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891.
Altitude dependence of polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) in surface soil from Tibetan Plateau, China 总被引:5,自引:0,他引:5
Pu Wang Qinghua Zhang Yawei Wang Thanh Wang Xiaomin Li Yingming Li Lei Ding Guibin Jiang 《Chemosphere》2009,76(11):1498-1504
Remote mountain areas besides high latitude regions are beginning to receive increased attention in studying the transport and behavior of persistent organic pollutants (POPs). In the present work, surface soil samples were collected from the Tibetan Plateau, the highest plateau in the world which includes the northern slope of Mt. Qomolangma, to investigate the levels and trends of polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) along the altitudinal gradient. The average PCB and PBDE concentrations were 185.6 ng kg−1 dry weight (dw) (range 47.1–422.6 ng kg−1 dw) and 11.1 ng kg−1 dw (range 4.3–34.9 ng kg−1 dw), respectively. Regression analysis between the log-transformed TOC-normalized concentrations and the altitudes of the sampling sites showed two opposite trends with regard to altitude dependence: negative relationship with altitude below about 4500 m followed by a positive altitude dependence above this point. Considering minimum anthropogenic activities and very sparse precipitation in the north of Himalayas, the trends above 4500 m imply that the significant altitude dependence of these two groups of POPs were irrespective of pollution sources, but could be predicted by the global distillation effect involving cold condensation in high altitude mountain areas. Increasing levels of heavier congeners were found in higher altitude sites, although the lighter congeners were the main contributors to the total amount, suggesting that less volatile congeners seem to become enriched easier than those more volatile at higher altitudes in this region. 相似文献
892.
不同水温时底泥扰动对不同形态磷分布的影响 总被引:3,自引:0,他引:3
研究了江南地区典型水温条件下,底泥扰动对上覆水中不同形态磷迁移的影响.结果表明,不同水温条件下,底泥扰动均有利于上覆水中溶解态磷(即溶解性总磷酸盐(DTP),包括溶解性正磷酸盐(DIP)和溶解性有机磷(DOP))向底泥迁移.与对照试验相比,不同水温时的扰动均导致DIP/TP和DTP/TP明显降低.与初始状态(第0天时)相比,扰动导致DIP/TP分别降低了39.61百分点(冬季水温)和17.38百分点(夏季水温),而DTP/TP则分别降低了39.16百分点(冬季水温)和19.06百分点(夏季水温).相反,对照试验中,DTP/TP分别上升了24.90百分点(冬季水温)和23.37百分点(夏季水温).这说明底泥扰动促进了溶解态磷向颗粒态磷(PP)的转化. 相似文献
893.
Ecologists are beginning to recognize the effect of heterogeneity on structure and function in arid and semiarid ecosystems.
Additionally, the influences of temperature on ecosystems are widely documented, but landscape temperature patterns and relationships
with vegetation are rarely reported in ecological studies. To better understand the importance of temperature patterns to
the conservation and restoration of native ecosystems, we designed an experiment to investigate relationships among soil surface
temperature, landscape heterogeneity, and grazing intensity. Grazing intensity did influence the vegetation structure and
composition. Heavy treatments had the greatest bare ground and the least vertical structure. Ungrazed treatments had the most
litter and live grass cover. However, average temperatures among the three grazing treatments were not different and ranged
less than 2°C during midday summer periods. The temperature difference between riparian and upland landscapes within grazing
treatments was 21°C. Landscape position (riparian vs. upland) did have a significant influence on soil surface temperature
and produced a variation in temperature 11 times greater than grazing intensities. Thermal heterogeneity did not differ among
grazing treatments. Lower soil surface temperatures (associated with riparian areas) may provide a critical thermal refuge
for many animals in arid and semiarid ecosystems on hot summer days, when air temperatures can exceed 37°C. Riparian zones,
specifically riparian vegetation, are an important component in ecosystem management. 相似文献
894.
应用电性拓扑状态指数预测烷烃自燃点 总被引:2,自引:0,他引:2
建立了一个基于人工神经网络的定量结构-性质相关性模型,用于52种烷烃化合物自燃点的预测研究。应用原子类型电性拓扑状态指数作为表征分子结构特征的描述符。该指数既能表征分子的电子特性,又反映其拓扑特征,同时易于计算,并有较强的同分异构体区分能力。采用误差反向传播(BP)神经网络方法对烷烃自燃点与电性拓扑状态指数间可能存在的非线性关系进行拟合。将52种烷烃样本随机划分为训练集(30种)、验证集(8种)和测试集(14种),并通过“试差法”确定网络的最优参数。运用最佳网络结构[64—1]对实验样本进行模拟,结果表明,多数样本的自燃点预测值与实验值符合良好,对于测试集,平均预测绝对误差为8.4℃,均方根误差为11.8,优于多元线性回归方法和传统基团贡献法所得结果。该方法的提出为工程上提供了一种根据分子结构预测有机物白燃点的有效方法。 相似文献
895.
为研究建筑火灾增长阶段室内温度的时间变化规律,提出了高温烟气的主要几种热损失的计算方法,发展了受火室与未受火室及环境的热平衡方程,并采用牛顿-拉菲尔森法迭代得到受火室的温度变化.计算了慢速、中速、快速、超快速四种火灾增长速率下,受火室气相温度及烟气热损失随时间的变化.本文的研究方法及有关结果可以为建筑防火及安全疏散提供有力依据. 相似文献
896.
