芳香烃在简单盐水溶液中ks值的计算

运用分子拓扑理论探讨了芳香烃在简单盐水溶液中盐效应常数ks与芳香烃和盐结构之间的定量关系,提出了新的拓扑指数,给出了新的计算方法,也计算了盐效应常数ks 的各种理论值,并与实验值进行了比较,证实了新方法的计算值最接近实际.     

The formation and maintenance of crayfish hierarchies: behavioral and self-structuring properties

Behavioral changes in fighting and the development of dominance relationships were analyzed in groups of juvenile crayfish (Astacus astacus) using quantitative behavioral techniques. When individuals were placed into an aquarium, the number of agonistic challenges, their mean duration, and maximum intensity reached were high initially but then decreased steadily as the hierarchy developed. In all groups, linear hierarchies emerged which became increasingly stable over time. Winning influenced subsequent fighting behavior on two distinct time scales. In the short term, recent winners became progressively less likely to retreat. Second, individuals occupying dominant positions for days became increasingly likely to escalate to higher intensities early in the encounter. Both effects biased the outcome of future interactions such that winning enhanced further success and losing decreased an individual’s subsequent chances for dominance. Received: 11 November 1999 / Revised: 1 March 2000 / Accepted: 3 May 2000     

美国的环保政策及对环保产业发展的影响

美国的环保政策是一种经济发展政策 ,强调在提高美国工业竞争力和维护社会经济繁荣的基础上加强环境保护 ,强调通过环保技术的开发和应用实现具体的环保目标 ;措施上它强调灵活性、创新性、多样性和公众的自觉参与 ,创造了环保产业宽松和不断创新的环境。     

城市屋面绿化生态热效应

文章在享有“火炉”这称的山城重庆夏末季节对草坪层面与水泥屋面的热特性进行了对比实测分析,研究结果表明草坪屋面具有显著的生态热效应。     

兰州市空气污染对儿童及其父母呼吸系统健康的影响

叙述了居住环境对儿童和儿童父母亲呼吸系统健康影响的研究结果。揭示了儿童对空气污染所引起的呼吸系统疾病的急性反应较成人更敏感。吸烟合并空气污染更能损害人的健康     

基于WRF模式的云南省干旱发生风险的预测分析

云南省作为西部大开发的典型省份之一,有着独特的自然环境和资源禀赋,但同时全省地形复杂多变且处于气候带的脆弱区,气候变率相当大.本研究在分析云南省近30年的土地利用/土地覆被变化的前提下,采用中尺度天气研究与预报Weather Researchand Forecasting (WRF)模式系统,对云南省未来40年干旱发生风险进行了预测分析.研究首先对WRF模式系统适用性进行了验证,重点分析了气温和降水两个主要干旱影响因子的未来时空变异特征.然后根据WRF模式系统的输出结果,选取了系列气象干旱指标因子,并采用综合气象干旱指数计算方法在空间和时间上对干旱发生风险进行了预测.从研究结果来看,加强对现用森林资源的保护,执行长期有效的生态工程建设,可以很大程度上减缓未来干旱发生频率.同时云南省当前“城市上山”等政策实施中也应考虑到建设用地扩张的不可逆转性,避免城市盲目上山.研究指出,未来区域发展规划应该对人为土地利用进行长期且合理有效部署,减少政策的不确定性,合理的区域发展规划是应对干旱风险的有效举措.     

关于可持续发展本质和实效的思考——兼论有中国特色的可持续发展模式

本文认为可持续发展基本上是一种发展理念、一种哲学思想 ,而不是一种统一的、具体的发展模式 ,在分析了可持续发展的本质和实效以后 ,指出 :对中国来说 ,可持续发展意味着把政府提出的各项政策、战略贯彻好 ,把这种思想贯彻到方方面面的工作中去     

无锡市城镇化进程中土地利用变化及其环境效应

20世纪90年代,城市用地扩展是我国区域土地利用演化的主导过程,城市土地利用所引起的地表景观格局的变化又是引起地表各种地理过程变化的主要原因。基于Landsat TM图像解译的土地利用的动态图斑,分析了20年代90年代无锡市土地利用的变化态势。研究表明,土地利用变化主要体现为耕地向林地、水域、建设用地的转移．林地向耕地、建设用地的转移,以及草地、水域向建设用地的转移;20世纪90年代中后期,国家颁布的一系列基本农田保护和“退耕还林还草”的政策法规,在一定程度上限制了大量耕地被建设占用的趋势。土地利用快速变化也导致明显环境效应．主要表现为水环境的恶化和现代“城市病”等方面。因此,加强土地规划管理、合理利用土地资源、重视能源开发与基础设施建设,应成为今后区域土地资源开发、利用与保护的重点与方向。     

Degradation of MTBE and TBA by a new isolate from MTBE-contaminated soil

Methyl ten-butyl ether （MTBE）, a gasoline additive, possesses serious problems to the environmental health. In the present study, a bacterial culture named A-3 which could effectively degrade MTBE was isolated from the MTBE contaminated soil. The isolate was identified as Chryseobacterium sp., a new species capable of degrading MTBE. In order to enhance its degradation ability, selected environment factors were investigated. The results showed that the optimal temperature was in the range of 25-30℃, the pH was 7.0, the inoculum size was 2 × 10^8 CFU/ml and the optimal concentration of MTBE was from 50 to 100 mg/L. The maximum MTBE utilization rate （Vmax） was 102 nmol MTBE/（mg cell protein.h）. Furthermore, it was found that the isolate could also degrade tert-butyl alcohol （TBA）. The degradation rates of TBA were much faster than those of MTBE. The additional TBA would lead to the decrease of the initial MTBE degradation rate and the inhibitory effect of TBA increased with the increase of TBA concentration. Similar protein profiles at least seven peptides were demonstrated after SDS-PAGE analysis of crude extracts obtained from the cells growing in MTBE and TBA culture.     

Effect of copper on the degradation of pesticides cypermethrin and cyhalothrin

The influence of coexisting copper (Cu) ion on the degradation of pesticides pyrethroid cypermethrin and cyhalothrin in soil and photodegradation in water system were studied.Serial concentrations of the pesticides with the addition of copper ion were spiked in the soil and incubated for a regular period of time,the analysis of the extracts from the soil was carried out using gas chromatography (GC).The photodegradation of pyrethroids in water system was conducted under UV irradiation.The effect of Cu~(2 ) on the pesticides degradation was measured with half life (t_(0.5)) of degradation.It was found that a negative correlation between the degradation of the pyrethroid pesticides in soil and Cu addition was observed.But Cu~(2 ) could accelerate photodegradation of the pyrethroids in water.The t_(0.5) for cyhalothrin extended from 6.7 to 6.8 d while for cypermethrin extended from 8.1 to 10.9 d with the presence of copper ion in soil.As for photodegradation,t_(0.5) for cyhalothrin reduced from 173.3 to 115.5 rain and for cypermethrin from 115.5 to 99.0 min.The results suggested that copper influenced the degradation of the pesticides in soil by affecting the activity of microorganisms.However, it had catalyst tendency for photodegradation in water system.The difference for the degradation efficiency of pyrethroid isomers in soil was also observed.Copper could obviously accelerate the degradation of some special isomers.