压实坡积土的应力应变关系三维曲面初步研究

对两组不同含水量的压实坡积土样进行三轴CD试验,利用试验得到的ε1～q曲线以及体应变εv、剪应变εr、平均正应力p和广义剪应力q等数据,通过神经网络反演,并采用可视化处理技术,得到试样的部分应力应变关系三维曲面,为三维数值建模研究创造条件。     

Estimating net primary production and annual plant carbon inputs, and modelling future changes in soil carbon stocks in arable farmlands of northern Japan

Soil C sequestration in croplands is deemed to be one of the most promising greenhouse gas mitigation options for Japan's agriculture. In this context, changes in soil C stocks in northern Japan's arable farming area over the period of 1971-2010, specifically in the region's typical Andosol (volcanic ash-derived) and non-Andosol soils, were simulated using soil-type-specific versions of the Rothamsted carbon model (RothC). The models were then used to predict the effects, over the period of 2011-2050, of three potential management scenarios: (i) baseline: maintenance of present crop residue returns and green manure crops, as well as composted cattle manure C inputs (24-34 Mg ha⁻¹ yr⁻¹ applied on 3-55% of arable land according to crop), (ii) cattle manure: all arable fields receive 20 Mg ha⁻¹ yr⁻¹ of composted cattle manure, increased C inputs from crop residues and present C inputs from green manure are assumed, and (iii) minimum input: all above-ground crop residues removed, no green manure crop, no cattle manure applied. Above- and below-ground residue biomass C inputs contributed by 8 major crops, and oats employed as a green manure crop, were drawn from yield statistics recorded at the township level and crop-specific allometric relationships (e.g. ratio of above-ground residue biomass to harvested biomass on a dry weight basis). Estimated crop net primary production (NPP) ranged from 1.60 Mg C ha⁻¹ yr⁻¹ for adzuki bean to 8.75 Mg C ha⁻¹ yr⁻¹ for silage corn. For the whole region (143 × 10³ ha), overall NPP was estimated at 952 ± 60 Gg C yr⁻¹ (6.66 ± 0.42 Mg C ha⁻¹ yr⁻¹). Plant C inputs to the soil also varied widely amongst the crops, ranging from 0.50 Mg C ha⁻¹ yr⁻¹ for potato to 3.26 Mg C ha⁻¹ yr⁻¹ for winter wheat. Annual plant C inputs to the soil were estimated at 360 ± 45 Gg C yr⁻¹ (2.52 ± 0.32 Mg C ha⁻¹ yr⁻¹), representing 38% of the cropland NPP. The RothC simulations suggest that the region's soil C stock (0-30 cm horizon), across all soils, has decreased from 13.96 Tg C (107.5 Mg C ha⁻¹ yr⁻¹) in 1970 to 12.46 Tg C (96.0 Mg C ha⁻¹ yr⁻¹) in 2010. For the baseline, cattle manure and minimum input scenarios, soil C stocks of 12.13, 13.27 and 9.82 Tg C, respectively, were projected for 2050. Over the period of 2011-2050, compared to the baseline scenario, soil C was sequestered (+0.219 Mg C ha⁻¹ yr⁻¹) by enhanced cattle manure application, but was lost (−0.445 Mg C ha⁻¹ yr⁻¹) under the minimum input scenario. The effect of variations of input data (monthly mean temperature, monthly precipitation, plant C inputs and cattle manure C inputs) on the uncertainty of model outputs for each scenario was assessed using a Monte Carlo approach. Taking into account the uncertainty (standard deviation as % of the mean) for the model's outputs for 2050 (5.1-6.1%), it is clear that the minimum input scenario would lead to a rapid decrease in soil C stocks for arable farmlands in northern Japan.     

咪唑类离子液体系列对卤虫的急性毒性研究

选取卤虫作为实验生物,研究了1-丁基,1-辛基,1-十二烷基-3甲基咪唑盐酸盐( [Cnmim][Cl](n = 4,8,12) ) 3种离子液体的暴露对卤虫个体存活率的影响.同时,选取了实验室常用的有机试剂甲醇和乙腈,无机化学品重铬酸钾作为阳性对照.根据剂量效应曲线的拟合结果发现,受试离子液体系列随着咪唑环上烃基侧链碳原子数的增加,对卤虫的毒性效应也相应增强,3种离子液体对卤虫的LC50-24h依次为171.1,133.6,17.76μg/mL.离子液体对卤虫的LC50-24h比甲醇(LC50-24h=84.83mg/mL)和乙腈(LC50-24h=52.84mg/mL)低了2~3个数量级,重铬酸钾对卤虫的(LC50-24h=16.87μg/mL)与离子液体对卤虫的LC50-24h处于同一水平.     

