国内外造纸行业水污染排放标准比较研究

中国是造纸大国,制浆造纸在中国属于重污染行业。2008年国家发布的《制浆造纸工业水污染物排放标准》对整个行业可能排放的污染物提出了要求。本文通过将该标准与国外造纸行业相关的水污染物排放标准进行比较研究,找出我国标准与国外的差别,并为完善我国造纸行业水污染物排放标准提出建议。     

Advanced Oxidation Processes in the Treatment of Trifluraline Effluent

The treatment of an effluent from the production of trifluraline was studied using a 1-L, semi-batch, tank-stirred glass reactor for performing three different advanced oxidation processes (photoperoxidation, Fenton, photo-Fenton). A commercial, medium-pressure mercury lamp was used for sample irradiation. The degradation was monitored by measurements of absorptiometric color reduction, UV-visible absorption spectra, and chemical oxygen demand (COD). The obtained results showed that the photo-Fenton process was the most effective treatment for the trifluraline effluent.     

Nature of the field-to-field distribution of pesticide residues

The supervised trial datasets (1950), consisting of a minimum of five residue values and selected by the experts of FAO/WHO Joint Meeting on Pesticide Residues for recommending maximum residue levels between 1997 and 2011, were evaluated to obtain information on the typical spread of residue values in individual datasets. The typical relative standard deviation, CV, of field-to-field variation of pesticide residues was about 80%. The spread of residues in datasets is independent from the chemical structure of pesticides, residue level, pre-harvest interval and number of values in the datasets. The CV ranges within the Codex commodity groups and between groups overlapped and their difference were not statistically significant. The number of residues below the limit of quantification (LOQ) affects the CV at various extents depending on the ratio of LOQ/R _mean. The combined uncertainty of the highest residue in a dataset significantly affects the CV of the dataset. The lowest and intermediate ones have less influence. The residues in different fields receiving the same treatment vary within large range: 55%, 72%, 78%, 86% and 89% of the 25,766 residues values were, respectively, within 3, 4, 5, 6 and 7 times the median value of the corresponding dataset.     

水化深度处理渗滤液尾水中的有机物

利用水泥的水化过程易受有机物影响的特点,采用硅酸盐水泥深度处理了垃圾渗滤液膜生物反应器(MBR)工艺出水,考察了不同因素,如投加量、初始pH、反应时间及振荡速率等对于渗滤液尾水中有机物的去除效果以及最佳工艺条件,并分析了渗滤液尾水中有机物的去除机理。结果表明,水化过程对渗滤液尾水中的有机物去除性能良好,且对不同有机物具有一定的选择性,尤其对具有近紫外区(200～400 nm)吸收峰特征的有机物去除效果更佳,同时发现,当投加量为50 g/L、pH=8.3(原渗滤液pH)、反应时间为24 h和振荡速度为200 r/min时,去除效果最佳,其COD、TOC和UV254的平均去除率分别达到55.6%、62.1%和68.8%。     

混凝对二级出水中有机物分布特性的影响

以城市污水处理厂二级出水为研究对象,通过烧杯实验,确定了以三氯化铁(FeCl3)和聚合氯化铝(PAC)为混凝剂时两种混凝剂的最佳投加量,在此基础上采用XAD树脂分离技术和超滤膜法对水中溶解性有机物(DOM)进行分级表征,研究了混凝前后水中DOM的亲疏水特性、分子量分布规律以及比紫外吸收值(SUVA)和E4/E6(A465nm/A665nm)的变化.结果表明,当FeCl3和PAC投加量分别达到30 mg/L和60 mg/L时,可以使出水水质满足《城镇污水处理厂污染物排放标准》(GB18918-2002)中的一级A标准;FeCl3对含碳碳不饱和双键及芳香环的有机物的去除效果优于PAC;FeCl3对小分子有机物的去除效率更高,而PAC对分子量＞100 000的大分子有机物的去除效果优于FeC13;混凝处理对疏水性有机物的去除效果优于对亲水性有机物的去除效果,同时其对酸性物质的去除效率高于对非酸性物质的去除效率.     

