Determination of organochlorine and organophosphate pesticide residues in fruits,vegetables and sediments

Abstract

A method is described for the determination of organochlorine and organophosphate pesticide residues in fruits, vegetables and sediments. The concentrated solvent extract was sealed in a polymeric membrane tube, dialysed in cyclohexane and the solvent replaced with hexane. The organophosphates were analysed on a specific thermionic detector without further clean‐up. For the organochlorine pesticides the extract was eluted through 3 g of alumina and analysed on GC/ECD. The clean‐up for sediment extract was carried out on a10 g alumina column with 100 mL hexane containing 5% acetone and the eluate was concentrated to 5 mL.

The detection limit for organophosphates on a 40 g sample and a final volume of 10 mL was on the average 0.01 mg/kg. The detection limit for organochlorine pesticides, with the final volume of 25 mL, was 0.005 mg/kg for all pesticides except for p,p'‐DDT and endosulfan sulphate, which was 0.01 mg/kg.

The detection limit for oganochlorine pesticides in sediment, with the final volume of 2 mL, was less than 1 μg/kg and for organophosphate pesticides less than 10 μg/kg when the final volume was made to 0.5 mL. At the detection limits the method produced a very high coefficient of variation for both organochlorine and organophosphate pesticides.     

Genotoxicity of chromium in vitro on yeast: Interaction with DNA†

The genotoxicity of chromium chloride was investigated in cells of D₇ strain of Saccharomyces cerevisiae harvested either from logarithmic or stationary growth phase.

A weak induction of mifotic gene conversion and point reverse mutation was obtained when the incubations were performed using phosphate buffer. No genetic effect was observed when the incubations were performed using Tris‐HCl buffer.

The experiments with ⁵¹Cr radiotracer demonstrated that Cr³⁺ ion enters the yeast cells and binds to DNA even if the incubation mixture was performed with Tris HCl buffer. This behaviour could be due to the highest concentration of CrCl₃ that cause some damages to cytoplasmatic membrane.     

膜生物反应器废水处理新工艺

概述了国内外膜生物反应器的研究与应用状况；介绍了其构形与特点；分析了膜污染的成因，影响因素及防制措施；指出了今后的研究方向。     

超滤技术在废水处理中的应用

文章对超滤原理、超滤膜种类、国内外超滤技术发展现状等做了较详尽的阐述,同时着重介绍了超滤技术在油田含油废水、石化含油废水、金属加工用乳化废液、纤维加工油剂废水及羊毛精制废水中回收羊毛脂的应用实例。     

天津市城区暴雨沥涝仿真模拟系统的研究

天津市位于黄河水系尾闾，是我国北方重要的工业和港口城市。该市历史上一直遭受洪涝灾害的威胁，加之近几年市区范围不断扩大，不透水面积增加，排水能力远远不能适应城市的发展要求，城市沥涝问题日趋严重。为了掌握天津市暴雨沥涝的规律，减轻洪涝灾害对该市的影响，作者利用二维不恒定流水动力学模型和计算机信息管理及图形技术，采用Power Station Fortran 4.0和Visual Basic5.0编程语言，在Widows98环境下开发了天津市暴雨沥涝仿真模拟系统。该系统首次实现了从城市暴雨预报、监测到城市暴雨沥涝仿真模拟的研究， 不仅能够处理实时的不均匀的降雨信息，还能处理数值预报模型的预报降雨信息。系统的信息前后处理模块用图形方式管理仿真模型的各类信息，方便用户显示、查询和修改，使系统更加完整、实用。     

Recovery of gold by chicken egg shell membrane-conjugated chitosan beads

We have successfully prepared a bead-type adsorbent from two materials with different adsorption characteristics. Heavy metals were removed by greatly swollen egg shell membrane-conjugated chitosan beads. The egg shell membrane accumulated and removed precious metal ions from a dilute aqueous solution with a high affinity in a short contact time. Experiments suggested that chitosan beads could take up gold ions with great capacity and selectivity by conjugation with egg shell membrane. Under certain conditions, the selective removal of gold and copper in a mixture of gold and copper ions by egg shell membrane-conjugated chitosan beads was 100% and 2%, respectively. Egg shell membrane-conjugated chitosan beads can be seen as a promising material to recover gold in wastewater from various industries, such as electroplating.     

表面过滤技术在焚烧厂烟气脱酸净化中的作用

随着城市垃圾焚烧工程的发展，国家对焚烧后尾气的处理技术提出了越来越高的要求。基于“表面过滤”理论的Gore过滤技术，不但为粉尘排放达到欧洲标准提供了技术保障，而且为脱酸／硫的后续反应提供了反应界面，在实际应用中可以有效节约反应剂。     

旋转风幕流场的数值模拟及实验研究

基于流体力学中空气射流理论,建立气幕旋风排风罩流场的三维数学模型。影响气幕旋风排风罩效果的因素很多,主要包括:射流气动参数、吹吸气动参数以及流动空间的边界条件和装置结构等。针对不同送风速度、不同送风角度下两种情况进行分析,并利用FLUENT计算动力学软件对这两种情况下气幕旋风排风罩的流场进行了数值模拟,经过比较确定出最佳效果时的参数,并利用示综烟雾进行了实验。结果表明:所建立的气幕旋风排风罩流场的数学模型完全正确,所确定的最佳效果时的参数和实际情况基本一致,可用于工程实际。     

BOD微生物膜的再利用研究初探

对失去大部分活性的微生物膜进行再培养，以研究膜再利用的可能性。试验结果初部表明：在1／2MS培养基中加入一定量的植物激素，不仅可以使膜的电位值（I0）显著升高，且活性强，稳定性好，可使膜重复利用。