Enzyme-Retted Flax Fiber and Recycled Polyethylene Composites

Municipal solid wastes generated each year contain potentially useful and recyclable materials for composites. Simultaneously, interest is high for the use of natural fibers, such as flax (Linum usitatissimum L.), in composites thus providing cost and environmental benefits. To investigate the utility of these materials, composites containing flax fibers with recycled high density polyethylene (HDPE) were created and compared with similar products made with wood pulp, glass, and carbon fibers. Flax was either enzyme- or dew-retted to observe composite property differences between diverse levels of enzyme formulations and retting techniques. Coupling agents would strengthen binding between fibers and HDPE but in this study fibers were not modified in anyway to observe mechanical property differences between natural fiber composites. Composites with flax fibers from various retting methods, i.e., dew- vs. enzyme-retting, behaved differently; dew-retted fiber composites resulted in both lower strength and percent elongation. The lowest level of enzyme-retting and the most economical process produces composites that do not appear to differ from the highest level of enzyme-retting. Flax fibers improved the modulus of elasticity over wood pulp and HDPE alone and were less dense than glass or carbon fiber composites. Likely, differences in surface properties of the various flax fibers, while poorly defined and requiring further research, caused various interactions with the resin that influenced composite properties.     

作物秸秆资源的利用及其影响因素--以山西省夏县为例

作物秸秆资源的利用对提高食物安全,减轻环境污染,促进农业可持续发展具有重要意义.通过对农户的调查,分析了山西省夏县的秸秆利用途径,对该县秸秆利用现状进行了评价,并分析了造成这种现状的原因.结果表明,夏县作为典型的"小麦-玉米"二熟农作区,秸秆利用效率较高,其中小麦秸秆主要用于工业原料、饲料和还田,玉米秸秆则主要用于饲料和弃置堆放.这种利用方式与造纸业发展、传统的牲畜饲喂方式、农业机械化发展和气候特点有关.最后提出了进一步高效利用秸秆资源的建议.     

垃圾焚烧飞灰中重金属的固化/稳定化处理实验研究

研究了城市生活垃圾焚烧-电灰的特性及飞灰中重金属的特性,对利用水泥作粘结剂进行飞灰固化/稳定化处理效果开展了系统的实验研究,分析了水泥固化/稳定化飞灰的工艺特点和最佳工艺参数,并讨论了粘结剂固化飞灰机理以及重金属浸出毒性,为进一步研究城市生活垃圾焚烧飞灰的无害化处理与利用提供了有重要价值的参考依据.     

国产多核处理器芯片TDBI技术研究

随着集成电路的功能越来越复杂,超大规模集成电路的动态老炼越来越成为一项困难的工作。传统针对超大规模集成电路的老炼多采用静态老炼方法,这种方法不能使电路内部的功能节点动作起来,无法保证老炼效果,因此能够实现电路内部所有功能模块全动态激励的TDBI技术越来越受到人们的关注。本文以国产多核处理器芯片为测试对象,为研究多核处理器芯片的TDBI方法进行了芯片老炼测试软硬件系统开发,解决了多核处理器老炼中大功率电源供电、图形存储空间不足等关键技术。     

Selective collection as a pretreatment for indirect solid recovered fuel generation

Effective selective collection (SC) has been increasing in many countries of the European Union. As a consequence the composition of residual municipal solid waste (RMSW) is changing not only because of economic development, but also due to the collection system. The input of RMSW treatment plants is thus not homogeneous. This paper analyses two case studies involving a total of five SC scenarios and their impact on the generation of solid recovered fuel (SRF) with/without bio-drying, post-treatment and packaging take back programs (TBPs). These case studies are based on two types of SC: kerbside and drop-off. The latest regulation on SRF classification is taken into account: energy content, Cl and Hg concentrations are assessed and discussed. The role of the respirometric index (RI) is also analyzed. Results show that when SC is highly efficient RMSW can be classified directly as SRF, but only if the introduction of RI does not set stringent respirometric targets. The role of packaging TBPs is important as the residual waste remaining after the packaging has been processed, can be valorized increasing the lower heating value (LHV) of the residual RMSW and minimizing the streams that should be landfilled. The source separation of food waste has a significant impact on the suitability of bio-drying: when the SC of food waste is very efficient, its percentage in the RMSW may be too low for effective bio-drying.     