关于CCUS技术发展与标准建设的思考

我国CCUS技术发展,迫切需要政策制度的积极引导和技术标准的强力支撑。阐述了我国发展CCUS技术的基本原则和相关政策;跟踪了国内外CCUS技术发展动态及其标准研究现状;重点分析了美国及欧盟在CCS相关政策、法规和标准方面的主要成果;依据我国CCUS发展规划和技术发展路线图,提出了我国CCUS技术发展与标准建设的相关建议。     

周期性浸泡腐蚀试验标准及相关设备分析

基于产品运输、使用环境的复杂性,单一环境因素模拟已不能满足产品测试需求。溶液浸泡腐蚀试验是一种常见的环境试验,目前,其试验形式除单一的溶液浸泡外,周期性浸泡腐蚀试验也逐步开展。对此,GB、TB、ISO、PSA、ASTM等相关标准给出了规定要求和试验方法,在此基础上为满足其要求相应的试验装置也逐步开始开发和应用。基于不同标准和现有试验设备对周期性浸泡腐蚀试验进行分析讨论,得出各个标准的不同适用范围和试验条件,并针对其原理共性提出开发通用性设备的展望,为浸泡腐蚀试验标准的选取及试验装置的开发提供参考意见。     

轨道交通电连接器国内环境试验标准分析

铁路作为国民经济大动脉、国家重要基础设施和大众化交通工具,在国民经济和社会生活中的作用至关重要。电连接器是铁路车辆设备的关键器件之一,有着很高的安全性和可靠性要求。着重分析了轨道交通电连接器标准中的电性能、机械性能和环境适应性的试验方法,并对这些标准进行了对比总结。经分析发现,更新版本的标准比被替换的标准增加了试验项目,细化了试验条件。然而,目前国内轨道交通电连接器的标准版本相对落后,仅GB/T 25022和GB/T 25023为2010年发布实施。亟需新的标准或试验方法以指导轨道交通电连接器的质量检测和认证。     

Removal of two cationic dyes from a textile effluent by filtration-adsorption on wood sawdust

BACKGROUND: Wastewater from textile industry contains various contaminants such as dyes, surfactants and heavy metals. Textile dyes have synthetic origin and complex aromatic molecular structures that make them difficult to biodegrade when discharged in the ecosystem. The objective of this study was to examine the decolourisation of textile effluents containing cationic dyes by filtration-adsorption on wood sawdust from two different origins; fir as an example of a conifer tree, and beech as an example of a deciduous one, and to explain the adsorption mechanism. METHODS: The process of dye removal was applied to a synthetic effluent in batch mode. Adsorption experiments were performed by suspending sawdust in the effluent and analyzing the supernatant by spectrophotometry. The effectiveness of the treatment process was evaluated by measuring coloration. RESULTS AND DISCUSSION: Experimental results showed a significant potential for wood sawdust, especially coniferous sawdust, to remove cationic dyes from textile effluents. Adsorption kinetics was influenced by the initial dye concentration, nature and amount of sorbent as well as sorbent particle size. The adsorption followed a pseudo first-order kinetics. For both basic dyes, the Langmuir adsorption equation showed a better fit than the Freundlich equation. CONCLUSION: Filtration-adsorption using an inexpensive and readily available biosorbent provided an attractive alternative treatment for dye removal, and it does not generate any secondary pollution. Recommendations and Perspectives. Laboratory studies provide promising perspectives for the utilization of wood sawdust as renewable adsorbent for reducing pollution while enhancing the reuse of textile effluents. However, the treatment process needs to be applied to the other textile dye classes in order to be used on an industrial scale.     

我国非煤矿山标准现状与分析

对1975—2007年间发布的775项非煤矿山标准的统计分析表明,我国非煤矿山标准的制修订、批准发布属于不同的标准化技术委员会和不同的部门;非煤矿山标准属于有色金属、黑色冶金、建筑材料、核工业、化工、轻工、石油、天然气、机械、汽车等行业领域。在775项标准中,推荐性标准有611项,占78.8%,推荐性标准比例高于强制性标准比例;2007—2002年、2001—1997年、1996—1992年、1991—1987年、1986—1982年、1981—1975年间发布的标准分别为218项、190项、270项、76项、12项、9项,发布时间在5年以上的标准占71.9%,平均发布时间为9.6年,我国非煤矿山标准老化、修订周期长问题比较突出,因此,应加强非煤矿山标准的制修订工作。