LPWCO method for the treatment of high concentrated organic wastewater

Based on wet air oxidation (WAO) and Fenton reagent, thispaper raises a new low pressure wet catalytic oxidation(LPWCO)which requires low pressure for the treatment of highlyconcentrated and refractory organic wastewater. Compared withgeneral wet air oxidation, the pressure of the treatment(0.1-0.6MPa) is only one of tens to percentage of latter(3.5-10MPa). Inaddition, its temperature is no more than 180℃.Compared withFenton reagent, while H2O2/COD(weight ratio) less than 1.2, theremoval of COD in the treatment is over twenty percents more thanFenton's even the value of COD is more than 14000mg/L. In thispaper, we study the effect factor of COD removal and the mechanismof this treatment. The existence of synergistic effect (catalytic oxidation and carbonization) for COD removal in H2SO4-Fenton reagent system under the condition of applied pressure and heating (0.1-0.6MPa, 104-165℃) was verified. The best condition of this disposal are as follows:H2O2/COD(weight ratio)=0.2-1.0, Fe2+ 0.6×10-3 mol, H2SO4 0.5mol, COD>1×104mg/L, the operating pressure is 0.1-0.6MPa and temperature is 104-165℃. This method suit to dispose the high-concentrated refractory wastewater, especially to the wastewater containing H2SO produced in the manufacture of pesticide, dyestuff and petrochemical works.     

黄磷尾气中单质磷的测定

研究了测定黄磷尾气中单质磷的分析方法 ,该方法具有灵敏度高 ,线性好 ,操作快速、简便的特点 ,检测限 1μg 5mL ,摩尔吸光系数为 4 5× 10 4L mol·cm ,线性相关系数为 0 9998     

滇池细菌总数与有机碳、氮、磷的调查研究

通过对滇池水体一年多的定点采样工作,重点调查研究了草海、外海表层水中细菌数量及有机营养盐碳、氮、磷的季节变化规律,分析探讨了细菌总数与环境条件和有机营养盐之间的某些关系.对滇池富营养治理提出了一些建议,并提出利用微生物学的方法参与这一研究.     

高级氧化技术机理及在水处理中的应用进展

综述了近年来发展迅速的高级氧化技术，主要包括Fenton法、臭氧氧化法、湿式氧化技术、超临界水氧化法、纳米光催化氧化法电化学催化降解法及超声降解法等。介绍了各种高级氧化技术的基本原理及在废水处理中的应用进展，并对其特点进行了评述。     

九龙江流域水体有机污染物背景调查方法

阐述了九龙江流域水体有机污染物背景调查的重要性和必要性,比较详细地论述了调查方案的制定方法、分析方法的确立、监测过程中的质量控制和质量保证措施等。     

SBR法处理中药材有机废水工艺研究

应用ＳＢＲ法对中药材有机废水进行了研究。考察了ＣＯＤＣＲ、ＢＯＤ５、ＳＳ、ＮＨ３－Ｈ的处理效果，以及ＰＨ、水温、污泥负荷等条件对去除率的影响。运行结果表明，ＰＨＯ ６．０－９．０、ｔ为１５－３０℃、污沁荷０．３ｋｇＢＯＤ５／ｋｇＭＬＳＳ．ｄ，运行程序：进水０．５ｈ（限制曝气）、曝气１０ｈ、脱氮１．５ｈ，沉降０．５ｈ，排水０．５ｈ、闲置１１ｈ，周期时间２４ｈ时ＣＯＤＣＲ去除率８８％、ＢＯＤ５９４％、     

土壤中总硒与水溶性硒相关性的环境因素

通过对湖北省部分地区土壤中总硒与水溶性硒的调查研究，分析土壤中总硒与水溶性硒的相关性与自然环境因素的关系。从而探讨导致缺硒和富硒疾病的成因。     

骆马湖的氮磷平衡及实施截污工程对水质改善效果的研究

骆马湖“九五”期间的氮磷平衡分析结果表明：氮磷在骆马湖湖体中的滞留量分别为1188.89t/a和193.36t/a。根据骆马湖的水质要求，在骆马湖截污工程完成后，没有新的污染进入水体的前提下，对骆马湖水体通过自然净化恢复到要求状态所需的时间进行了详细的数学推导和科学论证，结果表明，在不考虑底泥营养物质的情况下，只需0.19年左右的时间就能恢复，如果考虑底泥的影响。也只需0.59年左右的时间就能恢复，因此得出结论：对骆马湖实施截污是加速骆马湖水体改善的最佳途径。     

厌氧处理原理及其在低浓度有机废水处理中的应用现状

介绍了厌氧处理原理，并对厌氧处理低浓度废水的最新进展进行了较全面的综速，高效厌氧反应器及组合工艺为这一发展提供了可能。高效厌氧反应器中以膨胀颗粒污泥床（ECSB）反应器为首选。其结构及远行特性决定了它在处理低浓度虚水方面具有潜在的优势，但中国EC,SB的应用仅处于研究阶段，尚未有生产规模的EGSB；组合工艺对低浓度废水中污染物去除率极高，出水中COD、NH3-N、TP和SS浓度均可达到较高的排放标准，对生活污水、稀释后的工业有机废水等低浓度有机废水处理具有广阔的前景。     

Transformation of Organic Matter of the Larch Forest Soils in the Northern Taiga of Nizhne-Tungusskoe Plateau, Central Siberia

The evaluation of biospheric role of the boreal forests in the accumulation of carbon is connected with the evaluation of organic matter (OM) pool in soils. The research sites were larch forests, they are situated on Nizhne-Tungusskoe Plateau. Larch forests of feather-moss and lichen types (110 and 380 years old) were formed on 'ochric podbur' soils. Litter stocks are 3.5–4.5 kg m^{− 2} with thickness 10–25 cm. Cryomezomorphic northern taiga soils contains 38–73 t (carbon) ha^{− 1}. Pool of fast mineralized OM has average value 38.1 t (carbon) ha^{− 1}, including 20.5 and 6.4 t (Carbon) ha^{− 1} of labile compounds on surface and in the soil, and 11.2 t (carbon) ha^{− 1} of mobile OM. Microbial mass reaches 1.78–3.47 t (carbon) ha^{− 1}, its proportion is 3.6–4.9% of the total OM carbon. Zoomass of feather-moss larch forest is 0.20–0.61 * 10^{− 2}, in lichen larch forest −0.01–0.07 * 10^{− 2} t (carbon) ha^{− 1}. A pool of resistant to biological decomposition and bonded to mineral soil matrix OM is 17.7 t (carbon) ha^{− 1} and it varies from 18.6 to 29.0 in feather-moss larch forest, and from 6.4 to 17.0 t (carbon) ha^{− 1} in lichen larch forest. Two-years field experiment has been performed to determine transformation rates of various plant litter fractions and to clarify the role of soil biota in these processes. The results showed participation of all biota groups in the decomposition of plant residues caused weight loss of larch-needles and root mortmass. Isolation of organic matter from all-size invertebrate groups leads to some decrease of decomposition activity.