Pyrolysis technologies for municipal solid waste: A review

Pyrolysis has been examined as an attractive alternative to incineration for municipal solid waste (MSW) disposal that allows energy and resource recovery; however, it has seldom been applied independently with the output of pyrolysis products as end products. This review addresses the state-of-the-art of MSW pyrolysis in regards to its technologies and reactors, products and environmental impacts. In this review, first, the influence of important operating parameters such as final temperature, heating rate (HR) and residence time in the reaction zone on the pyrolysis behaviours and products is reviewed; then the pyrolysis technologies and reactors adopted in literatures and scale-up plants are evaluated. Third, the yields and main properties of the pyrolytic products from individual MSW components, refuse-derived fuel (RDF) made from MSW, and MSW are summarised. In the fourth section, in addition to emissions from pyrolysis processes, such as HCl, SO₂ and NH₃, contaminants in the products, including PCDD/F and heavy metals, are also reviewed, and available measures for improving the environmental impacts of pyrolysis are surveyed. It can be concluded that the single pyrolysis process is an effective waste-to-energy convertor but is not a guaranteed clean solution for MSW disposal. Based on this information, the prospects of applying pyrolysis technologies to dealing with MSW are evaluated and suggested.     

Co-pyrolysis of swine manure with agricultural plastic waste: Laboratory-scale study

Manure-derived biochar is the solid product resulting from pyrolysis of animal manures. It has considerable potential both to improve soil quality with high levels of nutrients and to reduce contaminants in water and soil. However, the combustible gas produced from manure pyrolysis generally does not provide enough energy to sustain the pyrolysis process. Supplementing this process may be achieved with spent agricultural plastic films; these feedstocks have large amounts of available energy. Plastic films are often used in soil fumigation. They are usually disposed in landfills, which is wasteful, expensive, and environmentally unsustainable. The objective of this work was to investigate both the energetics of co-pyrolyzing swine solids with spent plastic mulch films (SPM) and the characteristics of its gas, liquid, and solid byproducts. The heating value of the product gas from co-pyrolysis was found to be much higher than that of natural gas; furthermore, the gas had no detectable toxic fumigants. Energetically, sustaining pyrolysis of the swine solids through the energy of the product gas could be achieved by co-pyrolyzing dewatered swine solids (25% m/m) with just 10% SPM. If more than 10% SPM is used, the co-pyrolysis would generate surplus energy which could be used for power generation. Biochars produced from co-pyrolyzing SPM and swine solid were similar to swine solid alone based on the surface area and the ¹H NMR spectra. The results of this study demonstrated the potential of using pyrolysis technology to manage two prominent agricultural waste streams (SPM and swine solids) while producing value-added biochar and a power source that could be used for local farm operations.     

Pyrolysis of waste animal fats in a fixed-bed reactor: Production and characterization of bio-oil and bio-char

Several animal (lamb, poultry and swine) fatty wastes were pyrolyzed under nitrogen, in a laboratory scale fixed-bed reactor and the main products (liquid bio-oil, solid bio-char and syngas) were obtained. The purpose of this study is to produce and characterize bio-oil and bio-char obtained from pyrolysis of animal fatty wastes. The maximum production of bio-oil was achieved at a pyrolysis temperature of 500 °C and a heating rate of 5 °C/min. The chemical (GC–MS analyses) and spectroscopic analyses (FTIR analyses) of bio-oil showed that it is a complex mixture consisting of different classes of organic compounds, i.e., hydrocarbons (alkanes, alkenes, cyclic compounds…etc.), carboxylic acids, aldehydes, ketones, esters,…etc. According to fuel properties, produced bio-oils showed good properties, suitable for its use as an engine fuel or as a potential source for synthetic fuels and chemical feedstock. Obtained bio-chars had low carbon content and high ash content which make them unattractive for as renewable source energy.     

Nitrogen evolution during the co-combustion of hydrothermally treated municipal solid waste and coal in a bubbling fluidized bed

Nitrogen evolution was studied during the co-combustion of hydrothermally treated municipal solid wastes (HT MSW) and coal in a bubbling fluidized bed (BFB). HT MSW blending ratios as 10%, 20% and 30% (wt.%) were selected and tested at 700, 800, 900 °C. Emissions of NO and N₂O from blends were measured and compared with the results of mono-combustion trials. Moreover, concentrations of precursors like NH₃ and HCN were also quantified. The results are summarized as follows: NO emissions were predominant in all the cases, which rose with increasing temperature. The blending of HT MSW contributed to the NO reduction. N₂O emissions decreased with temperature rising and the blending of HT MSW also presented positive effects. At 30% HT MSW addition, both NO and N₂O emissions showed the lowest values (391.85 ppm and 55.33 ppm, respectively at 900 °C). For the precursors, more HCN was detected than NH₃ and both played important roles on the gas side nitrogen evolution.     

Alternative management structures for municipal waste collection services: The influence of economic and political factors

Identifying and characterising the factors that determine why a local authority opts for a particular way of managing its waste collection service is an important issue, warranting research interest in the field of municipal solid waste (MSW) management. This paper presents empirical evidence spanning a broad time horizon (2002–2010) showing that economic and political factors impact in different ways on the provision of waste management services. We examine five alternatives in this area, including public and private service delivery formulas and, within each field, individual and joint options. Our findings highlight the importance of the service cost and that of the various indicators of fiscal stress as determinant factors of management decisions regarding the provision of MSW management services.