、环境流速）对污水近区稀释扩散效果的影响，实验结果表明，除了环境条件对污水稀释扩散效果影响明显之外，扩散器设计参数对污水的近区稀释扩散也有显著的影响，针对白龙港排放口水域，喷口射流角度宜控制在１０°左右，喷口个数取１６个     

核电厂址事故大气弥散因子计算的实验与理论研究

在目前常用的计算核电厂事故概率大气扩散因子的模式基础上提出了考虑内边界层影响的计算模式，根据某待建滨海核电厂址大气弥散实验的实测参数，分别采用本模式和常用模式估算了厂址边界０．５ｋｍ外的最终评价用事故概率扩散因子和各途径的剂量及有效剂量。计算结果表明，无论是事故概率扩散因子还是个人有效剂量，本模式给出的值都是常用模式的５．９倍。因此，在不能忽略内边界层出现频率的滨海厂址，必须考虑内边界层对事故扩散     

Experimental verification for real-time environmental emergency response system: WSPEEDI by European tracer experiment

Japan Atomic Energy Research Institute has developed an emergency response system WSPEEDI to forecast long-range atmospheric dispersions of radionuclides discharged into the atmosphere. The latest version of WSPEEDI consists of an atmospheric dynamic model MM5 for calculating meteorological fields and a particle random-walk model for atmospheric dispersion. The performance of WSPEEDI was evaluated by data obtained from a field tracer experiment over Europe (ETEX) in this paper. The model validation was done with respect to the following points: (1) the dependence of model accuracy on the temporal and spatial resolutions of the meteorological fields and (2) the superiority of an atmospheric dynamic model over a mass-consistent wind model. Regarding (1), it was shown that the calculation accuracy of the new version with high temporal resolution was improved, especially at the edge of the plume. Moreover, although the increase in horizontal spatial resolution of the old version had no substantial effect on the model performance, increase in horizontal resolution of the new version contributed to the significant improvement of the calculation accuracy. These results showed that the dynamically calculated meteorological field with the spatial resolution of the meso-β–γ scale greatly improved calculation accuracy.     

纳米颗粒的分散及其在水与废水处理中的应用

纳米颗粒由于其吸附活性而极易产生自身团聚 ,这不利于纳米颗粒在使用介质中的分散并影响其应用。本文综述了近年来有关纳米颗粒在水中的分散方法、原理及影响因素 ,归纳总结了分散的纳米颗粒在强化水处理中的若干应用。     

Integrating models to predict regional haze from wildland fire

Visibility impairment from regional haze is a significant problem throughout the continental United States. A substantial portion of regional haze is produced by smoke from prescribed and wildland fires. Here we describe the integration of four simulation models, an array of GIS raster layers, and a set of algorithms for fire-danger calculations into a modeling framework for simulating regional-scale smoke dispersion. We focus on a representative fire season (2003) in the northwestern USA, on a 12 km domain, and track the simulated dispersion and concentration of PM_2.5 over the course of the season. Simulated visibility reductions over national parks and wilderness areas are within the ranges of measured values at selected monitoring sites, although the magnitudes of peak events are underestimated because these include inputs other than fire. By linking the spatial and temporal patterns of haze-producing emissions to climatic variability, particularly synoptic weather patterns, and the stochastic nature of fire occurrence across the region, we can provide a robust method for estimating the quantity and distribution of fire-caused regional haze under climate-warming scenarios.     

Steady Shallow-Water Current and Solute Transport around a Semi-Conical Headland

Laboratory experiments have been carried out to investigate the effects of a sloping wall headland on the flow characteristics and the associated concentration distributions from a point source around the headland. A semi-conical headland with a slope of 1:2 was set up in a flow basin, 4.8 m long and 3.8 m wide. In this paper, the experimental results of a steady shallow-water current are reported. Three dimensional flow velocities in the basin were measured using Sontek-ADV instrument. The dye concentration levels in the basin were measured by two fluorometers. The experimental results showed a large-scale re-circulation region behind the semi-conical headland. The peak turbulence energy, at about 53% of the local kinetic flow energy, coincides with the region of high velocity gradient. Significant vertical flows were observed around the area near the downhill slope of the headland, with a maximum ratio of vertical to horizontal velocities being about 22%. Such relatively significant vertical scouring velocities, coupled with strong turbulence energy and high horizontal velocity gradients in the same region, could cause severe bed erosion. The experimental results have also been compared with the predicted results of a depth-averaged numerical model. The predicted eddy structure and the concentration distribution in the re-circulation area were found to compare favourably with the experimental results. However, the discrepancies in the flow velocities and the concentration levels near the headland were apparent. It was observed that the dye concentration continued to spread in the cross-stream direction after passing the headland, whereas only a limited extent of the lateral spreading was predicted by the numerical model further downstream of the headland.