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751.
752.
本文建立了准确预测多环芳烃(PAHs)及其烷基衍生物的正-辛醇/水分配系数(Kow)模型。模型表明PAHs的分配性质可用零阶价分子连接性指数(~°x~v)描述,~°x~v数值与PAHs的logKow成正比。应用本模型可以预测大范围PAHs的logKow值。 相似文献
754.
讨论了城市污水经过A/O工艺处理时活性污泥的二次污染问题。将原水、处理后的出水及活性污泥用甲苯萃取,萃取相经过真空浓缩后,采用GC/MS测定了样品中的有机化合物,结果表明,在A/O工艺处理城市污水过程中,活性污泥的吸附作用是主要的,降解作用是次要的;A/O工艺所排放的活性污泥仍然是一种危险的污染物。 相似文献
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756.
R. Lorenzo R. Kaegi R. Gehrig B. Grobty 《Atmospheric environment (Oxford, England : 1994)》2006,40(40):7831-7841
The goal of this study was to identify and quantify particles emitted from railway traffic. For that purpose PM10 samples were collected near a busy railway line using a wind direction and speed controlled sampling equipment consisting of five devices. Measurements taken perpendicular to the railway lines at 10, 36 and 120 m distance enable an identification and separation of particles caused by the railway traffic from background particles. Morphology and chemistry of more than 11,000 particles were analysed by computer controlled scanning electron microscopy (CCSEM). Based on chemical composition five particle classes are defined and assigned to their sources. The mass of the individual particles is determined by multiplying their volumes, calculated based on their morphology with a density assigned specifically to each particle class. The density of the particle classes is derived from their chemical composition. To estimate the PM10 contributions of the railway lines, the mass of PM10 at 120 m (background, not influenced by the railway lines) is subtracted from the mass of PM10 at 10 m. The emissions of the railway lines are dominated by ‘iron’ particles, which contribute 2.9 μg m−3 or 67% to the railway related PM10. In addition, ‘aluminium’ and ‘calcium’ particles contribute also to the railway related PM10 (1.0 μg m−3 or 23% for the ‘aluminium’ and 0.4 μg m−3 or 10% for the ‘calcium’ particles). These particles are assigned to abrasion of the gravel bed and re-suspension of mineral dust.Long-term gravimetric results of the contribution of iron to the mass of railway related PM10 from a study performed earlier at the same site are in good agreement with the data presented in this study. 相似文献
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In FRG and other countries unequivocal criteria for the limitation of dioxins (PCDD's/PCDF's) in food like vegetables and fruits are lacking. These have to be directly associated with the limitation of dioxins in the soil and the deposition of particulate matter as the two main pathways for plant contamination. Based on recent investigations in the vicinity of cable-waste incinerators in Northrhine-Westphalia with comparatively high contents of dioxins in garden plants and soils and other sources of dioxins, considerations are given for the establishment of the criteria urgently needed. 相似文献
759.
G.F. Vanness T.O. Tiernan M.S. Hanes C.J. Reynolds J.H. Garrett D.J. Wagel J.G. Solch 《Chemosphere》1990,20(10-12)
An analytical procedure has been developed for quantitatively measuring dibenzo-p-dioxin (DBD) and dibenzofuran (DBF) present at part-per-billion levels in paper mill defoamers and paper pulp using gas chromatography coupled with either low resolution mass spectrometry (GC-LRMS) or high resolution mass spectrometry (GC-HRMS). 相似文献
760.