Air Quality in Norwich, UK Multi-Scale Modelling to Assess the Significance of City, County and Regional Pollution Sources 总被引:1,自引:0,他引:1
T. Chatterton S. Dorling A. Lovett M. Stephenson 《Environmental monitoring and assessment》2000,65(1-2):425-433
Norwich is the eastern most city in the United Kingdom. Despite a population of only 100,000 and very little local industry, studies have shown that the city experiences levels of nitrogen dioxide, ozone, particulates and sulphur dioxide exceeding the UK Air Quality Standards. Because of Norwich's situation within a large, predominantly rural area a large non-resident workforce is one factor that contributes to large, often very congested traffic flows. The city's location close to the European mainland also exposes it to polluted airmasses transported from the continent, especially in the case of particulates and ozone. In order to assess the relative contributions of local and regional sources, data from rural and urban monitoring sites are to be used in conjunction with ADMS-Urban and the UK Meteorological Office's NAME model. 相似文献
897.
A. Joyce J. Adamson B. Huntley T. Parr R. Baxter 《Environmental monitoring and assessment》2001,68(2):127-136
Daily mean, maximum and minimum surface airtemperature data were gathered from a network ofautomatic weather stations (AWS) within the Moor HouseNational Nature Reserve in northern England. Five AWSwere installed next to the official EnvironmentalChange Network weather station at Moor House. Datawere compared graphically and correction constantswere calculated to adjust data from each AWS to thestandard of the official station by optimising theconcordance correlation coefficient. Each correctedstation was re-located next to one of five in-situstations in and around the reserve, allowingcorrection of all temperature sensors to a commonstandard. The mean error associated with measureddaily mean, maximum and minimum temperature for eachsensor does not exceed ±0.2 K. The procedurequantifies a source of systematic measurement error,improving the identification of spatial temperaturedifferences between stations. 相似文献
898.
XIAO Jun-ping WANG Xue-feng ZHOU Qing-xiang FAN Xiao-yuan SU Xian-f Bai Hua-hu DUAN Hai-jing 《环境科学学报(英文版)》2007,19(5):622-627
A rapid, simple and sensitive method was demonstrated for the determination of phenolic compounds in water samples by alternating-current oscillopolarographic titration. With the presence of sulfuric acid, phenol could be transferred into a nitroso-compound by reacting with NaNO2. The titration end-point was obtained by the formation of a sharp cut in the oscillopolarographic with infinitesimal NaNO2 on double platinum electrodes. The results showed that phenol concentration had an excellent linear relationship over the range of 4.82×10-6-9.65×10-3 mol/L, the RSD of the proposed method was lower than 1.5%, and the spiked recoveries of three real water samples were in the range of 95.6%-106.9%. 相似文献
899.
Anaerobic ammonium oxidation (ANAMMOX) technology has potential technical superiority and economical efficiency for the nitrogen removal from landfill leachate, which contains high-strength ammonium nitrogen (NH4 -N) and refractory organics. To complete the ANAMMOX process, a preceding partial nitritation step to produce the appropriate ratio of nitrite/ammonium is a key stage. The objective of this study was to determine the optimal conditions to acquire constant partial nitritation for landfill leachate treatment, and a bench scale fixed bed bio-film reactor was used in this study to investigate the effects of the running factors on the partial nitritation. The results showed that both the dissolved oxygen (DO) concentration and the ammonium volumetric loading rate (Nv) had effects on the partial nitritation. In the controlling conditions with a temperature of 30±1℃, Nv of 0.2-1.0 kg NH4 -N/(m3d), and DO concentration of 0.8-2.3 mg/L, the steady partial nitritation was achieved as follows: more than 94% partial nitritation efficiency (nitrite as the main product), 60%-74% NH4 -N removal efficiency, and NO2--N/NH4 -N ratio (concentration ratio) of 1.0-1.4 in the effluent. The impact of temperature was related to iVv at certain DO concentration, and the temperature range of 25-30癈 was suitable for treating high strength ammonium leachate. Ammonium-oxidizing bacteria could be acclimated to higher FA (free ammonium) in the range of 122-224 mg/L. According to the denaturing gradient gel electrophoresis analysis result of the bio-film in the reactor, there were 25 kinds of 16S rRNA gene fragments, which indicated that abundant microbial communities existed in the bio-film, although high concentrations of ammonium and FA may inhibit the growth of the nitrite-oxidizing bacteria and other microorganisms in the reactor. 相似文献
900.
WANG Jian-li ZHONG Jun-bo GONG Mao-chu LIU Zhi-min ZHAO Ming CHEN Yao-qiang 《环境科学学报(英文版)》2007,19(6):644-646
Five monolithic catalysts with low noble metal content were prepared by irnmerge method (Pt/γ=Al2O3, Pt/La-Al2O3, Pt/YSZ-AI203, Pt+Pd/La-Al2O3 and Pd/La-Al2O3) and their activity measurements were carried out in a conventional fixed-bed flow reactor. The results show that La-Al2O3 can promote activity of the prepared catalysts and can decrease the complete conversion temperature of cooking fume. The Pt/La-Al2O3 catalyst has the highest activity and can be applied in wide range of gas hourly space velocity (GHSV). Some characterizations (XRD, TPR) were carried out with the objective to explain differences in catalytic behaviors. The prepared catalyst showed a great potential for application. 相似文献