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排序方式: 共有863条查询结果,搜索用时 31 毫秒
811.
812.
Kebede Nigussie Mekonnen Abayneh Ataro Ambushe Mesfin Redi Abshiro Robert Ian McCrindle 《毒物与环境化学》2013,95(10):1980-1994
A total of thirty three water samples were collected from Tinishu Akaki River, Lake Awassa, and Lake Ziway, Ethiopia. Multi-element determination of trace elements (V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, Ag, Cd, Sn, Hg, and Pb) in water samples was carried out by inductively coupled plasma-mass spectrometry after acidification with 1% HNO3. The concentration (in µg?L?1) of the elements were in the range of 1.0–19, <0.42–83, 1.1–1580, <45–1760, <0.11–2.0, 0.43–13, 0.77–13, 6–300, <0.94–2.0, <0.3–1.5, <0.012–0.63, 0.13–4.8, <0.29, and 0.2–7.2 for V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, Ag, Cd, Sn, Hg, and Pb, respectively. The concentrations of all the quantified elements, with the exception of Mn, were in the range of the permissible limits of the Ethiopian, European Community, and World Health Organization for both drinking water quality guidelines and irrigation water guidelines. The accuracy of the method was validated by analyzing trace elements in water standard reference material (SRM 1643e). The measured values of trace elements in the SRM agreed well with the certified values at the 95% confidence level. 相似文献
813.
In this study, the concentrations of Co, Ni, Fe, Cu, Mn, Pb, Cr, and Cd were determined in 15 cigarette brands from Turkey by flame atomic absorption spectrometry (FAAS). A wet digestion method was employed to cigarette samples. The mean values obtained for Co, Ni, Fe, Cu, Mn, Pb, Cr, and Cd were 1.2, 4.1, 134, 14, 66, 3.7, 5.0, and 1.1?µg?g?1, respectively, i.e., in the order of Fe?>?Mn?>?Cu?>?Cr?>?Ni?>?Pb?>?Co?>?Cd. The results were compared with the literature values for other international cigarette brands. 相似文献
814.
The concentration levels of major (Al, Ca, Fe, K, Mg, Mn, Na, Si, Ti) and some trace (Be, Se, Tl) elements were determined by atomic absorption spectrometry for the coal fly ashes emitted in the combustion of anthracite and soft coals. Total contents and concentration profiles were established for all elements studied as a function of the mean particle size. The content of those elements volatilized during coal combustion (Se, Tl) decreases with increasing particle size, while the unvolatilized elements show small changes in their concentration profiles. The content of aluminium shows a minimum level at a mean particle size of about 25 μm. 相似文献
815.
Four crop plants were grown in a greenhouse in soils amended with 0, 5, 10, and 20% by weight of coal combustion fly ash to evaluate potential trace element uptake by the vegetation. The leaves and stems from each plant were harvested and analyzed for As, Cd, Co, Cu, Mn, Mo, Pb, Se, Tl, and Zn content during early, middle, and late growth. The trace element data were statistically analyzed using Analysis of Variance (ANOVA) to determine whether the trace element uptake in the four crop plants differed significantly between the soil treatments, and to identify significant differences in trace element uptake through time. The results show that the amount of amended fly ash does not significantly influence the concentration of most trace elements in plant tissue, and that some concentrations actually decrease with time. Although this study did not find a significant increase in trace element uptake, care must be taken in a natural environment where plants may behave differently. 相似文献
816.
This study was designed to determine the protective effects of zinc (Zn) using liver marker enzymes in the serum and liver along with hepatic elemental profile in lead (Pb)-treated protein-deficient (PD) Sprague–Dawley male rats. Zn in the form of zinc sulfate at a dose of 227?mg?L?1 in drinking water was administrated to control, PD as well as Pb-treated PD rats for 8 weeks. Pb treatment was given orally as lead acetate at a dose level of 100?mg?kg?1 body weight to control and PD rats. The effects of different treatments were studied on the activities of enzymes that included alkaline phosphatase (ALP), aspartate aminotransferase (AST) and alanine aminotransferase (ALT) in serum. The status of different elements (Cl, K, Mn, Fe, Cu, Zn, Se, Rb, Pb) in liver was also studied. Rats given PD diet and Pb showed significant inhibition in serum ALP activity associated with significant elevation in both AST and ALT activities. Serum ALP activity showed a significant inhibition week 1 until week 8 in Pb-treated PD rats. In contrast, serum AST activity was elevated both at 3 and 8 weeks while serum ALT activity was elevated at 8 weeks in Pb-treated PD rats. Pb treatment to PD rats elevated hepatic ALP, AST and ALT activities but depressed hepatic AST. Zn supplementation to Pb-treated PD rats restored the altered enzyme activities. The levels of K, Fe, Cu, Zn, Se and Rb were altered in protein deficiency. Furthermore, treatment with Pb to these animals depressed the Cu levels. Zn treatment to Pb-treated PD animals tended to restore the levels of altered elements. Hence, the present study clearly suggests that Zn plays an important role in regulating the liver marker enzymes and essential elements under conditions of Pb toxicity and protein deficiency. 相似文献
817.
