乌鲁木齐树木叶片汞浓度时空特征及环境意义

城市大气环境由于受人为活动影响,具有较高大气汞浓度和时空分布不均一特征。植被叶片虽具有较强富集大气汞的能力,但能否指示城市大气汞时空变化,目前尚有存疑。本文通过连续监测新疆乌鲁木齐市区内6个采样点5种常见树种叶片,在生长季（2019年5～10月）内的汞浓度,分析树叶汞浓度的时空分布变化特征,进而寻找潜在的最优树种叶片,反演乌鲁木齐大气汞污染程度。结果表明,城市内的局地污染能够显著提高叶片汞浓度;树种叶片对大气汞浓度的敏感性存在明显差异（P<0.01）;落叶阔叶树的叶汞浓度与叶片生长时间呈显著正相关关系（P<0.01）,即叶片在整个生长期不断积累大气汞;而针叶汞浓度一年之内与生长时间无显著关系。考虑到圆冠榆叶片对大气汞浓度敏感性较高且分布范围更广,圆冠榆作为乌鲁木齐城市大气汞的生物监测器较为合适。本研究为研究城市大气汞浓度生物监测提供了典型的案例与借鉴。     

环境约束下长江经济带全要素能源效率的时空分异研究——基于超效率DEA模型和ML指数法

基于超效率DEA模型和ML指数法,考察长江经济带1999~2013年全要素能源效率。实证研究结果显示:研究期内,环境约束下的长江经济带全要素能源效率年均下降2.9%,而不考虑环境因素的全要素能源效率年均下降幅度仅为0.4%,污染是导致能源效率损失的重要因素;长江经济带整体层面全要素能源效率的发展演变基本呈"双峰一谷"的"M"形分布,表现为两个"上升—下降"周期,而省际和上中下游全要素能源效率的演变特征迥异;从空间差异看,省际全要素能源效率差异远远大于上中下游差异,但近年来这种差异均有不同程度的缩小。未来长江经济带发展必须践行生态文明发展战略,保证发展的可持续性,同时加强能源、环保等领域的合作,促进长江经济带全要素能源效率发展的协同进步。     

Life-cycle phosphorus use efficiency of the farming system in Anhui Province,Central China

The rapid increase of phosphorus (P) use in farming has raised concerns regarding its conservation and environmental impact. Increasing the P use efficiency (PUE) is an approach to mitigating these adverse impacts. In this study, we applied substance flow analysis (SFA) to establish a life-cycle P use efficiency model to determine the life-cycle PUE of the farming system used in Anhui Province in 2011, which is typical of the agriculture practiced in central China. Based on this model, the P flows and PUEs of five subsystems were identified and quantified: crop farming, crop processing, livestock breeding, rural living, and urban living. The three largest P flows were found in the crop farming and livestock breeding subsystems; it can therefore be concluded that these subsystems have substantial impacts on the entire farming system. In contrast, the PUEs of crop farming, rural consumption, and livestock breeding subsystems presented the three lowest PUEs (58.79%, 71.75%, and 76.65%, respectively). These results were also consistent with the finding that the greatest P losses occurred in crop farming and livestock breeding. Consequently, the study proposes that great potential exists for increasing PUEs in the farming system of Anhui, and several of the most promising measures could be combined for improving PUEs. Finally, the study assesses data quality and presents a sensitivity analysis for use in interpreting the results. The study also shows that improving PUE and decreasing P losses in farming systems through improved nutrient management must be considered an important issue, and this study represents valuable experience in resource conservation and agricultural development in China.     

大红丙烯酸油漆着色剂替代及其综合利用研究

清洁生产与资源综合利用是人们持续研究的课题,笔者在大红丙烯酸油漆着色剂"颜料红GL"替代"镉红颜料"中,开展了颜料红GL随温度、时间变化与热塑性丙烯酸树脂、有机硅助剂、二甲苯最佳浓度配比,确保着色效果及其资源综合利用等一系列试验,实现了年综合利用工艺冲洗水25.6万吨,减排CODcr 218.24吨、总镉:油漆中8031.5吨,废水中0.41吨、固废中0.088吨,提高了产品市场竞争率。     

控释尿素不同施用条件下冬小麦产量和氮素利用效应

采用田间试验方法研究了控释尿素不同施用条件对冬小麦产量、氮素利用和经济效益的影响。试验共设7个处理,即CK （空白处理,不施氮肥）、100%PU10/0（普通尿素全量基施,N 240 kg＆#183;hm-2）、100%PU6/4（60%的普通尿素基施、40%的普通尿素于拔节期追施,N 240 kg＆#183;hm-2）、80%PU6/4（60%的普通尿素基施、40%的普通尿素于拔节期追施,N 192 kg＆#183;hm-2）、100%CRU（全量树脂包膜控释尿素基施,N 240 kg＆#183;hm-2）、80%CRU（80%树脂包膜控释尿素基施,N 192 kg＆#183;hm-2）和40%CRU＋40%PU（40%树脂包膜控释尿素＋40%的普通尿素基施,N 192 kg＆#183;hm-2）。结果表明,无论是产量效应还是氮素利用效应,树脂包膜控释尿素（CRU）处理总体优于普通尿素（PU）处理,尤其树脂包膜控释尿素和普通尿素配施（40%CRU＋40%PU）效果最佳,以7709 kg＆#183;hm-2的产量、36.44%的氮肥吸收利用率、15946元＆#183;hm-2的相对净收入达到处理间最高水平。该处理在减少氮素投入量的情况下,不仅促进了冬小麦增产,而且显著提高了肥料的利用率,拥有较高的产投比。因此,树脂包膜控释尿素和普通尿素的配施处理（40%CRU＋40%PU）是本试验条件下最优的氮肥处理。     