滨河湿地地下水水位变化及其与河水响应关系研究

滨河湿地的发育与退化过程受河流水文过程的显著影响.以黄河湿地国家自然保护区盂津湿地为研究对象,通过滨河湿地地下水位变化(特刖是小浪底水库调水调沙期间)野外定位观测,深入分析了滨河湿地地下水水位与洪水的响应关系.结果表明,滨河湿地地下水位受河水水位影响显著,地下水位的波动幅度与河岸距离之间存在明显的负指数关系,调水期内这...     

秦巴山区生态系统服务与居民福祉耦合关系的时空变化

保护生态系统、提高居民福祉是实现联合国2030可持续发展目标的核心内容。在分析秦巴山区生态系统服务与居民福祉时空演化特征的基础上,采用弹性系数揭示了二者的时空耦合关系。研究发现：（1）1990—2018年秦巴山区水源涵养总量、土壤保持总量均呈波动下降趋势,碳储量总量则呈缓慢增长趋势,且各生态系统服务呈不同的空间分异特征。（2）1990—2018年居民福祉呈上升趋势,增幅高达220%,并呈“南高北低”的分布格局。（3）县域尺度上,三种生态系统服务与居民福祉明显不协调发展。其中,水源涵养、固碳服务与居民福祉的耦合关系均以“福祉增—服务减”为主,占比分别为88.75%、62.5%;而土壤保持服务与居民福祉的耦合关系则以“双增”为主,占比为57.5%。此外,各项生态系统服务与居民福祉反向变化区多分布于汉江河谷盆地和秦岭山脉中段。研究结果可为促进贫困山区生态系统服务与居民福祉协调发展提供决策依据。     

陕西省城市化与生态环境系统耦合关系

采用层次分析法(AHP)和系统科学的理论构建了城市化与生态环境系统的评价指标体系和耦合模型,并将这个耦合系统的演化周期分为低级共生、协调发展等4个阶段,根据耦合度为45°时,耦合效果最佳的理论又可将协调发展阶段分为相对协调、最佳协调、低度协调3个状态.1990-2008年陕西省的城市化综合指数呈现直线上升的趋势,生态环...     

定量构效关系模型在化合物毒性预测领域的应用、发展与展望

定量构效关系（Quantitative Structure Activity Relationship, QSAR）在化合物毒性虚拟计算领域被广为使用,能够高效、准确地用于化合物毒性的预测和风险评估.本文综述了利用QSAR方法开展化合物毒性预测中数据集、数据输入和模型方法3个领域的发展与变化,分析了研究的发展历程,提出了当前研究热点,并针对定量构效关系在化合物毒性预测领域的未来发展提出了展望.     

Transformational leadership,relationship quality,and employee performance during continuous incremental organizational change

Although transformational leadership has been investigated in connection with change at higher levels of organizations, less is known about its “in‐the‐trenches” impact. We examined relations among transformational leadership, explicit change reactions (i.e., relationship quality), change frequency, and change consequences (i.e., task performance and organizational citizenship behavior (OCB)) during continuous incremental organizational change at lower hierarchical levels. In a sample of 251 employees and their 78 managers, analyses revealed that the quality of relationships between leaders and employees mediated the influence of transformational leadership on employee task performance and OCB. We also found that change frequency moderated the positive association of relationship quality with task performance and OCB, such that associations were stronger when change frequency was high. Copyright © 2012 John Wiley & Sons, Ltd.     

An Empirical Investigation of the Influence of Safety Climate on Organizational Citizenship Behavior in Taiwan’s Facilities

Although the social exchange relationships between employers and employees are increasingly important to the performance of safety management systems, the psychological effects of work attitudes on this relationship have been less studied. Using a sample of first-line operators and their supervisors from 188 facilities in Taiwan which had Occupational Health and Safety Assessment Series 18000 (OHSAS 18000) certification, the current research conducted an empirical investigation of the influence of safety climate on organizational citizenship behavior (OCB). Work attitude was used to disclose the psychological effect. Research results indicated that (a) safety climate was a significant predicator of OCB, (b) the psychological effect significantly influenced social exchange relationships, and (c) job satisfaction showed a stronger mediating influence than organizational commitment due to the frequent top management turnover. Discussions and implications are also addressed.