运用因子分析法分析了临沂商品城沉积剖面特征微量地球化学元素及其比值,揭示了沂河中游末次冰消期至中全新世的气候演变过程.结果表明,沂河中游末次冰消期至中全新世沂河中游气候演变经历了6个阶段:(1)16866—13630 cal a B.P.末次冰消期气候冷干;(2)13630—10440 cal a B.P.气候回升但在11868—10440 cal a B.P.,气候突然变得冷干,基本上可以与YD气候事件相对应;(3)10440—8672 cal a B.P.进入全新世后气候以冷湿为主;(4)8672—6755 cal a B.P.大暖期气候不稳定波动剧烈,气候干湿交替,以暖湿为主;(5)6755—5850 cal a B.P.气候趋向干旱化;(6)5850—4698 cal a B.P.气候转向暖湿. 相似文献
818.
Neutron activation analysis was used for the determination of the elemental composition of different plants and soils. Variations in concentrations of elements during the day were found. Mean concentrations, standard deviations and relationships between elements in soils and different parts of plants were studied. It was shown that the behaviour of chemical elements in samples from urban and unpolluted areas have significant differences. 相似文献
819.
Cd-Cu-Pb复合污染对芥菜吸收Cd、Cu和Pb及矿质元素的影响 总被引:4,自引:2,他引:2
以十字花科的芥菜为材料,通过室内盆栽均匀设计试验,研究了Cd-Cu-Pb复合污染下芥菜对重金属的吸收转运特点以及对矿质元素吸收的影响. 结果表明:3种重金属在芥菜体内积累能力为Cd>Cu>Pb;芥菜对Pb、Cd有较强耐性,对高浓度Cu耐性不强. 土壤中重金属的含量是影响芥菜各部分重金属含量的主要因素之一;Cd可抑制芥菜对Pb的吸收和转移,促进Cu向芥菜地上部转移;Cd-Pb复合效应促进了Cd在芥菜体内累积;Cu抑制芥菜吸收Pb;Cu-Pb可促进Cd抑制Cu在芥菜各部的积累. 与对照相比,复合污染显著降低了芥菜对矿质元素的吸收累积,各处理芥菜对Mg、Fe和K的吸收转移特点显示出相似的规律,即地上部w(Mg)远大于地下部而w(Fe)和w(K)为地下部占优. Cd可极大促进芥菜对K的吸收而抑制对Fe的吸收,Cu则阻碍地下部对K的吸收;Cu与Cd-Pb复合效应可抑制K向地上部转移. 相似文献
820.
Trace element concentration in wheat grain: results from the Swedish long-term soil fertility experiments and national monitoring program 总被引:4,自引:1,他引:3
Holger Kirchmann Lennart Mattsson Jan Eriksson 《Environmental geochemistry and health》2009,31(5):561-571
Concentrations of trace elements in wheat grain sampled between 1967 and 2003 from the Swedish long-term soil fertility experiments
were analyzed using ICP-MS. The long-term effect of inorganic and organic fertilization on trace metal concentrations was
investigated including the impact of atmospheric deposition and myccorhiza, whereas other factors such as soil conditions,
crop cultivar, etc. are not discussed in this paper. Mean values derived from 10 experimental sites were reported. Significantly
declining Pb and Cd concentrations in wheat grain could be explained by lower atmospheric deposition. Mean Se contents in
all samples were 0.031 mg kg−1 grain dry weight. No samples had sufficiently high Se concentrations for human (0.05 mg Se kg−1) or animal demand (0.1 mg Se kg−1). Concentrations of Co in wheat grain were extremely low, 0.002–0.005 mg Co kg−1 grain dry weight, and far below the minimum levels required by animals, which applied to all fertilizer treatments. A doubling
of Mo concentrations in grain since 1975 resulted in Cu/Mo ratios often below one, which may cause molybdenosis in ruminants.
The increase in Mo concentrations in crops correlated with the decline in sulfur deposition. Concentrations of Cu and Fe declined
in NPK-fertilized wheat as compared to unfertilized or manure-treated wheat. Very low concentrations of Se and Co and low
concentrations of Fe and Cu require attention to counteract risks for deficiencies. The main characteristic of the study is
that there are few significant changes over time between different fertilizer treatments, but throughout there are low concentrations
of most trace elements in all treatments. In general, good agreement between concentrations in wheat from the long-term fertility
experiments and the national monitoring program indicate that values are representative. 相似文献