Environmental resource footprinting of drug manufacturing: Effects of scale-up and tablet dosage

The formulation and scale-up of batch processes is one of the major challenges in the development of pharmaceutical dosage forms and at the same time a significant resource demanding process which is generally overlooked in environmental sustainability assessments. First, this paper proposes general trends in the experience curve of cumulative resource consumption of pharmaceutical tablet manufacturing of PREZISTA^® 800 mg through wet granulation (WG) at four consecutive scales in both R&D and manufacturing environments (resp. WG1 = 1 kg/h, WG5 = 5 kg/h, WG30 = 30 kg/h and WG240 = 240 kg/h). Second, the authors aim at evaluating the environmental impact from a life cycle perspective of a daily consumption of PREZISTA^® 2× 400 mg tablets versus the bioequivalent PREZISTA^® 800 mg tablet which was launched to enhance patient compliance. Environmental sustainability assessment was conducted at three different system boundaries, which enables identification, localization and eventually reduction of burdens, in this case natural resource extraction. Exergy Analysis (EA) was used at process level (α) and plant level (β) while a cradle-to-gate Exergetic Life Cycle Assessment (ELCA) was conducted at the overall industrial level (γ) by means of the CEENE method (Cumulative Exergy Extraction from the Natural Environment). Life cycle stages taken into account are Active Pharmaceutical Ingredient (API) production, Drug Product (DP) production and Packaging. At process level (α), the total resource extraction for the manufacturing of one daily dose of PREZISTA^® (800 mg tablet) amounted up to 0.44 MJ_ex at the smallest scale (WG1) while this amount proved to be reduced by 58%, 79% and 83% at WG5, WG30 and WG240 respectively. Expanding the boundaries to the overall industrial level (γ) reveals that the main resource demand is at the production of the Active Pharmaceutical Ingredient (API), excipients, packaging materials and cleaning media used in DP production. At the largest scale (WG240) the use of cleaning media during DP production contributes considerably less to the total resource extraction. Overall, the effect of scale-up and learning on resource consumption during DP production showed to possess a power-law experience curve y = 2.40 * x^−0.57 when shifting from WG1 (smallest lab scale) to WG240 (industrial manufacturing). Tablet dosage (2× 400 mg versus 1× 800 mg) did not significantly affect the absolute environmental burden. However, the relative contribution of resource categories did change due to the different production technology. It could be concluded that in meeting social and economic demands by launching the PREZISTA^® 800 mg tablet, no trade-off in environmental burden occurred. On the long term, future research should strive to take into account R&D processes and all services related to pipeline activities taking place prior to market launch and eventually to allocate impacts to the final product.     

System dynamics model for analyzing effects of eco-design policy on packaging waste management system

EU's long-term objective is to become a recycling and resource effective society, where waste is utilized as a resource and waste generation is prevented. A system dynamics model was developed to analyze the policy mechanisms that promote packaging material efficiency in products through increased recycling rates. The model includes economic incentives such as packaging and landfill taxes combined with market mechanisms, behavioral aspects and ecological considerations in terms of material efficiency (the packaging material per product unit, recycled fraction in products). The paper presents the results of application of various policy instruments for increasing packaging material efficiency and recovery rate and reducing landfilled fraction. The results show that a packaging tax is an effective policy instrument for increasing the material efficiency. It ensures the decrease of the total consumption of materials and subsequent waste generation. The tax helps to counteract a rebound effect, which, as identified by the analysis, can be caused by reduced material costs due to eco-design. The model is applied to the case of Latvia. Yet, the elements and structure of the model developed are similar to waste management systems in many countries. By changing numeric values of certain parameters, the model can be applied to analyze policy mechanisms in other countries.     

秸秆还田下氮肥用量对玉米产量及土壤无机氮的影响

研究连续2年秸秆还田下氮肥用量对玉米产量、氮肥利用率及土壤硝态氮的影响,结果表明,玉米产量随着施氮量的增加逐渐增加,施氮量达到216 kg·hm^-2时,产量最高,施氮量超过216 kg·hm^-2时产量有降低的趋势。相同施氮处理玉米产量年际变化明显,2010年较2009年产量提高0.69％~4.75％。氮肥利用率、氮肥农学利用率和氮收获指数随着秸秆还田年限的增加,均有不同程度的增加。2年0~100 cm土层土壤硝态氮含量均以施氮240 kg·hm^-2最高,且有向土壤深层迁移的趋势,对浅层地下水构成潜在的威胁。与施氮240 kg·hm^-2相比,施氮168、192 kg·hm^-2和216 kg·hm^-2处理0~100 cm土壤无机氮残留量2年平均减少39.87％、35.84％和29.38％。相同施氮处理,0~100 cm土壤无机氮累积量2010年较2009年略有降低。综合考虑玉米产量、氮肥利用率与生态环境效益,该地区最适施氮量200 kg·hm^-2左右。     

我国工业固体废物处理利用行业2013年发展综述

综述了我国工业固体废物处理利用行业2013年的发展环境形势和发展概况;介绍了2013年国内工业固体、危险废物及生活垃圾的产生量和处理情况;阐述并分析了目前国内固体废物处理技术和设施的现状;就行业发展存在的主要问题提出了建议.     

基于突变级数法的武汉市农地利用绩效评价及影响因素分析

根据突变级数法基本原理,对武汉市2002-2011年农地利用绩效动态变化情况进行分析,并利用障碍度模型找出影响其绩效水平的主要障碍因子.研究结果表明,研究时段内武汉市农地利用绩效整体呈上升趋势,且带有明显的阶段性特征;经济绩效是影响农地利用绩效的最主要障碍因素;从单项指标来看,随着生态理念的不断深化,未来农地利用程度及资源安全将对农地利用绩效产生较大影响.